A method for preparing a palladium-loaded heterojunction composite framework aerogel, including: preparing a hollow tin dioxide (SnO.sub.2) nanofiber; preparing a tetrabutyl titanate-hollow SnO.sub.2 nanofiber mixed solution; preparing a palladium dichloride (PdCl.sub.2) precursor solution; adding the PdCl.sub.2 precursor solution to the tetrabutyl titanate-hollow SnO.sub.2 nanofiber mixed solution to form a heterojunction double-network composite framework gel; and preparing a palladium nanoparticle-loaded heterojunction double-network composite framework aerogel. A method for preparing a hydrogel sensor coated with the palladium-loaded heterojunction composite framework aerogel is also provided herein.

The present invention is a method for obtaining a ceramic slurry for the production of filaments for 3D FDM printing, comprising adding a polysaccharide, a glycol or an ethanolamine as a gelling agent to a suspension of ceramic material in order to produce said ceramic slurry. The invention also comprises the green body obtained from said slurry and the ceramic filament extruded from the green body.

A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.

The invention relates to a method for preparing a composite metal oxide hollow fibre. A certain stoichiometry of composite metal oxide raw material and a polymer binding agent are added to an organic solvent, and mixed mechanically to obtain an evenly dispersed spinning solution having a suitable viscosity. After defoaming treatment, the spinning solution is extruded through a spinneret and, after undergoing a certain dry spinning process, enters an external coagulation bath; during this period, a phase inversion process occurs and composite metal oxide hollow fibre blanks are formed. The blanks are immersed in the external coagulation bath and the organic solvent is displaced; after natural drying, the blanks undergo a heat treatment process; during this period, polymer burn off, in situ reaction, and in situ sintering processes occur to obtain the composite metal oxide hollow fibre.

An alumina fiber aggregate that is formed of alumina short fibers and has been subjected to needling treatment, wherein the alumina short fibers have an average fiber diameter of 6.0 μm or more and 10.0 μm or less and a specific surface area of 0.2 m.sup.2/g or more and 1.0 m.sup.2/g or less, and a residual percentage (%) of high-temperature-cycle opened gap pressure of the alumina fiber aggregate is 45% or more. A value obtained by subtracting twice the standard error of a length-weighted geometric mean diameter of fiber diameters of the alumina short fibers from the length-weighted geometric mean diameter is 6.0 μm or more. A proportion of alumina short fibers having a fiber diameter of more than 10.0 μm is preferably 5.0% or less on a number basis.

A method for predicting a creep fracture behavior of a woven ceramic matrix composite is provided. A fiber axial stress distribution equation is obtained according to a shear lag model, a random matrix cracking model, a fracture mechanical interface debonding criterion and a fiber failure model; a matrix crack spacing equation is obtained according to the random matrix cracking model; an interface debonding length equation is obtained according to the fracture mechanics interface debonding criterion, and an equation of the load bearing relationship between intact fibers and broken fibers and a fiber fracture probability equation are obtained based on an overall load bearing criterion; and at last a creep strain equation of the woven ceramic matrix composite material is obtained, according to the overall load bearing criterion, to predict the creep fracture behavior of the woven ceramic matrix composite material affected by the random load.

Provided herein are nanofibers and processes of preparing nanofibers. In some instances, the nanofibers are metal and/or ceramic nanofibers. In some embodiments, the nanofibers are high quality, high performance nanofibers, highly coherent nanofibers, highly continuous nanofibers, or the like. In some embodiments, the nanofibers have increased coherence, increased length, few voids and/or defects, and/or other advantageous characteristics. In some instances, the nanofibers are produced by electrospinning a fluid stock having a high loading of nanofiber precursor in the fluid stock. In some instances, the fluid stock comprises well mixed and/or uniformly distributed precursor in the fluid stock. In some instances, the fluid stock is converted into a nanofiber comprising few voids, few defects, long or tunable length, and the like.

The present development is a reactor system for the production of nanostructures. The reactor system comprises a conical reactor body designed to maintain an upwardly directed vertical plasma flame and hydrocarbon flame. The reactor system further includes a metal powder feed that feeds into the plasma flame, a cyclone and a dust removal unit. The system is designed to produce up to 100 grams of metal oxide nanomaterials per minute.

The present invention is a method for obtaining a ceramic slurry for the production of filaments for 3D FDM printing, comprising adding a polysaccharide, a glycol or an ethanolamine as a gelling agent to a suspension of ceramic material in order to produce said ceramic slurry. The invention also comprises the green body obtained from said slurry and the ceramic filament extruded from the green body.

Spherical ceramic-glass nanocomposite dielectrics made from ceramics and glasses that are separately pre-milled by mechanical ball milling using selected ball-to-powder weight ratios and combined to form a mixture that is ball milled. A stable liquid suspension of the milled mixture including an added dispersant such as polyacrylic acid to improve uniformity is spray dried through a nozzle and recovered product is annealed. The novel dielectrics have a microstructure where ceramic primary particles are uniformly distributed and fully embedded in a glass matrix. The dielectrics have a mean particle size of about 1-20 um and a sphericity of about 0.8 or higher which are suitable for fabricating multilayer ceramic capacitors for high temperature applications. The novel dielectrics afford decreased sintering temperature, enhanced breakdown strength, lower dielectric lose tangent, and lower costs. Calcium titanate zirconate with manganese-doping-based or barium titanate-based dielectric ceramics and alkali-free borosilicate glass produce superior nanocomposite dielectrics.