Cement slurries, cured cements, and methods of making cured cement and methods of using cement slurries have, among other attributes, an extended thickening time, leading to improved retardation, flowability, and pumpability and may be used, for instance, in the oil and gas drilling industry. The cement slurry includes water, microfine cement material, and bisphenol-F diglycidyl ether resin.

Curable resin compositions comprising an epoxy resin and a hydrazide curing agent and methods for using the curable resin compositions in cementing and/or remedial operations in a subterranean formation are provided. In one embodiment, the method may comprise combining an epoxy resin and a curing agent to form a curable resin composition, wherein the curing agent comprises a hydrazide curing agent; introducing the curable resin composition into a subterranean formation; and allowing the curable resin composition to at least partially cure.

Curable resin compositions comprising an epoxy resin and a hydrazide curing agent and methods for using the curable resin compositions in cementing and/or remedial operations in a subterranean formation are provided. In one embodiment, the method may comprise combining an epoxy resin and a curing agent to form a curable resin composition, wherein the curing agent comprises a hydrazide curing agent; introducing the curable resin composition into a subterranean formation; and allowing the curable resin composition to at least partially cure.

A method includes introducing a cementing composition into a subterranean formation, the cementing composition including a pumpable slurry of cement including an epoxy resin, an epoxy resin hardening agent, and a compatibilizer, where the compatibilizer is a lignite grafted copolymer; and allowing at least a portion of the cementing composition to harden. A composition includes a pumpable slurry of cement including an epoxy resin, an epoxy resin hardening agent, and a compatibilizer, where the compatibilizer is a lignite grafted copolymer.

A method includes introducing a cementing composition into a subterranean formation, the cementing composition including a pumpable slurry of cement including an epoxy resin, an epoxy resin hardening agent, and a compatibilizer, where the compatibilizer is a lignite grafted copolymer; and allowing at least a portion of the cementing composition to harden. A composition includes a pumpable slurry of cement including an epoxy resin, an epoxy resin hardening agent, and a compatibilizer, where the compatibilizer is a lignite grafted copolymer.

Compositions for a curable substance for fixing purposes, comprising an epoxy component (a), which contains curable epoxides, and a hardener component (b), which comprises a Mannich base formulation, obtainable by reaction of specific amines, and/or mixtures of styrenated phenols with low molecular weight amines, to novel Mannich base formulations or mixtures of styrenated phenols with low molecular weight amines, and to the use of such Mannich base formulations and/or of such mixtures of styrenated phenols with low molecular weight amines, and in each case especially further additional ingredients, especially in hardener components for epoxy resins.

Provided are aqueous resin solutions having unique rheologies and products incorporating the same. The water-based materials provided herein are thermo-thickening, and the materials increase dramatically in viscosity (at least 100 times) in a desired temperature range increase (20 C to <100 C) at ambient pressure. Suitable resins comprising a hydrophobic group and a hydrophilic group may be selected from an epoxy resin, a phenol-formaldehyde resin, a polyurethane resin, an acrylic resin, a polyester resin, an acrylic-urethane resin, a melamine resin, a melamine-formaldehyde resin, an amino resin, and combinations thereof. A specific epoxy functional resin/polymer suitable for the resin solutions are prepared by reacting (A) an epoxy pre-polymer of (1) one or more polyols and (2) one or more epoxy functional materials with (B) a di- or polyamine, thereby forming the aqueous thermo-thickening resin solution. The resin solutions are substantially free of cross-linking agents.

Provided are aqueous resin solutions having unique rheologies and products incorporating the same. The water-based materials provided herein are thermo-thickening, and the materials increase dramatically in viscosity (at least 100 times) in a desired temperature range increase (20 C to <100 C) at ambient pressure. Suitable resins comprising a hydrophobic group and a hydrophilic group may be selected from an epoxy resin, a phenol-formaldehyde resin, a polyurethane resin, an acrylic resin, a polyester resin, an acrylic-urethane resin, a melamine resin, a melamine-formaldehyde resin, an amino resin, and combinations thereof. A specific epoxy functional resin/polymer suitable for the resin solutions are prepared by reacting (A) an epoxy pre-polymer of (1) one or more polyols and (2) one or more epoxy functional materials with (B) a di- or polyamine, thereby forming the aqueous thermo-thickening resin solution. The resin solutions are substantially free of cross-linking agents.

A method of controlling the equivalent circulating density of an epoxy resin, used to cement a wellbore, is provided. The method includes adjusting the cross sectional area of the annulus exit using a valve or other mechanism to increase or decrease the equivalent circulating density of the epoxy resin.

A method of controlling the equivalent circulating density of an epoxy resin, used to cement a wellbore, is provided. The method includes adjusting the cross sectional area of the annulus exit using a valve or other mechanism to increase or decrease the equivalent circulating density of the epoxy resin.