Environmental barrier coatings including a bondcoat layer including silicon and a rare earth silicate-based hermetic layer and rare earth silicate-based non-hermetic layer are provided. The rare earth silicate-based hermetic layer is deposited on the bondcoat via a thermal spray process and has an elastic modulus ranging from 100 GPa to 180 GPa. The at least one rare earth silicate-based non-hermetic layer is deposited on the rare earth silicate-based hermetic layer and has an elastic modulus ranging from 50 GPa to 100 GPa. Coated gas turbine engine components and methods for coating gas turbine engine components are also provided.

A method for manufacturing an item (1) comprising a through-decoration (2) forming a so-called backlit plique--jour enamel, the method including obtaining a blank (5); removing part of the blank (5) from the inner face (5b) of the blank (5) to produce a decoration (2a) that does not pass through to the outer face (5a); depositing, from the inner face (5b), one or more layers of enamel (3) within the non-through decoration (2a); depositing, from the inner face (5b), a layer of luminescent material (4) on the enamel (3); depositing a protective layer (6) on the layer of luminescent material (4); and machining the outer face (5a) to reveal the enamel. Also, the related item.

A method for manufacturing an item (1) comprising a through-decoration (2) forming a so-called backlit plique--jour enamel, the method including obtaining a blank (5); removing part of the blank (5) from the inner face (5b) of the blank (5) to produce a decoration (2a) that does not pass through to the outer face (5a); depositing, from the inner face (5b), one or more layers of enamel (3) within the non-through decoration (2a); depositing, from the inner face (5b), a layer of luminescent material (4) on the enamel (3); depositing a protective layer (6) on the layer of luminescent material (4); and machining the outer face (5a) to reveal the enamel. Also, the related item.

A method for manufacturing an item (1) including a through-decoration (2) filled with an enamel (3) to form a plique--jour enamel. The method includes: obtaining a blank (5) defined with an upper face (5a) and a lower face (5b) opposite the upper face (5a); removing part of the blank (5) from the upper face (5a) to produce a decoration (2a) that does not pass through to the lower face (5b) or, alternatively, in the previous step, obtaining said blank (5) directly with the non-through decoration (2a); depositing one or more layers of enamel (3) within the non-through decoration (2a) and firing the enamel (3) after each 10 layer has been deposited; machining, preferably by grinding, the lower face (5b) to reveal the enamel (3) and thus produce the item (1) with the through-decoration (2) filled with enamel (3).

A method for manufacturing an item (1) including a through-decoration (2) filled with an enamel (3) to form a plique--jour enamel. The method includes: obtaining a blank (5) defined with an upper face (5a) and a lower face (5b) opposite the upper face (5a); removing part of the blank (5) from the upper face (5a) to produce a decoration (2a) that does not pass through to the lower face (5b) or, alternatively, in the previous step, obtaining said blank (5) directly with the non-through decoration (2a); depositing one or more layers of enamel (3) within the non-through decoration (2a) and firing the enamel (3) after each 10 layer has been deposited; machining, preferably by grinding, the lower face (5b) to reveal the enamel (3) and thus produce the item (1) with the through-decoration (2) filled with enamel (3).

An object of the present invention is to provide a cubic boron nitride sintered body and a coated cubic boron nitride sintered body that can extend the tool life by having excellent wear resistance and fracture resistance. A cubic boron nitride sintered body including cubic boron nitride and a binder phase, wherein in a cross-sectional structure, content ratios of the cubic boron nitride and the binder phase fall within specific ranges, the binder phase includes a Ti compound phase containing a specific compound, an Al compound phase containing a specific compound, and a W compound phase containing WC, an average grain size of the W compound phase is 0.5 m or more and 3.0 m or less, content ratios of the Ti compound phase and the Al compound phase based on a whole of the binder phase fall within specific ranges, a content ratio X1 of the W compound phase is 2.0 area % or more and 30.0 area % or less, a content ratio X2 of the W compound phase based on a whole of the binder phase in a range from an interface between the cubic boron nitride and the binder phase to a distance of 300 nm toward the binder phase side is larger than the content ratio X1.

An object of the present invention is to provide a cubic boron nitride sintered body and a coated cubic boron nitride sintered body that can extend the tool life by having excellent wear resistance and fracture resistance. A cubic boron nitride sintered body including cubic boron nitride and a binder phase, wherein in a cross-sectional structure, content ratios of the cubic boron nitride and the binder phase fall within specific ranges, the binder phase includes a Ti compound phase containing a specific compound, an Al compound phase containing a specific compound, and a W compound phase containing WC, an average grain size of the W compound phase is 0.5 m or more and 3.0 m or less, content ratios of the Ti compound phase and the Al compound phase based on a whole of the binder phase fall within specific ranges, a content ratio X1 of the W compound phase is 2.0 area % or more and 30.0 area % or less, a content ratio X2 of the W compound phase based on a whole of the binder phase in a range from an interface between the cubic boron nitride and the binder phase to a distance of 300 nm toward the binder phase side is larger than the content ratio X1.

A method includes forming a crystallized metal carbide undercoat on a surface of a carbon-carbon composite substrate. The method further includes forming an overcoat on a surface of the undercoat. The overcoat includes a plurality of crystallized ultra-high melting point overcoat layers. Each overcoat layer is sequentially formed by applying a mixture to a surface of an underlying layer and heating the mixture. The mixture includes a plurality of ultra-high melting point refractory ceramic particles and a pre-ceramic polymer. The mixture is heated to a heat treatment temperature to pyrolyze the pre-ceramic polymer and form the overcoat layer in an inert atmosphere or under vacuum. As a result, the overcoat layer includes a crystallized ultra-high melting point polymer-derived ceramic matrix that includes the plurality of ultra-high melting point refractory ceramic particles.

A method includes forming a crystallized metal carbide undercoat on a surface of a carbon-carbon composite substrate. The method further includes forming an overcoat on a surface of the undercoat. The overcoat includes a plurality of crystallized ultra-high melting point overcoat layers. Each overcoat layer is sequentially formed by applying a mixture to a surface of an underlying layer and heating the mixture. The mixture includes a plurality of ultra-high melting point refractory ceramic particles and a pre-ceramic polymer. The mixture is heated to a heat treatment temperature to pyrolyze the pre-ceramic polymer and form the overcoat layer in an inert atmosphere or under vacuum. As a result, the overcoat layer includes a crystallized ultra-high melting point polymer-derived ceramic matrix that includes the plurality of ultra-high melting point refractory ceramic particles.

A CMAS resistant overlay coating including at least one CMAS resistant layer, wherein the overlay coating is i. disposed over a surface of a substrate including a material susceptible to CMAS corrosion, ii. includes a metal oxide matrix and iii. has at least partially a vertical columnar structure. Moreover, at least one non-oxidized metallic constituent selected from the group of aluminum, chromium and metallic constituents including aluminum and chromium is embedded in the metal oxide matrix. Furthermore, a substrate has a CMAS resistant overlay coating at issue on a surface of a material susceptible to CMAS corrosion. A CAE process is provided for forming such a CMAS resistant overlay coating on a surface of a material susceptible to CMAS corrosion.