Expansive cements for use in cementing subterranean wells comprise water, an inorganic cement and one or more particulate materials that swell upon contact with a water immiscible fluid. The cements may further comprise a water immiscible fluid. Such cements are designed to seal microannuli arising from the presence of water immiscible fluids on casing surfaces, borehole wall surfaces or both.

An insulation medium invention includes a plurality of microspheres. Each microsphere comprises a porous core comprising a porous core material and having an exterior surface, a gas within the porous core, and a coating layer coating all of the exterior surface of the porous core. The coating layer comprises a coating material which transitions from a first state to a second state. In the first state, the coating material is permeable to the gas. In the second state the material is impermeable to the gas. The coating material in the second state is configured to encapsulate and maintain partial vacuum of the gas inside the porous core. In one embodiment, in the second state the coating is impermeable to air. Insulated structures, a method of making an insulation medium, a fluid storage media, and a method of delivering a fluid are also disclosed.

An insulation medium invention includes a plurality of microspheres. Each microsphere comprises a porous core comprising a porous core material and having an exterior surface, a gas within the porous core, and a coating layer coating all of the exterior surface of the porous core. The coating layer comprises a coating material which transitions from a first state to a second state. In the first state, the coating material is permeable to the gas. In the second state the material is impermeable to the gas. The coating material in the second state is configured to encapsulate and maintain partial vacuum of the gas inside the porous core. In one embodiment, in the second state the coating is impermeable to air. Insulated structures, a method of making an insulation medium, a fluid storage media, and a method of delivering a fluid are also disclosed.

This disclosure provides electron beam irradiated products and methods thereof. In particular, the invention is directed to a products and methods that comprise an electron beam irradiated component and a second component. The electron beam irradiated component may be plastic. The second component may be a building material or construction material. The invention is also directed to methods of manufacturing a modified polymer material with an electron-beam. Methods comprise irradiating the polymer particles of the material by dosing with electron beam radiation to produce a modified polymer material comprising irradiated polymer particles.

This disclosure provides electron beam irradiated products and methods thereof. In particular, the invention is directed to a products and methods that comprise an electron beam irradiated component and a second component. The electron beam irradiated component may be plastic. The second component may be a building material or construction material. The invention is also directed to methods of manufacturing a modified polymer material with an electron-beam. Methods comprise irradiating the polymer particles of the material by dosing with electron beam radiation to produce a modified polymer material comprising irradiated polymer particles.

Methods, compositions, and apparatuses are provided herein that utilize polystyrene from recycled products to make a high strength composite concrete that can be used for subgrade utility vaults, utility trenches, etc. Polystyrene is a widely-used plastic that can be collected and then densified at particular parameters including temperature to transform the polystyrene to a usable form. Then, the densified polystyrene is combined with other resin materials and dry materials to form a high-strength concrete material. The amount of densified polystyrene that is combined with the other materials is critical to control shrinkage and expansion of the concrete material during manufacturing.

Methods, compositions, and apparatuses are provided herein that utilize polystyrene from recycled products to make a high strength composite concrete that can be used for subgrade utility vaults, utility trenches, etc. Polystyrene is a widely-used plastic that can be collected and then densified at particular parameters including temperature to transform the polystyrene to a usable form. Then, the densified polystyrene is combined with other resin materials and dry materials to form a high-strength concrete material. The amount of densified polystyrene that is combined with the other materials is critical to control shrinkage and expansion of the concrete material during manufacturing.

An asphalt composition includes asphalt, a non-epoxidized oil chosen from flux oils, bio oils, recycled motor oils, liquid plasticizers, and combinations thereof, and a polyolefin. The polyolefin has a weight average molecular weight (Mw) of from about 1,000 to about 20,000 g/mol, an optional acid number of from about 10 to about 50 mg KOH/g, an optional saponification number of from about 10 to about 100 mg KOH/g, and a density of from about 0.92 to about 1 g/cm.sup.3. The asphalt composition has a performance grade of PG (52 to 88) and (−22 to −40), wherein (52 to 88) is an average seven day maximum pavement design temperature in degrees Celsius and represents deformation resistance and (−22 to −40) is an average one day minimum pavement design temperature in degrees Celsius and represents thermal cracking resistance, each as determined using AASHTO M320.

An asphalt composition includes asphalt, a non-epoxidized oil chosen from flux oils, bio oils, recycled motor oils, liquid plasticizers, and combinations thereof, and a polyolefin. The polyolefin has a weight average molecular weight (Mw) of from about 1,000 to about 20,000 g/mol, an optional acid number of from about 10 to about 50 mg KOH/g, an optional saponification number of from about 10 to about 100 mg KOH/g, and a density of from about 0.92 to about 1 g/cm.sup.3. The asphalt composition has a performance grade of PG (52 to 88) and (−22 to −40), wherein (52 to 88) is an average seven day maximum pavement design temperature in degrees Celsius and represents deformation resistance and (−22 to −40) is an average one day minimum pavement design temperature in degrees Celsius and represents thermal cracking resistance, each as determined using AASHTO M320.

A filler for production of cement-bound shaped bodies, comprising a material group mixture of comminuted and sorted waste materials, conditioned with chemical reagents/compounds in the presence of water, wherein the material group mixture is composed of comminuted and sorted waste materials, selected from the following material groups: PPK: paper, paperboard, cardboard plastics inert material textiles wood
which are mixed according with a mass-related material group vector and then comminuted.