A refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.

A refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.

Fused cast refractory product including, as weight percentages on the basis of the oxides and for a total of 100%: ZrO.sub.2: balance to 100%, Hf.sub.2O: <5%, SiO.sub.2: 8.1% to 12.0%, B.sub.2O.sub.3: 0.20% to 0.90%, Na.sub.2O+K.sub.2O: 0.40% to 0.80%, Al.sub.2O.sub.3: 0.3% to 2.0%, Y.sub.2O.sub.3: <2.0%, Fe.sub.2O.sub.3+TiO.sub.2: <0.6%, and other species: <1.5%.

Fused cast refractory product including, as weight percentages on the basis of the oxides and for a total of 100%: ZrO.sub.2: balance to 100%, Hf.sub.2O: <5%, SiO.sub.2: 8.1% to 12.0%, B.sub.2O.sub.3: 0.20% to 0.90%, Na.sub.2O+K.sub.2O: 0.40% to 0.80%, Al.sub.2O.sub.3: 0.3% to 2.0%, Y.sub.2O.sub.3: <2.0%, Fe.sub.2O.sub.3+TiO.sub.2: <0.6%, and other species: <1.5%.

A process for treating a fused refractory product including more than 10% by mass of ZrO.sub.2, or “base product.” The process includes heating at least a portion of the surface of the product, so as to melt ZrO.sub.2 crystals in a superficial region extending to a depth of less than 2000 μm. The process includes cooling the molten superficial region obtained in the preceding step so as to obtain a protective layer.

A process for treating a fused refractory product including more than 10% by mass of ZrO.sub.2, or “base product.” The process includes heating at least a portion of the surface of the product, so as to melt ZrO.sub.2 crystals in a superficial region extending to a depth of less than 2000 μm. The process includes cooling the molten superficial region obtained in the preceding step so as to obtain a protective layer.

A refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.

A refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.

A method for producing a refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.

A method for producing a refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO.sub.2 and/or partially stabilized ZrO.sub.2 and/or fully stabilized ZrO.sub.2, wherein the total content of tetragonal and cubic ZrO.sub.2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.