Disclosed is to a calcium aluminate cement, including a calcium aluminate with a first crystallised mineralogical phase of calcium dialuminate CA2 including one calcium oxide CaO for two aluminium oxides Al.sub.2O.sub.3 and/or a second crystallised mineralogical phase of dicalcium alumina silicate C2AS including two calcium oxides CaO for one aluminium oxide Al.sub.2O.sub.3 and one silicon dioxide SiO.sub.2. The mass fraction of all of the first and second mineralogical phases in the calcium aluminate is greater than or equal to 80%.

The present invention is a granular material that can be well recoated regardless of the type of the granular material, and enables a refractory aggregate in an unprinted portion to be used without any regeneration process, in the manufacture of a three-dimensional laminated and shaped mold. This granular material is a granular material for use in three-dimensional laminated mold shaping, and obtained by adding a material that causes a hydration reaction having a moisture absorbing function and generates a catalytic effect to a coating material mixed with or coated with an acid as a catalyst which activates and hardens an organic binder for binding the granular material.

The invention relates to a new concrete admixture based on metal silicate hydrates and ettringite for improving the strength development at both early and longer ages of low-carbon cementitious compositions based on Portland cement and supplementary cementitious materials SCMs, including fly ash, slag, natural pozzolans, silica fume, calcined clays and fillers, such as limestone powder.

[A] curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant and at least one second accelerant, the at least one second accelerant is different than the at least one first accelerant, wherein a proportion by weight of the at least one second accelerant is equal to or less than 2% of a proportion of magnesium oxide by weight of the mixture. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.

A coated article (20;60) includes a substrate (22) and a coating (24;62) on the substrate. The coating includes at least a first layer (30). The first layer has: a matrix (50); and a filler (52) at 2.0% to 40% by volume in the first layer. The first layer is selected from alkaline earth or transition metal (M) tungstates (MWO4); alkaline earth molybdates (MMoO.sub.4); rare earth (RE) phosphates (REPO.sub.4); and combinations thereof.

A coated article (20;60) includes a substrate (22) and a coating (24;62) on the substrate. The coating includes at least a first layer (30). The first layer has: a matrix (50); and a filler (52) at 2.0% to 40% by volume in the first layer. The first layer is selected from alkaline earth or transition metal (M) tungstates (MWO4); alkaline earth molybdates (MMoO.sub.4); rare earth (RE) phosphates (REPO.sub.4); and combinations thereof.

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).

An article has a substrate and a layer atop the substrate. The layer has: a matrix comprising at least one of hafnium silicate (HfSiO.sub.4) and ytterbium disilicate (Yb.sub.2Si.sub.2O.sub.7); and barium magnesium alumino silicate (BMAS).