The present invention relates to a method for producing ceramic gas-separation membranes, which comprises depositing, by means of inkjet printing, water-based inks that form layers of a gas separation membrane. More specifically, the method comprises at least the following steps forming a porous support (i) compatible with a functional separation layer; depositing on the support (i), by means of inkjet printing, at least one functional separation layer (ii) formed by at least two inks, and depositing at least one porous catalytic activation layer (iii) on the functional separation layer (ii); and performing at least one heat treatment, which produces sintering. The functional separation layer (ii) is deposited in a manner to produce a surface with fadings, patterns, or combinations thereof he invention also relates to a gas separation membrane produced using the described method.

The present invention relates to a method for producing ceramic gas-separation membranes, which comprises depositing, by means of inkjet printing, water-based inks that form layers of a gas separation membrane. More specifically, the method comprises at least the following steps forming a porous support (i) compatible with a functional separation layer; depositing on the support (i), by means of inkjet printing, at least one functional separation layer (ii) formed by at least two inks, and depositing at least one porous catalytic activation layer (iii) on the functional separation layer (ii); and performing at least one heat treatment, which produces sintering. The functional separation layer (ii) is deposited in a manner to produce a surface with fadings, patterns, or combinations thereof he invention also relates to a gas separation membrane produced using the described method.

An environmental barrier coating, comprising a substrate containing silicon; an environmental barrier layer applied to said substrate; said environmental barrier layer comprising a rare earth composition.

An environmental barrier coating, comprising a substrate containing silicon; an environmental barrier layer applied to said substrate; said environmental barrier layer comprising a rare earth composition.

A coating method includes depositing a slurry including a coarsely particulate ceramic and a finely particulate ceramic on a base material configured with an oxide-based ceramics matrix composite such that a proportion of coarse particles decreases towards a surface of the base material; forming a bond coating by performing a heat treatment on the base material on which the slurry has been deposited; and forming a top coating by thermally spraying a ceramic onto the bond coating. The oxide-based ceramics matrix composite is an alumina silica type oxide-based ceramics matrix composite. The coarsely particulate ceramic and the finely particulate ceramic are alumina-based powder.

A coating method includes depositing a slurry including a coarsely particulate ceramic and a finely particulate ceramic on a base material configured with an oxide-based ceramics matrix composite such that a proportion of coarse particles decreases towards a surface of the base material; forming a bond coating by performing a heat treatment on the base material on which the slurry has been deposited; and forming a top coating by thermally spraying a ceramic onto the bond coating. The oxide-based ceramics matrix composite is an alumina silica type oxide-based ceramics matrix composite. The coarsely particulate ceramic and the finely particulate ceramic are alumina-based powder.

Methods of forming sintered coatings are provided, along with the resulting coatings on a substrate. The sintered coating may comprise a rare earth compound and a sintering aid, with the rare earth compound has the formula: A.sub.1−bB.sub.bZ.sub.1−dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to about 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to about 0.5; and M is Ta, Nb, or a mixture thereof. The coating may be densified at a sintering temperature, such as 1300° C. to 1600° C.

Methods of forming sintered coatings are provided, along with the resulting coatings on a substrate. The sintered coating may comprise a rare earth compound and a sintering aid, with the rare earth compound has the formula: A.sub.1−bB.sub.bZ.sub.1−dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to about 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to about 0.5; and M is Ta, Nb, or a mixture thereof. The coating may be densified at a sintering temperature, such as 1300° C. to 1600° C.

Methods for forming a coating on a surface of a substrate are provided. The method can include: preheating the surface of the substrate; spraying a slurry suspension onto the surface of the substrate to form a coating, wherein the slurry composition comprises a rare earth compound, a sintering agent, and a solvent, wherein the rare earth compound has the formula: A.sub.1-bB.sub.bZ.sub.1-dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to 0.5; and M is Ta, Nb, or a mixture thereof; and thereafter, heat treating the coating to densify the coating from an initial porosity to a sintered porosity.

Methods for forming a coating on a surface of a substrate are provided. The method can include: preheating the surface of the substrate; spraying a slurry suspension onto the surface of the substrate to form a coating, wherein the slurry composition comprises a rare earth compound, a sintering agent, and a solvent, wherein the rare earth compound has the formula: A.sub.1-bB.sub.bZ.sub.1-dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to 0.5; and M is Ta, Nb, or a mixture thereof; and thereafter, heat treating the coating to densify the coating from an initial porosity to a sintered porosity.