The invention relates to a method for manufacturing a composite component of a timepiece or of a jewelry part, the composite component comprising a porous ceramic part and a metallic material filling the pores of said ceramic part, said method comprising the steps of: providing a porous ceramic preform of the component, providing a metallic material, heating the metallic material to a temperature higher than the melting point of the metallic material, filling the pores of the ceramic preform with the molten metallic material, cooling the metallic material and the ceramic preform to obtain a solidified metallic material in the pores of the ceramic preform, and applying finishing treatments to obtain the composite component,

wherein said porous ceramic preform consists essentially of a material selected from the group consisting of Si.sub.3N.sub.4, SiO.sub.2 and mixtures thereof, and said metallic material is selected from the group consisting of gold, platinum, palladium metals and alloys of these metals.

The invention relates also to a composite component of a timepiece or of a jewelry part comprising a porous ceramic part and a metallic material filling the pores of said ceramic part, wherein said porous ceramic part consists essentially of a material selected from the group consisting of Si.sub.3N.sub.4, SO.sub.2 and mixtures thereof, and said metallic material which is selected from the group consisting of gold, platinum, palladium metals and alloys of these metals.

The invention relates to a method for manufacturing a composite component of a timepiece or of a jewelry part, the composite component comprising a porous ceramic part and a metallic material filling the pores of said ceramic part, said method comprising the steps of: providing a porous ceramic preform of the component, providing a metallic material, heating the metallic material to a temperature higher than the melting point of the metallic material, filling the pores of the ceramic preform with the molten metallic material, cooling the metallic material and the ceramic preform to obtain a solidified metallic material in the pores of the ceramic preform, and applying finishing treatments to obtain the composite component,

wherein said porous ceramic preform consists essentially of a material selected from the group consisting of Si.sub.3N.sub.4, SiO.sub.2 and mixtures thereof, and said metallic material is selected from the group consisting of gold, platinum, palladium metals and alloys of these metals.

The invention relates also to a composite component of a timepiece or of a jewelry part comprising a porous ceramic part and a metallic material filling the pores of said ceramic part, wherein said porous ceramic part consists essentially of a material selected from the group consisting of Si.sub.3N.sub.4, SO.sub.2 and mixtures thereof, and said metallic material which is selected from the group consisting of gold, platinum, palladium metals and alloys of these metals.

A method for manufacturing an environmental barrier comprising the steps of coating a rare earth silicate powder with a precursor of a densification agent in order to form a rare earth silicate powder coated with the precursor of the densification agent, thermally spraying the coated powder onto a substrate in order to obtain an at least partially amorphous environmental barrier on the substrate and thermally treating the environmental barrier in order to crystallize and densify the environmental barrier.

A method for manufacturing an environmental barrier comprising the steps of coating a rare earth silicate powder with a precursor of a densification agent in order to form a rare earth silicate powder coated with the precursor of the densification agent, thermally spraying the coated powder onto a substrate in order to obtain an at least partially amorphous environmental barrier on the substrate and thermally treating the environmental barrier in order to crystallize and densify the environmental barrier.

A method of altering a surface of a ceramic matrix composite to aid in nodule removal is described. A fiber preform comprising a framework of ceramic fibers is heated to a temperature at or above a melting temperature of silicon. During the heating, the fiber preform is infiltrated with a molten material comprising silicon. After the infiltration, the fiber preform is cooled, and the infiltrated fiber preform is exposed to a gas comprising nitrogen during cooling. Silicon nitride may be formed by a reaction of free (unreacted) silicon at or near the surface of the infiltrated fiber preform with the nitrogen. Thus, a ceramic matrix composite having a surface configured for easy nodule removal is formed. Any silicon nodules formed on the surface during cooling may be removed without machining or heat treatment.

In some examples, techniques of repairing and/or reinforcing oxide-oxide ceramic matrix composite (CMC) materials using a metallic material. In one example, a method including applying a metallic material at an edge of an oxide-oxide CMC substrate; and heating the metallic material to diffuse the metal material into the oxide-oxide CMC substrate at the edge. In another example, a method including applying a metallic material onto a damaged area of the oxide-oxide CMC; applying a reinforcing phase material onto the damaged area of the oxide-oxide CMC; and heating the metallic material to diffuse the metallic material into the oxide-oxide CMC and attach the reinforcing phase material to the damaged area of the oxide-oxide CMC.

In some examples, techniques of repairing and/or reinforcing oxide-oxide ceramic matrix composite (CMC) materials using a metallic material. In one example, a method including applying a metallic material at an edge of an oxide-oxide CMC substrate; and heating the metallic material to diffuse the metal material into the oxide-oxide CMC substrate at the edge. In another example, a method including applying a metallic material onto a damaged area of the oxide-oxide CMC; applying a reinforcing phase material onto the damaged area of the oxide-oxide CMC; and heating the metallic material to diffuse the metallic material into the oxide-oxide CMC and attach the reinforcing phase material to the damaged area of the oxide-oxide CMC.

The present invention provides a gallium nitride sintered body and a gallium nitride molded article which have high density and low oxygen content without using a special apparatus. According to the first embodiment, a gallium nitride sintered body, which is characterized by having density of 2.5 g/cm.sup.3 to less than 5.0 g/cm.sup.3 and an intensity ratio of the gallium oxide peak of the (002) plane to the gallium nitride peak of the (002) plane of less than 3%, which is determined by X-ray diffraction analysis, can be obtained. According to the second embodiment, a metal gallium-impregnated gallium nitride molded article, which is characterized by comprising a gallium nitride phase and a metal gallium phase that exist as separate phases and having a molar ratio, Ga/(Ga+N), of 55% to 80%, can be obtained.

The present invention provides a gallium nitride sintered body and a gallium nitride molded article which have high density and low oxygen content without using a special apparatus. According to the first embodiment, a gallium nitride sintered body, which is characterized by having density of 2.5 g/cm.sup.3 to less than 5.0 g/cm.sup.3 and an intensity ratio of the gallium oxide peak of the (002) plane to the gallium nitride peak of the (002) plane of less than 3%, which is determined by X-ray diffraction analysis, can be obtained. According to the second embodiment, a metal gallium-impregnated gallium nitride molded article, which is characterized by comprising a gallium nitride phase and a metal gallium phase that exist as separate phases and having a molar ratio, Ga/(Ga+N), of 55% to 80%, can be obtained.

A method of producing a ceramic matrix composite including a protective ceramic coating thereon comprises applying a surface slurry onto an outer surface of an impregnated fiber preform. The surface slurry includes particulate ceramic solids dispersed in a flowable preceramic polymer comprising silicon, and the impregnated fiber preform comprises a framework of ceramic fibers loaded with particulate matter. The flowable preceramic polymer is cured, thereby forming on the outer surface a composite layer comprising a cured preceramic polymer with the particulate ceramic solids dispersed therein. The cured preceramic polymer is then pyrolyzed to form a porous ceramic layer comprising silicon carbide, and the impregnated fiber preform and the porous ceramic layer are infiltrated with a molten material comprising silicon. After infiltration, the molten material is cooled to form a ceramic matrix composite body with a protective ceramic coating thereon.