The present invention includes methods of promoting single crystal growth via solid-solid transformation of an appropriate glass, while avoiding the gaseous or liquid phase. In certain embodiments, in the all-solid-state glass-to-crystal transformation of the invention, extraneous nucleation is avoided relative to crystal growth via spatially localized laser heating and optional inclusion of a suitable glass former in the composition. The ability to fabricate patterned single-crystal architecture on a glass surface was demonstrated, providing a new class of micro-structured substrate for low cost epitaxial growth and active planar devices, for example.

Provided is a sulfide solid electrolyte glass ceramic containing a lithium atom, a sulfur atom, a phosphorus atom, and a halogen atom and having peaks at diffraction angles (2) of 20.2 and 29.3 in X-ray diffractometry using CuK line. Due to an intensity ratio (P.sub.A/P.sub.B) of a peak intensity (P.sub.A) of the peak appearing at 2=20.2 to a peak intensity (P.sub.B) of the peak appearing at 2=29.3 made into more than 1.0, the sulfide solid electrolyte glass ceramic has a high ionic conductivity and has an increased water resistance. A method for producing the sulfide solid electrolyte glass ceramic is also provided.

The main object or purpose of the present invention is to provide a glass material that is suitable for mold forming, can reduce the size, and allows rays having a wavelength region between visible light to far-infrared light to pass through. To overcome this object, the present invention provides a glass material allowing rays having a wavelength in the region from visible light to far-infrared light to pass through, the glass material comprising, in terms of molar concentration: 50 to 70% of S, 15 to 30% of Ge, 5 to 20% of Ga, 0.5 to 15% of Ba, and 3 to 15% of at least one member selected from the group consisting of Cl, Br, and I, with the proviso that when the Cl is present alone, the molar concentration is 6 to 15%.

Provided is a thermally stable and inexpensive infrared-transmitting glass. An infrared-transmitting glass contains, in terms of % by mole, over 0 to 9% Ge, over 0 to 50% Ga, 50 to 90% Te, 0 to 40% Si+Al+Ti+Cu+In+Sn+Bi+Cr+Sb+Zn+Mn+Cs+Ag+As+Pb, and 0 to 40% F+Cl+Br+I.

The present invention aims to provide a vehicular exterior member that is excellent in strength and cost, and sufficiently ensures a viewing field of sharpness of a thermal image obtained by a far-infrared camera. A vehicular exterior member that includes a light blocking region and is configured to be attached to a vehicle equipped with a far-infrared camera. The vehicular exterior member further includes, in the light blocking region, a far-infrared ray transmitting region having an opening and a far-infrared ray transmitting member disposed in the opening. An average transmittance of far-infrared rays having a wavelength ranging from 8 to 13 m of the far-infrared ray transmitting member is equal to or larger than 25%. A length of the longest straight line in straight lines connecting any desired two points on a surface on a vehicle exterior side of the far-infrared ray transmitting member is equal to or smaller than 80 mm. A diameter of the largest circle in circles formed in a projected shape obtained by projecting the far-infrared ray transmitting member in an optical axis direction of the far-infrared camera is equal to or larger than 12 mm. An average thickness of the far-infrared ray transmitting member is equal to or larger than 1.5 mm.

A metal element-containing sulfide solid electrolyte may suppress H.sub.2S generation. Such a metal element-containing sulfide solid electrolyte may include a lithium element, a sulfur element, a phosphorus element, a halogen element, and at least one metal element selected from metal elements of Groups 3 to 12 and Period 4 or higher of the Periodic Table, in which the molar ratio of the lithium element to the phosphorus element (Li/P) is 2.4 or more and 12 or less, and the molar ratio of the sulfur element to the phosphorus element (S/P) is 3.7 or more and 12 or less.

Provided is a thermally stable and inexpensive infrared-transmitting glass. An infrared-transmitting glass contains, in terms of % by mole, over 0 to 9% Ge, over 0 to 50% Ga, 50 to 90% Te, 0 to 40% Si+Al+Ti+Cu+In+Sn+Bi+Cr+Sb+Zn+Mn+Cs+Ag+As+Pb, and 0 to 40% F+Cl+Br+I.

Described are a solid material which has ionic conductivity for lithium ions, a process for preparing the solid material, a use of the solid material as a solid electrolyte for an electrochemical cell, a solid structure selected from the group consisting of a cathode, an anode and a separator for an electrochemical cell, and an electrochemical cell including the solid structure.

Provided is a thermally stable infrared-transmitting glass. An infrared-transmitting glass contains, in terms of % by mole, over 15 to 40% Ge, over 0 to 40% Ga, 40 to below 80% Te, 0 to 40% Si+Al+Ti+Cu+In+Sn+Bi+Cr+Sb+Zn+Mn+Cs+Ag+As+Pb, and 0 to 40% F+Cl+Br+I.