The present invention relates to a copolymer, especially for use as a dispersant for solid particles, in particular for use as dispersant for mineral binder compositions, having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a gradient structure in at least one section A in a direction along the polymer backbone with regard to the ionizable monomer unit M1 and/or with regard to the side chain-bearing monomer unit M2.

The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.

The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.

The present invention relates to a copolymer, especially for use as a dispersant for solid particles, in particular for use as dispersant for mineral binder compositions, having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a gradient structure in at least one section A in a direction along the polymer backbone with regard to the ionizable monomer unit M1 and/or with regard to the side chain-bearing monomer unit M2.

The invention relates to the use of branched copolymers as dispersants of mineral binders, wherein the copolymers are formed from (1) at least one olefinically unsaturated carboxylic acid monomer (2) at least one olefinically unsaturated macromonomer of the general structure (I)

##STR00001## where R.sup.1 is an olefinically unsaturated radical which has 2-10 carbon atoms and may optionally be substituted by oxygen and/or nitrogen, preferably vinyl, allyl, methallyl, vinyloxybutyl, isoprenyl, acryloyl and/or methacryloyl, X=O or NH, A is in each case independently C1-C10 alkylene, preferably ethylene, propylene and/or butylene, R.sup.2=C1-C16 alkyl, B is in each case independently C1-C10 alkylene, preferably ethylene, propylene and/or butylene, m is in each case independently an integer in the range of 0-350, preferably 2-200, more preferably 5-150, especially 7-30, n is an integer in the range of 0-100, preferably 1-100, more preferably 2-75, most preferably 5-55, p is 0 or 1, preferably 0, o is an integer in the range of 1-50, preferably 3-40, more preferably 6-30, especially 8-20, and q is an integer in the range of 1-10.

The invention relates to the use of branched copolymers as dispersants of mineral binders, wherein the copolymers are formed from (1) at least one olefinically unsaturated carboxylic acid monomer (2) at least one olefinically unsaturated macromonomer of the general structure (I)

##STR00001## where R.sup.1 is an olefinically unsaturated radical which has 2-10 carbon atoms and may optionally be substituted by oxygen and/or nitrogen, preferably vinyl, allyl, methallyl, vinyloxybutyl, isoprenyl, acryloyl and/or methacryloyl, X=O or NH, A is in each case independently C1-C10 alkylene, preferably ethylene, propylene and/or butylene, R.sup.2=C1-C16 alkyl, B is in each case independently C1-C10 alkylene, preferably ethylene, propylene and/or butylene, m is in each case independently an integer in the range of 0-350, preferably 2-200, more preferably 5-150, especially 7-30, n is an integer in the range of 0-100, preferably 1-100, more preferably 2-75, most preferably 5-55, p is 0 or 1, preferably 0, o is an integer in the range of 1-50, preferably 3-40, more preferably 6-30, especially 8-20, and q is an integer in the range of 1-10.

The application describes an admixture comprising a polymer as fluidifier of a cement composition comprising: from 20 to 64 wt. % clinker, from 5 to 60 wt. % activated clay, from 0 to 35 wt. % limestone, from 0 to 10 wt. % calcium sulfate,

the proportions being relative to the dry weight of the cement composition.

The invention relates to a process for producing a composition suitable as accelerator for the curing of cement, by contacting the components aa) at least one component selected from the series of hydraulic binders and/or latent hydraulic binders, and bb) at least one dispersant suitable for the dispersing of inorganic particles in water, and cc) water, the weight ratio of components aa) to cc) being between 1.5:1 and 1:70, wherein the rate ratio of components aa) to bb) is between 20:1 and 1:2. In addition, the use of the composition obtained as hardening acceleration for chemical mixtures in construction is disclosed.

The invention relates to a process for producing a composition suitable as accelerator for the curing of cement, by contacting the components aa) at least one component selected from the series of hydraulic binders and/or latent hydraulic binders, and bb) at least one dispersant suitable for the dispersing of inorganic particles in water, and cc) water, the weight ratio of components aa) to cc) being between 1.5:1 and 1:70, wherein the rate ratio of components aa) to bb) is between 20:1 and 1:2. In addition, the use of the composition obtained as hardening acceleration for chemical mixtures in construction is disclosed.

The present invention relates to admixtures, especially a dispersant for solid particles, in particular a dispersant for mineral binder compositions, comprising: a) a superplasticizer and b) a copolymer having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a nonrandom distribution of the monomer units M1 and/or the monomer units M2 in a direction along the polymer backbone,
and wherein the superplasticizer and the copolymer differ from a chemical and/or structural point of view.