Patent classifications
C03C2201/50
SPRAY GRANULATION OF SILICON DIOXIDE IN THE PREPARATION OF QUARTZ GLASS
One aspect relates to a process for the preparation of a quartz glass body. The process includes providing a silicon dioxide granulate, making a glass melt out of the silicon dioxide granulate, and making a quartz glass body out of at least a part of the glass melt. In one aspect, providing a silicon dioxide granulate includes providing of a silicon dioxide powder and processing of the powder to obtain a silicon dioxide granulate including the spray drying of a silicon dioxide slurry using a nozzle. The nozzle has a contact surface to the slurry made of glass, plastic or a combination thereof. Furthermore, one aspect relates to a quartz glass body obtainable by this process. Furthermore, one aspect relates to the preparation of a silicon dioxide granulate. One aspect also relates to a light guide, an illuminant, and a formed body, made from processing of the quartz glass body.
OPTICAL FIBER PREFORM
An optical fiber preform includes a silica-glass core portion, and a cladding portion surrounding the core portion, the cladding portion being composed of a fluorine-containing silica glass having a lower refractive index than the core portion, the core portion including a first region that does not include the central axis thereof, the first region containing a first dopant selected from sodium, potassium, and compounds thereof, and a second region that includes the central axis, the second region containing a second dopant that reduces the viscosity of the silica glass, the second dopant having a diffusion coefficient of 110.sup.12 cm.sup.2/s or more and less than the first dopant at 2,000 C. to 2,300 C., in which the entire core portion has an average first dopant concentration of 10 atomic ppm or more and 2,000 atomic ppm or less and an average second dopant concentration of 10 atomic ppm or more.
PREPARATION OF CARBON-DOPED SILICON DIOXIDE GRANULATE AS AN INTERMEDIATE IN THE PREPARATION OF QUARTZ GLASS
One aspect relates to a process for the preparation of a quartz glass body. The process includes providing a silicon dioxide granulate I prepared from a pyrogenically produced silicon dioxide powder, treating the silicon dioxide granulate I with a reactant at a temperature in a range from 1000 to 1300 C., and making a glass melt out of the silicon dioxide granulate. A quartz glass body is made out of at least a part of the glass melt. Furthermore, one aspect relates to a quartz glass body obtainable by this process. Furthermore, one aspect relates to a light guide, an illuminant, and a formed body, each of which is obtainable by further processing of the quartz glass body. One aspect additionally relates to a process for the preparation of a silicon dioxide granulate II.
METHOD FOR MANUFACTURING OPTICAL FIBER PREFORM, METHOD FOR MANUFACTURING OPTICAL FIBER, AND METHOD FOR DOPING SILICA GLASS
Provided is an alkali doping process of bringing a melt of an alkali metal compound or an alkaline earth metal compound into contact with a part of the inner circumferential surface of a silica glass tube, and thus doping the silica glass tube with the alkali metal compound or the alkaline earth metal compound, and in the alkali doping process, the contact location between the inner circumferential surface of the silica glass tube and the melt is moved along the longitudinal direction of the silica glass tube while rotating the silica glass tube around its longitudinal axis.
OPTICAL FIBER
Provided is an optical fiber containing an alkali metal element or the like having a smaller diffusion coefficient than K and having a low Rayleigh scattering loss. An optical fiber is composed of silica glass and includes a core and a cladding arranged to surround the core which has a lower refractive index than the core. The core includes a first core including a central axis and a second core arranged to surround the first core. The average concentration of an alkali metal element or alkaline-earth metal element in the first core is 10 mol ppm or less. The average concentration of chlorine in the first core is 2000 mol ppm or more. The average concentration of an alkali metal element or alkaline-earth metal element in the second core is 10 mol ppm or more. The average concentration of chlorine in the second core is 10 to 600 mol ppm.
System and process for forming curved glass laminate article utilizing glass viscosity differential for improved shape matching
A system and process for forming a curved glass laminate article is provided. The process and system utilizes co-sagging of a stack of glass sheets of different thicknesses and different glass materials. During co-sagging the thicker glass layer is placed on top of the thinner glass layer. In this process, shape mismatch is avoided by selecting/controlling the glass materials of the sheets of glass such that the viscosity of the lower, thinner sheet during co-sagging is greater than the viscosity of the thicker glass sheet.
Optical fiber preform
An optical fiber preform of the present embodiment comprises a core portion and a cladding each comprised of silica glass. The core portion has a first dopant region including a central axis of the core portion and a second dopant region away from the central axis. The first dopant region contains a first dopant selected from among Na, K, and their compounds, and a concentration of the first dopant is 10 atomic ppm or more but 2,000 atomic ppm or less. The second dopant region contains a second dopant reducing viscosity of the silica glass. The second dopant has, as a characteristic at a temperature of 2,000 C. to 2,300 C., a diffusion coefficient of 110.sup.12 cm.sup.2/s or higher but lower than that of the first dopant, and a concentration of the second dopant region is 10 atomic ppm or more.
OPTICAL FIBER WITH LOW LOSS AND NANOSCALE STRUCTURALLY HOMOGENEOUS CORE
An optical fiber has a core region that is doped with one or more viscosity-reducing dopants in respective amounts that are configured, such that, in a Raman spectrum with a frequency shift of approximately 600 cm.sup.1, the fiber has a nanoscale structure having an integrated D2 line defect intensity of less than 0.025. Alternatively, the core region is doped with one or more viscosity-reducing dopants in respective amounts that are configured such that the fiber has a residual axial compressive stress with a stress magnitude of more than 20 MPa and a stress radial extent between 2 and 7 times the core radius.
According to another aspect of the invention a majority of the optical propagation through the fiber is supported by an identified group of fiber regions comprising the core region and one or more adjacent cladding regions. The fiber regions are doped with one or more viscosity-reducing dopants in respective amounts and radial positions that are configured to achieve viscosity matching among the fiber regions in the identified group.
GLASS FIBER COMPOSITION, GLASS FIBER AND COMPOSITE MATERIAL THEREFROM
The present invention provides a glass fiber composition, glass fiber and composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 58-63% SiO.sub.2, 13-17% Al.sub.2O.sub.3, 6-11.8% CaO, 7-11% MgO, 3.05-8% SrO, 0.1-2% Na.sub.2O+K.sub.2O+Li.sub.2O, 0.1-1% Fe.sub.2O.sub.3, 0-1% CeO.sub.2 and 0-2% TiO.sub.2, wherein a weight percentage ratio C1=(MgO+SrO)/CaO is greater than 1. Said composition greatly improves the refractive index of glass, significantly shields against harmful rays for humans and further reduces glass crystallization risk and production costs, thereby making it more suitable for large-scale production with refractory-lined furnaces.
Optical fiber
An optical fiber containing alkali metal elements or the like in which Rayleigh scattering loss can be reduced is provided. An optical fiber includes a core composed of silica glass and a cladding which surrounds the core, has a refractive index lower than a refractive index of the core, and is composed of silica glass containing fluorine. The core contains a first group of dopants and a second group of dopants having a diffusion coefficient lower than a diffusion coefficient of the first group of dopants. The difference between the maximum value and the minimum value of residual stress in the optical fiber is 150 MPa or less.