The present invention relates to a process for preparing a decorative fired substrate such as ceramic, glass, brick, metal or metal enamel. The process includes a step of digitally applying a primer ink composition comprising a metal or metalloid ion component dissolved in a liquid matrix on selective locations of the substrate. The primer ink composition can be applied before or after the application of a color ink. By applying a primer ink composition, the color of the substrate is improved after the substrate is fired, and the manufacture cost is reduced compared with current industrial decorative ceramic tile processes.

The present invention relates to a process for preparing a decorative fired substrate such as ceramic, glass, brick, metal or metal enamel. The process includes a step of digitally applying a primer ink composition comprising a metal or metalloid ion component dissolved in a liquid matrix on selective locations of the substrate. The primer ink composition can be applied before or after the application of a color ink. By applying a primer ink composition, the color of the substrate is improved after the substrate is fired, and the manufacture cost is reduced compared with current industrial decorative ceramic tile processes.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of non-radioactive nuclear waste; swarf, insoluble hydroxide of carbonate salts, radioactive wastes, petroleum coke, spent solvent wastes, electroporating and other metal finishing wastes, dioxin-bearing wastes, chlorinated aliphatic hydrocarbons production, wood preserving wastes, petroleum refinery wastewater treatment sludges, multisource leachate, organic chemicals manufacturing waste, pesticide manufacturing waste, petroleum refining waste, human pharmaceuticals manufacturing waste; veterinary pharmaceuticals manufacturing waste; inorganic pigment manufacturing waste; inorganic chemicals manufacturing waste; explosives manufacturing waste; iron and/or steel production waste; primary aluminum production waste; secondary lead processing waste; ink formulation waste; coking waste; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mill.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of non-radioactive nuclear waste; swarf, insoluble hydroxide of carbonate salts, radioactive wastes, petroleum coke, spent solvent wastes, electroporating and other metal finishing wastes, dioxin-bearing wastes, chlorinated aliphatic hydrocarbons production, wood preserving wastes, petroleum refinery wastewater treatment sludges, multisource leachate, organic chemicals manufacturing waste, pesticide manufacturing waste, petroleum refining waste, human pharmaceuticals manufacturing waste; veterinary pharmaceuticals manufacturing waste; inorganic pigment manufacturing waste; inorganic chemicals manufacturing waste; explosives manufacturing waste; iron and/or steel production waste; primary aluminum production waste; secondary lead processing waste; ink formulation waste; coking waste; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mill.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of calcareous sludge; paper pulp, biomass flyash; bag house dust; biomass sludge; filter cakes from bio industry's and wastewater treatment; bio ash; biomedical ash; agricultural ash; sugar cane bagasse; rice husk ash; palm oil fuel ash; oxygen furnace slags; plant stalks; bio char; starch; pyrophyllite; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mixer.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of calcareous sludge; paper pulp, biomass flyash; bag house dust; biomass sludge; filter cakes from bio industry's and wastewater treatment; bio ash; biomedical ash; agricultural ash; sugar cane bagasse; rice husk ash; palm oil fuel ash; oxygen furnace slags; plant stalks; bio char; starch; pyrophyllite; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mixer.

A soluble alkali metal compound for adjusting, in particular reducing, the viscosity of an aluminum sulfate suspension, the alkali metal being selected from among sodium, potassium and/or lithium.

A soluble alkali metal compound for adjusting, in particular reducing, the viscosity of an aluminum sulfate suspension, the alkali metal being selected from among sodium, potassium and/or lithium.

A porous refractory in the K.sub.2OSiO.sub.2B.sub.2O.sub.3 system is formed by chemical direct foaming by heating to over 600 C., resulting in adherent black or white foam. The foam can function as highly porous thermal insulation, a high or low thermal emissivity surface, as a sealant for deteriorated refractory surfaces, as a filler for pockmarks/holes/gaps or as a bonding agent for parts with large gaps between them.

A porous refractory in the K.sub.2OSiO.sub.2B.sub.2O.sub.3 system is formed by chemical direct foaming by heating to over 600 C., resulting in adherent black or white foam. The foam can function as highly porous thermal insulation, a high or low thermal emissivity surface, as a sealant for deteriorated refractory surfaces, as a filler for pockmarks/holes/gaps or as a bonding agent for parts with large gaps between them.