A vitrifiable feed material for producing flint glass by way of a process that uses submerged combustion melting includes a base glass portion, an oxidizing agent, and a decolorant. The base glass portion includes an SiO.sub.2 contributor, an Na.sub.2O contributor, and a CaO contributor to provide SiO.sub.2, Na.sub.2O, and CaO, respectively, to a glass melt when melted therein. The oxidizing agent may be a sulfate compound in an amount ranging from 0.20 wt % to 0.50 wt % as expressed as SO.sub.3 based on the total weight of the vitrifiable feed material, and the decolorant may be selenium in an amount ranging from 0.008 wt % to 0.016 wt % or manganese oxide in an amount ranging from 0.1 wt % to 0.2 wt % based on the total weight of the vitrifiable feed material.

Processes and systems for producing glass fibers having regions devoid of glass using submerged combustion melters, including feeding a vitrifiable feed material into a feed inlet of a melting zone of a melter vessel, and heating the vitrifiable material with at least one burner directing combustion products of an oxidant and a first fuel into the melting zone under a level of the molten material in the zone. One or more of the burners is configured to impart heat and turbulence to the molten material, producing a turbulent molten material comprising a plurality of bubbles suspended in the molten material, the bubbles comprising at least some of the combustion products, and optionally other gas species introduced by the burners. The molten material and bubbles are drawn through a bushing fluidly connected to a forehearth to produce a glass fiber comprising a plurality of interior regions substantially devoid of glass.

Submerged combustion burners having improved fuel and oxidant mixing characteristics. Submerged combustion melters including the burners. Methods of using submerged combustion melters to melt glass-forming materials and produce molten glass.

A method of producing glass using submerged combustion melting includes supplying a combustible gas mixture to one or more submerged burners of a submerged combustion melter, combusting the combustible gas mixture supplied to the submerged burner(s) to produce combustion products, and discharging the combustion products from the submerged burner(s) directly into a glass melt contained within the submerged combustion melter to agitate and heat the glass melt. The glass melt is comprised of soda-lime-silica glass and has a redox ratio. Additionally, the disclosed method involves controlling one or more operating conditions of the submerged combustion melter selected from (1) an oxygen-to-fuel ratio of the combustible gas mixture supplied to each of the submerged burners, (2) a residence time of the glass melt, and (3) a gas flux through the glass melt.

A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a dissolvable fining material component. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed that includes a housing, a skimmer, and a dissolvable fining material component disposed directly beneath the skimmer.

A method of producing glass includes receiving unrefined molten glass in a stilling chamber of a stilling tank at a fluctuating flow rate. An intermediate pool of molten glass is held within the stilling chamber of the stilling tank and is heated therein by one or more non-submerged burners. Molten glass flows from the intermediate pool of molten glass to a transfer pool of molten glass held in a spout chamber of a feeding spout that is appended to the stilling tank. A molten glass feed can be drawn from the transfer pool of molten glass and delivered from the feeding spout at a controlled flow rate.

An apparatus for manufacturing glass includes a furnace. A doghouse of the furnace receives and melts solid-glass forming material using one or more submerged combustion burners. An elongated tank positioned downstream of the doghouse includes a melting chamber, a refining chamber, and a thermal conditioning. The melting chamber has in inlet through which molten glass is received from the doghouse. The refining chamber is positioned downstream of the melting chamber and receives molten glass from the melting chamber. The thermal conditioning chamber is positioned downstream of the refining chamber and receives molten glass from the refining chamber. Additionally, the thermal conditioning chamber delivers molten glass to a glass forming machine.

A method of melting glass and glass-ceramics that includes the steps: conveying a batch of raw materials into a submerged combustion melting apparatus, the melting apparatus having liquid-cooled walls and a floor; directing a flame into the batch of raw materials and the melted batch with sufficient energy to form the raw materials into the melted batch; and heating a delivery orifice assembly in the floor of the submerged melting apparatus to convey the melted batch through the orifice assembly into a containment vessel. The melted batch has a glass or glass-ceramic composition that is substantially reactive to a refractory material comprising one or more of silica, zirconia, alumina, platinum and platinum alloys.

A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a dissolvable fining material component. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed.

A method of producing and fining glass includes monitoring a temperature of a molten glass bath contained within a fining chamber of a fining vessel and, based on the monitored temperature, controlling an amount of a sulfate chemical fining agent added into a glass melt contained within an interior reaction chamber of an upstream submerged combustion melter that feeds the fining vessel. The temperature of the molten glass bath may be determined within a temperature indication zone that encompasses a subsurface portion of the molten glass bath that lies adjacent to a floor of a housing of the fining vessel. By monitoring the temperature of the molten glass bath and controlling the amount of the sulfate chemical fining agent added to the glass melt of the submerged combustion melter, the wasteful use of the sulfate chemical fining agent can be minimized and the fining process rendered more efficient.