An article that includes: a glass-based substrate comprising opposing major surfaces; a crack mitigating composite over one of the major surfaces, the composite comprising an inorganic element and a polymeric element; and a hard film disposed on the crack mitigating composite comprising an elastic modulus greater than or equal to the elastic modulus of the glass-based substrate. The crack mitigating composite is characterized by an elastic modulus of greater than 30 GPa. Further, the hard film comprises at least one of a metal-containing oxide, a metal-containing oxynitride, a metal-containing nitride, a metal-containing carbide, a silicon-containing polymer, a carbon, a semiconductor, and combinations thereof.

The present invention provides a glass sheet with a low-emissivity multilayer film having improved properties required for glass products. A glass sheet (10) with a low-emissivity multilayer film according to the present invention includes a glass sheet (1) and a low-emissivity multilayer film (2) supported by the glass sheet (1). The low-emissivity multilayer film (2) has a ZrO.sub.2-containing layer (3) disposed on an outermost side of the low-emissivity multilayer film (2) and a transparent conductive layer (4) disposed between the glass sheet (1) and the ZrO.sub.2-containing layer (3). A content of ZrO.sub.2 in the ZrO.sub.2-containing layer (3) is 8 mol % or more and 100 mol % or less. A content of SiO.sub.2 in the ZrO.sub.2-containing layer (3) is 0 mol % or more and 92 mol % or less. An arithmetic average roughness Ra of a surface (3a) of the ZrO.sub.2-containing layer (3) is 12 nm or less, and is smaller than an arithmetic average roughness Ra of a surface (4a) of the transparent conductive layer (4).

A method of manufacturing a variable reflectance mirror reflective element suitable for use in a vehicular rearview mirror assembly includes providing a front glass sheet and a plurality of rear glass substrates, and joining and spacing the rear glass substrates at the front glass sheet via perimeter seals. After the rear glass substrates are joined with the front glass sheet, the front glass sheet is cut to form a plurality of front glass substrates. A back plate is attached at the rear side of each of the rear glass substrates. After cutting the front glass sheet, the back plate of the respective rear glass substrate and cut front glass substrate portion is fixtured at a finishing tool, which processes the cut edges of at least the respective front glass substrate to provide a finished perimeter edge of the front glass substrate to form a variable reflectance mirror reflective element.

Methods of processing coated articles, such as transparencies, are provided comprising flash annealing one or more layers of the coated article. The one or more layers may be reflective metallic layers, such as silver layers, or comprise a transparent conductive oxide, such as indium tin oxide, or a semiconductor.

A heating device equipped with a chamber defining a cavity, includes a door or wall incorporating a triple glazing including three transparent substrates defining, from the interior to the exterior of the cavity, faces numbered 1 to 6 respectively, at least the faces 1 and 2 of the first substrate and 3 and/or 4 of the second substrate being covered with heat-reflecting coatings, wherein the mean spacing e1 between the first substrate and the second substrate and the mean spacing e2 between the second substrate and the third substrate is different, the ratio between the largest spacing and the smallest spacing being greater than 1.1, and e1 and e2 being between 2 and 20 mm.

Methods and materials to fabricate electrochromic including electrochemical devices are disclosed. In particular, emphasis is placed on the composition, fabrication and incorporation of electrolytic sheets in these devices. Composition, fabrication and incorporation of redox layers and sealants suitable for these devices are also disclosed. Incorporation of EC devices in insulated glass system (IGU) windows is also disclosed.

A treated substrate includes a low emissivity coating layer disposed on a substrate and a high emissivity coating layer disposed on the low emissivity coating layer. The low emissivity coating layer is formed a low emissivity coating composition including silver, or indium tin oxide, or fluorine-doped tin oxide, while the high emissivity coating layer is formed from a high emissivity coating composition including a carbon-doped silicon oxide. The treated substrate has an emissivity of from 0.7 to less than 1.0 at wavelengths ranging from 8 micrometers to 13 micrometers and has an emissivity of greater than 0 to 0.3 at wavelengths less than 6 micrometers. The treated substrate also maintains a visually acceptable mechanical brush durability resistance for at least 150 test cycles tested in accordance with ASTM D2486-17.

An electrochromic article includes a first substrate having a first surface and an opposite second surface and a second substrate having a third surface and an opposite fourth surface separated from the first substrate. The second surface of the first substrate faces the third surface of the second substrate and a first electrode is positioned over at least a portion of the second surface of the first substrate. A second electrode is positioned over at least a portion of the third surface of the second substrate. A sealant material is positioned between the first electrode and second electrode. An electrochromic composition is positioned in direct contact with at least a portion of the first electrode and at least a portion of the second electrode. The sealant material is formed from an organic polymer material having an oxygen transmission rate (OTR) of less than or equal to 2 cc.Math.mm/m.sup.2.Math.day.Math.atm.

The present disclosure relates generally to methods for the integration of electrochromic films onto a substrate, such as a glass window, and the systems/structures formed via such methods.

The invention provides transparent conductive coatings based on indium tin oxide. The coating has an oxide overcoat, such as an alloy oxide overcoat. In some embodiments, the coating further includes one or more overcoat films comprising silicon nitride, silicon oxynitride, silicon dioxide, or titanium dioxide.