A substrate for a display article is described herein including (a) a primary surface; and (b) a textured region disposed at the primary surface, the textured region comprising: (i) one or more higher surfaces residing at a higher mean elevation parallel to a base-plane disposed below the textured region extending through the substrate; (ii) one or more lower surfaces residing at a lower mean elevation parallel to the base-plane; and (iii) surface features providing at a least a portion of either or both of (i) the one or more higher surfaces and (ii) the one or more lower surfaces. The surface features can include larger surface features and smaller surface features, either or both providing one or more surfaces of the substrate that reside at one or more intermediate mean elevations parallel to the base-plane between the higher mean elevation and the lower mean elevation.

A silicate-based composition includes: 40-80 mol % SiO.sub.2, >0-25 mol % MO, 15-40 mol % R.sub.2O, >0-10 mol % Al.sub.2O.sub.3, >0-10 mol % P.sub.2O.sub.5, and >0-5 mol % ZrO.sub.2, such that MO is a sum of BeO, MgO, CaO, SrO, and BaO; and R.sub.2O is a sum of Li.sub.2O, Na.sub.2O, K.sub.2O, Rb.sub.2O, Cs.sub.2O.

A glass of the present invention includes as a glass composition, in terms of mass %, 50% to 75% of SiO.sub.2, 1% to 30% of Al.sub.2O.sub.3, 0% to 25% of B.sub.2O.sub.3, 0% to 10% of Li.sub.2O, 0.01% to 20% of Na.sub.2O, 0% to 10% of K.sub.2O, 0.0001% to 0.1% of Fe.sub.2O.sub.3, 0.00001% to 0.01% of Cr, 0.00001% to 0.01% of Ni, and 0.0001% to 0.5% of TiO.sub.2.

A patterned article that includes: an alkali silicate glass substrate comprising a thickness and a primary surface, the substrate having a bulk composition; a patterned region defined by at least a portion of the primary surface; and a compressive stress region that extends from the at least a portion of the primary surface to a first depth within the substrate. The patterned region comprises a surface roughness (Ra) from about 1 nm to about 600 nm and at least one of a plurality of protrusions and a plurality of depressions. Further, each of the compressive stress region and the patterned region comprises a concentration of at least one alkali metal ion that is different than the concentration of the at least one alkali metal ion in the bulk composition.

A patterned article that includes: an alkali silicate glass substrate comprising a thickness and a primary surface, the substrate having a bulk composition; a patterned region defined by at least a portion of the primary surface; and a compressive stress region that extends from the at least a portion of the primary surface to a first depth within the substrate. The patterned region comprises a surface roughness (Ra) from about 1 nm to about 600 nm and at least one of a plurality of protrusions and a plurality of depressions. Further, each of the compressive stress region and the patterned region comprises a concentration of at least one alkali metal ion that is different than the concentration of the at least one alkali metal ion in the bulk composition.

A process for the preparation of multi-coloured dental restorations is described, in which glasses and glass ceramics with various compositions are given the shapes of dental restorations and colour changes are effected in the glasses and glass ceramics by irradiating them with artificial electromagnetic radiation and subjecting them to a heat treatment.

A process for the preparation of multi-coloured dental restorations is described, in which glasses and glass ceramics with various compositions are given the shapes of dental restorations and colour changes are effected in the glasses and glass ceramics by irradiating them with artificial electromagnetic radiation and subjecting them to a heat treatment.

A three dimensional glass ceramic article with a thickness between 0.1 mm and 2 mm, having a dimensional precision control of less than or equal to ±0.1 mm. A method for forming a three dimensional glass ceramic article including placing a nucleated glass article into a mold, and heating the nucleated glass article to a crystallization temperature, where the nucleated glass article is in the mold during the heating. Then, holding the nucleated glass article at the crystallization temperature for a duration sufficient to crystallize the nucleated glass article and form a three dimensional glass ceramic article, where the nucleated glass article is in the mold during the holding, and removing the three dimensional glass ceramic article from the mold.

Embodiments of articles with optical coatings are described herein. According to one embodiment, an article may comprise a substrate having a major surface, and an optical coating disposed on the major surface and forming an anti-reflective surface, the optical coating comprising an anti-reflective coating. The article may exhibit a maximum hardness of about 12 GPa or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm or greater. The article may exhibit a single side average light reflectance measured at the anti-reflective surface of about 8% or less over an optical wavelength regime in the range from about 400 nm to about 800 nm. The article may exhibit an average light transmission of about 90% or greater over an optical wavelength regime in the range from about 400 nm to about 800 nm.

Embodiments of articles with optical coatings are described herein. According to one embodiment, an article may comprise a substrate having a major surface, and an optical coating disposed on the major surface and forming an anti-reflective surface, the optical coating comprising an anti-reflective coating. The article may exhibit a maximum hardness of about 12 GPa or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm or greater. The article may exhibit a single side average light reflectance measured at the anti-reflective surface of about 8% or less over an optical wavelength regime in the range from about 400 nm to about 800 nm. The article may exhibit an average light transmission of about 90% or greater over an optical wavelength regime in the range from about 400 nm to about 800 nm.