Disclosed is a refractory product for casting of steel, which is capable of forming a dense surface layer which is high in terms of a slag infiltration suppressing ability and strong, in a surface region thereof efficiently or sufficiently or in an optimum state. The refractory product contains 1 mass % or more of free carbon, and 2 mass % to 15 mass % of an aluminum component as metal, with the remainder comprising a refractory material as a main composition, wherein the refractory product has a permeability of 1×10.sup.−16 m.sup.2 to 15×10.sup.−16m.sup.2.

A refractory article includes a body having a first portion defining at least a portion of a first exterior surface of the body, the first portion including a carbide, and further including a second portion defining at least a portion of a second exterior surface of the body opposite the first exterior surface, the second portion including an oxide, and a thermal conductivity difference (ΔTC) of at least 10 W/mK between the first exterior surface and the second exterior surface, and an average Shell Temperature of not greater than 400° C.

A refractory article includes a body having a first portion defining at least a portion of a first exterior surface of the body, the first portion including a carbide, and further including a second portion defining at least a portion of a second exterior surface of the body opposite the first exterior surface, the second portion including an oxide, and a thermal conductivity difference (ΔTC) of at least 10 W/mK between the first exterior surface and the second exterior surface, and an average Shell Temperature of not greater than 400° C.

A plugged honeycomb structure, including: a pillar-shaped honeycomb structure body including porous partition walls; and plugging portions disposed at open ends of cells at an inflow end face side or at an outflow end face side, wherein a pore diameter corresponding to the cumulative pore volume of 10% is D10, a pore diameter corresponding to the cumulative pore volume of 30% is D30, a pore diameter corresponding to the cumulative pore volume of 50% is D50, a pore diameter corresponding to the cumulative pore volume of 70% is D70, a pore diameter corresponding to the cumulative pore volume of 90% is D90, the pore diameter D10 is 6 μm or more, the pore diameter D90 is 58 μm or less, and the plugged honeycomb structure satisfies the relationship of Expression (1).
0.35≤(D70−D30)/D50≤1.5  Expression (1):

A plugged honeycomb structure, including: a pillar-shaped honeycomb structure body including porous partition walls; and plugging portions disposed at open ends of cells at an inflow end face side or at an outflow end face side, wherein a pore diameter corresponding to the cumulative pore volume of 10% is D10, a pore diameter corresponding to the cumulative pore volume of 30% is D30, a pore diameter corresponding to the cumulative pore volume of 50% is D50, a pore diameter corresponding to the cumulative pore volume of 70% is D70, a pore diameter corresponding to the cumulative pore volume of 90% is D90, the pore diameter D10 is 6 μm or more, the pore diameter D90 is 58 μm or less, and the plugged honeycomb structure satisfies the relationship of Expression (1).
0.35≤(D70−D30)/D50≤1.5  Expression (1):

The invention relates to an additive manufacturing method comprising the steps: additive application of a layer of material (1), and modifying a part of the applied material layer (1) in a property so that a partial layer (3) in the material layer (1) is structured, the partial layer (3) differing from the remaining material layer at least in the modified property. The invention also relates to a correspondingly manufactured component and a suitable manufacturing apparatus.

A dry substance mixture for a batch, preferably a refractory batch, for the production of a coarse ceramic, refractory, non-basic, shaped or unshaped product, such a refractory batch, such a product as well as a method for its production and a lining of an industrial furnace for the aluminum industry, and such an industrial furnace as well as a lining of a launder transport system or a mobile transport vessel for the aluminum industry, and such a launder transport system and such a transport vessel.

A refractory composition for forming a working lining in a metallurgical vessel contains a coarse-grain refractory particle fraction and a fine-grain refractory particle fraction, or at least 0.25% additive calcium oxide, or at least 0.25% titanium dioxide. The coarse-grain refractory particles can include alumina particles, magnesia particles, magnesium aluminate spinel particles, zirconia particles, or doloma particles, or a combination of any of these particles. The fine-grain refractory particles can be comprised of any low-magnesia refractory oxide. The refractory composition can be applied to a metallurgical vessel by spraying, gunning, shotcreting, vibrating, casting, troweling, or positioning preformed refractory shapes, or a combination of any of these techniques. When contacted by molten metal, the molten metal penetrates into the refractory material, wetting the coarse-grain refractory particles, and forming a refractory-metal composite barrier layer that decreases or blocks oxygen transport through the refractory lining.

A refractory composition for forming a working lining in a metallurgical vessel contains a coarse-grain refractory particle fraction and a fine-grain refractory particle fraction, or at least 0.25% additive calcium oxide, or at least 0.25% titanium dioxide. The coarse-grain refractory particles can include alumina particles, magnesia particles, magnesium aluminate spinel particles, zirconia particles, or doloma particles, or a combination of any of these particles. The fine-grain refractory particles can be comprised of any low-magnesia refractory oxide. The refractory composition can be applied to a metallurgical vessel by spraying, gunning, shotcreting, vibrating, casting, troweling, or positioning preformed refractory shapes, or a combination of any of these techniques. When contacted by molten metal, the molten metal penetrates into the refractory material, wetting the coarse-grain refractory particles, and forming a refractory-metal composite barrier layer that decreases or blocks oxygen transport through the refractory lining.

The present invention relates to a method for manufacturing at least one monolithic inorganic porous support (1) having a porosity comprised between 10% and 60% and an average pore diameter ranging from 0.5 μm to 50 μm, using a 3D printer type machine (I) to build, in accordance with a 3D digital model, a manipulable three-dimensional raw structure (2) intended to form, after sintering, the monolithic inorganic porous support(s) (1).