Methods, compositions, and tools for use in creating rapidly forming plugs in situ in subterranean formations. In one instance, the disclosure provides a method that includes: placing a first pill comprising a calcium-aluminate-based cement composition at a plug location within the wellbore with the tubing; and placing a second pill comprising an alkaline fluid composition into the wellbore adjacent to the first pill with the tubing. In some cases there is a spacer fluid or spacer device between the first pill and the second pill. In some cases tubing having a mixing device is located at the bottom of the tubing in the wellbore to aid I mixing the first pill and the second pill to facilitate a chemical in situ reaction of the first pill and the second pill. The reaction between the first pill and the second pill forms a set plug at the plug location.

Disclosed herein is a method and an apparatus for producing a shaped article. The method comprises obtaining a freshly produced aluminosilicate-containing particulate waste material and, before the waste material cools to ambient temperature, mixing the waste material into a mixture, wherein the mixture comprises the aluminosilicate, a metal oxide, an alkali, a water soluble silicate and water; shaping the mixture; and curing the shaped mixture, whereby the shaped article is produced.

Disclosed herein is a method and an apparatus for producing a shaped article. The method comprises obtaining a freshly produced aluminosilicate-containing particulate waste material and, before the waste material cools to ambient temperature, mixing the waste material into a mixture, wherein the mixture comprises the aluminosilicate, a metal oxide, an alkali, a water soluble silicate and water; shaping the mixture; and curing the shaped mixture, whereby the shaped article is produced.

The invention relates to a process for producing a composite comprising: a. providing a particulate material, wherein the particulate material comprises minerals having a content of at least 30% m/m of calcium, magnesium, aluminium, silicon, potassium or iron, or a combination of two or more thereof. b. providing an aggregate, c. providing a primary additive, wherein the primary additive comprises a sugar or derivative thereof, a polyol or derivative thereof, an organic acid, an organic acid salt or an inorganic acid, or any combination of two or more thereof, d. mixing the particulate material, the aggregate and the primary additive with water to form a mixture, and e. carbonating the mixture in the presence of carbon dioxide, wherein the concentration of carbon dioxide is greater than about 2 vol %.

The invention relates to a process for producing a composite comprising: a. providing a particulate material, wherein the particulate material comprises minerals having a content of at least 30% m/m of calcium, magnesium, aluminium, silicon, potassium or iron, or a combination of two or more thereof. b. providing an aggregate, c. providing a primary additive, wherein the primary additive comprises a sugar or derivative thereof, a polyol or derivative thereof, an organic acid, an organic acid salt or an inorganic acid, or any combination of two or more thereof, d. mixing the particulate material, the aggregate and the primary additive with water to form a mixture, and e. carbonating the mixture in the presence of carbon dioxide, wherein the concentration of carbon dioxide is greater than about 2 vol %.

Disclosed herein is a composition comprising a cementitious material, a pozzolanic material, aplite, and an aqueous fluid. Also disclosed herein is a method of servicing a wellbore penetrating a subterranean formation, comprising: placing the composition into the wellbore; and allowing the composition to form a set cement. The composition can develop suitable mechanical properties and permeability after setting in a wellbore and be expansive.

A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, water and concentration thereof, and, optionally, at least one supplementary cementitious material and a concentration thereof, such that a cement slurry comprising the cement, the water, and, if present, the at least one supplementary cementitious material, meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the selecting comprises selecting different concentrations and/or different chemical identities for the cement and/or the supplementary cementitious material than previously selected, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and preparing the cement slurry.

A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, water and concentration thereof, and, optionally, at least one supplementary cementitious material and a concentration thereof, such that a cement slurry comprising the cement, the water, and, if present, the at least one supplementary cementitious material, meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the selecting comprises selecting different concentrations and/or different chemical identities for the cement and/or the supplementary cementitious material than previously selected, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and preparing the cement slurry.

Disclosed herein is a method of servicing a wellbore penetrating a subterranean formation, comprising: placing a cementitious composition of the type disclosed herein into the wellbore. The cementitious composition comprises a cement blend and water, wherein the cement blend comprises Portland cement and pozzolan, wherein the Portland cement is present in an amount of from equal to or greater than about 0.01 wt. % to equal to or less than about 25.0 wt. % based on the total weight of the cement blend.

Disclosed herein is a method of servicing a wellbore penetrating a subterranean formation, comprising: placing a cementitious composition of the type disclosed herein into the wellbore. The cementitious composition comprises a cement blend and water, wherein the cement blend comprises Portland cement and pozzolan, wherein the Portland cement is present in an amount of from equal to or greater than about 0.01 wt. % to equal to or less than about 25.0 wt. % based on the total weight of the cement blend.