Disclosed are compositions, methods and processes for fabricating and using a device or other implement including a surface or surfaces having a nanoscale or microscale layer or coating of Si—O—N—P. These coatings and/or layers may be continuous, on the surface or discontinuous (e.g., patterned, grooved), and may be provided on silica surfaces, metal (e.g., titanium), ceramic, and combination/hybrid materials. Methods of producing an implantable device, such as a load-bearing or non-load-bearing device, such as a bone or other structural implant device (load-bearing), are also presented. Craniofacial, osteogenic and disordered bone regeneration (osteoporosis) uses and applications of devices that include at least one surface that is treated to include a nanoscale or microscale layer or coating of Si—O—N—P are also provided. Methods of using the treated and/or coated devices to enhance enhanced vascularization and healing at a treated surface of a device in vivo, is also presented.

A sintered body includes a first hard particle, a second hard particle, and a binder. The first hard particle is an M sialon particle having a coating layer. The M sialon particle is represented by M.sub.xSi.sub.(6−x−z)Al.sub.zO.sub.zN.sub.(8−z) (in the formula, M is a metal containing at least one selected from the group consisting of calcium, strontium, barium, scandium, yttrium, lanthanoid, manganese, iron, cobalt, nickel, copper, and group IV, group V, and group VI elements of the periodic table, and relationships of 0.01≦x≦2, 0.01≦z≦4.2, and 1.79≦(6−x−z)≦5.98 are satisfied). The second hard particle is a cubic boron nitride particle.

A method is disclosed for forming a blended phosphor composition. The method includes the steps of firing precursor compositions that include europium and nitrides of at least calcium, strontium and aluminum, in a refractory metal crucible and in the presence of a gas that precludes the formation of nitride compositions between the nitride starting materials and the refractory metal that forms the crucible. The resulting compositions can include phosphors that convert frequencies in the blue portion of the visible spectrum into frequencies in the red portion of the visible spectrum.

A method is disclosed for forming a blended phosphor composition. The method includes the steps of firing precursor compositions that include europium and nitrides of at least calcium, strontium and aluminum, in a refractory metal crucible and in the presence of a gas that precludes the formation of nitride compositions between the nitride starting materials and the refractory metal that forms the crucible. The resulting compositions can include phosphors that convert frequencies in the blue portion of the visible spectrum into frequencies in the red portion of the visible spectrum.

A ceramic material includes of β-sialon (Si.sub.(6-z)Al.sub.zO.sub.zN.sub.(8-z)), polytype 15R, an intergranular phase, and yttrium. The polytype 15R includes twin grains.

A ceramic material includes of β-sialon (Si.sub.(6-z)Al.sub.zO.sub.zN.sub.(8-z)), polytype 15R, an intergranular phase, and yttrium. The polytype 15R includes twin grains.

An environmental barrier coating system for a turbine component, including an environmental barrier layer applied to a turbine component substrate containing silicon; the environmental barrier layer comprising an oxide matrix surrounding a fiber-reinforcement structure and a self-healing phase interspersed throughout the oxide matrix; wherein the fiber-reinforcement structure comprises at least one first fiber bundle oriented along a load bearing stress direction of said turbine component substrate; wherein the fiber-reinforcement structure comprises at least one second fiber bundle oriented orthogonal to the at least one first fiber bundle orientation; wherein the fiber-reinforcement structure comprises at least one third fiber woven between the at least one first fiber bundle and the at least one second fiber bundle.

An environmental barrier coating system for a turbine component, including an environmental barrier layer applied to a turbine component substrate containing silicon; the environmental barrier layer comprising an oxide matrix surrounding a fiber-reinforcement structure and a self-healing phase interspersed throughout the oxide matrix; wherein the fiber-reinforcement structure comprises at least one first fiber bundle oriented along a load bearing stress direction of said turbine component substrate; wherein the fiber-reinforcement structure comprises at least one second fiber bundle oriented orthogonal to the at least one first fiber bundle orientation; wherein the fiber-reinforcement structure comprises at least one third fiber woven between the at least one first fiber bundle and the at least one second fiber bundle.

Phosphors include a CaAlSiN.sub.3 family crystal phase, wherein the CaAlSiN.sub.3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.

Phosphors include a CaAlSiN.sub.3 family crystal phase, wherein the CaAlSiN.sub.3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.