The present invention includes a method of creating electrical air gap or other low loss low cost RF mechanically and thermally stabilized interdigitated resonate filter in photo definable glass ceramic substrate. A ground plane may be used to adjacent to or below the RF filter in order to prevent parasitic electronic signals, RF signals, differential voltage build up and floating grounds from disrupting and degrading the performance of isolated electronic devices by the fabrication of electrical isolation and ground plane structures on a photo-definable glass substrate.

The present invention provides a plating film that exhibits good adhesion to glass substrates. The present invention is a plating film comprising an oxide layer, an electroless plating film, and an electrolytic copper plating film in this order.

The present invention includes a method of creating electrical air gap low loss low cost RF mechanically and thermally stabilized interdigitated resonate filter in photo definable glass ceramic substrate. Where a ground plane may be used to adjacent to or below the RF filter in order to prevent parasitic electronic signals, RF signals, differential voltage build up and floating grounds from disrupting and degrading the performance of isolated electronic devices by the fabrication of electrical isolation and ground plane structures on a photo-definable glass substrate.

An article including a glass or glass ceramic substrate, a noble metal layer, an adhesion promoting layer positioned between and bonded to the substrate and the noble metal layer, and a conductive metal layer positioned on and bonded to the noble metal layer. The adhesion promoting layer includes a siloxy group bonded with the substrate and a thiol group bonded to the noble metal layer. A method for manufacturing an article including applying an adhesion promoting layer comprising mercaptosilane to at least a portion of a glass or glass ceramic substrate, wherein siloxane bonds are formed between the mercaptosilane and the substrate, applying a noble metal layer to the adhesion promoting layer, the noble metal layer bonds with a thiol present in the mercaptosilane, thermally treating the noble metal layer, and applying a conductive metal layer to the noble metal layer.

The present invention includes a method of creating high Q empty substrate integrated waveguide devices and/or system with low loss, mechanically and thermally stabilized in photodefinable glass ceramic substrate. The photodefinable glass ceramic process enables high performance, high quality, and/or low-cost structures. Compact low loss RF empty substrate integrated waveguide devices are a cornerstone technological requirement for RF systems, in particular, for portable systems.

Provided is a glass sheet (1) with a film, including a laminated film (2), which includes a plurality of films laminated together, formed on a glass sheet (3). The laminated film (2) includes: an inorganic material film (4), which contains at least a noble metal, formed on the glass sheet (3); a plated metal film (5) formed on the inorganic material film; and a metal film (6) formed on the plated metal film (5). The laminated film (2) is black when viewed from a glass sheet (3) side.

An article includes a glass or glass-ceramic substrate having a first major surface and a second major surface opposite the first major surface, and at least one via extending through the substrate from the first major surface to the second major surface over an axial length in an axial dimension. The article also includes a metal connector disposed within the via that hermetically seals the via. The article has a helium hermeticity of less than or equal to 1.010.sup.8 atm-cc/s after 1000 thermal shock cycles, each of the thermal shock cycle comprises cooling the article to a temperature of 40 C. and heating the article to a temperature of 125 C., and the article has a helium hermeticity of less than or equal to 1.010.sup.8 atm-cc/s after 100 hours of HAST at a temperature of 130 C. and a relative humidity of 85%.

In accordance with at least one aspect of this disclosure, a thermochromic window can include a first transparent layer, a second transparent layer, and a thermochromic fiber layer sandwiched between the first transparent layer and the second transparent layer. In certain embodiments, the thermochromic fiber layer may be embedded in the second transparent layer. The thermochromic window can be configured to selectively absorb or reflect infrared radiation (IR) as a function of a critical temperature.

Provided is process for producing a surface-metalized fiber, yarn, or fabric, the process comprising: (a) preparing a graphene dispersion comprising multiple graphene sheets and an optional conductive filler dispersed in a first liquid medium, which is an adhesive monomer or contains a liquid adhesive monomer or oligomer dissolved in a solvent; (b) feeding a continuous fiber, yarn, or fabric from a feeder roller into a deposition zone, wherein the graphene dispersion is dispensed to deposit the graphene sheets to a surface of the fiber, yarn, or fabric; (c) moving the graphene-coated fiber, yarn, or fabric into a metallization chamber which accommodates a plating solution therein for plating a layer of a desired metal onto the graphene-coated fiber, yarn, or fabric to obtain a surface-metalized fiber, yarn, or fabric; and (d) operating a winding roller to collect the surface-metalized fiber, yarn, or fabric.

Provided is process for producing a surface-metalized fiber, yarn, or fabric, the process comprising: (a) Feeding a continuous fiber, yarn, or fabric from a feeder roller into a graphene deposition chamber containing therein a graphene dispersion comprising multiple graphene sheets and an optional conducive filler dispersed in a first liquid medium and an optional adhesive resin dissolved in the first liquid medium; (b) Operating the graphene deposition chamber to deposit the graphene sheets and optional conductive filler to a surface of the fiber, yarn, or fabric for forming a graphene-coated fiber, yarn, or fabric; (c) Moving the graphene-coated fiber, yarn, or fabric into a metallization chamber which accommodates a plating solution therein for plating a layer of a desired metal onto the graphene-coated fiber, yarn, or fabric to obtain a surface-metalized fiber, yarn, or fabric; and (d) Operating a winding roller to collect the surface-metalized fiber, yarn, or fabric.