A spray material for hot and dry spray application with improved corrosion resistance, and a hot and dry spray application method with improved corrosion resistance. A hot and dry spray application method comprises pressure-feeding a mixture comprising a refractory material and a binder, toward a spraying nozzle via a pipe, and adding water to the mixture at a distal end of the spraying nozzle to apply a spray under a hot condition. The mixture contains magnesium limestone having a particle size of 0.075 mm to less than 1 mm, in an amount of 10 mass % to 50 mass %, in 100 mass % of a total amount of the refractory material and the binder. The content of magnesium limestone having a particle size of less than 0.075 mm in 100 mass % of the total amount of the refractory material and the binder is 35 mass % or less (including 0).

A spray material for hot and dry spray application with improved corrosion resistance, and a hot and dry spray application method with improved corrosion resistance. A hot and dry spray application method comprises pressure-feeding a mixture comprising a refractory material and a binder, toward a spraying nozzle via a pipe, and adding water to the mixture at a distal end of the spraying nozzle to apply a spray under a hot condition. The mixture contains magnesium limestone having a particle size of 0.075 mm to less than 1 mm, in an amount of 10 mass % to 50 mass %, in 100 mass % of a total amount of the refractory material and the binder. The content of magnesium limestone having a particle size of less than 0.075 mm in 100 mass % of the total amount of the refractory material and the binder is 35 mass % or less (including 0).

This invention relates to an adaptable Geopolymer cement composition for application in oil and gas wells having a wide range of downhole temperatures. The base Geopolymer cement composition has an acceptable rheology of below 200 cP and can be tailored by the inclusion of various chemicals to control properties such as thickening time over a wide range of temperatures and densities. The disclosed Geopolymer cement composition is pumpable, mixable and stable. The composition can also be adapted to have expandable and swellable properties.

This invention relates to an adaptable Geopolymer cement composition for application in oil and gas wells having a wide range of downhole temperatures. The base Geopolymer cement composition has an acceptable rheology of below 200 cP and can be tailored by the inclusion of various chemicals to control properties such as thickening time over a wide range of temperatures and densities. The disclosed Geopolymer cement composition is pumpable, mixable and stable. The composition can also be adapted to have expandable and swellable properties.

Magnesium phosphate cement binder systems and method for providing magnesium phosphate cements are described. In an embodiment, a magnesium phosphate cement binder system may include magnesium oxide that has been calcined at a temperature of between about 900° F. to about 1800° F. The magnesium phosphate cement binder system may also include a phosphate material. Other formulations, compositions, and methods are also described.

Magnesium phosphate cement binder systems and method for providing magnesium phosphate cements are described. In an embodiment, a magnesium phosphate cement binder system may include magnesium oxide that has been calcined at a temperature of between about 900° F. to about 1800° F. The magnesium phosphate cement binder system may also include a phosphate material. Other formulations, compositions, and methods are also described.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

A sulfate-resistant cement composition may contain calcium magnesium aluminum oxide silicate, brownmillerite, dolomite, periclase, and calcium aluminum oxide. The composition may contain the calcium aluminum oxide in an amount in the range of 0.01 to 2.0 wt. %. The composition may contain the brownmillerite in an amount of the range of 20 to 30 wt. %.

A sulfate-resistant cement composition may contain calcium magnesium aluminum oxide silicate, brownmillerite, dolomite, periclase, and calcium aluminum oxide. The composition may contain the calcium aluminum oxide in an amount in the range of 0.01 to 2.0 wt. %. The composition may contain the brownmillerite in an amount of the range of 20 to 30 wt. %.