The current invention relates to the use of chitin nanocrystals and chitin nanocrystal derivatives. More specifically, the present invention relates to the use of chitin nanocrystals and chitin nanocrystals used in oil and gas operations. The chitin nanocrystals and chitin nanocrystals derivatives can be used as additives to cement and wellbore fluids and can be used to inhibit corrosion in pipelines, on downhole tools and on other oil and gas related equipment.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; nano-reinforcement particle such as single-wall carbon nanotubes or multi-wall carbon nanotubes; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, nano-reinforcement articles such as single-wall carbon nanotubes or multi-wall carbon nanotubes, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; nano-reinforcement particle such as single-wall carbon nanotubes or multi-wall carbon nanotubes; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, nano-reinforcement articles such as single-wall carbon nanotubes or multi-wall carbon nanotubes, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.

A cement slurry composition, containing hydraulic cement, water, and from 1 to less than 4% of an organically modified nanoclay. A method for cementing a high pressure high temperature well by pumping the cement composition of claim 1 between a casing and a formation of a well bore to fill a gap between the casing and the formation, and allowing the cement to harden.

Fluid loss control additives for a cement slurry are provided. An exemplary fluid loss control additive includes a copolymer containing 2-acrylamido-2-methylpropane sulfonic acid monomer units and acryloylmorpholine monomer units, and a graft copolymer. The graft copolymer contains a humate and, grafted onto the humate, a side-chain polymer containing at least one of acrylamide monomer units, acryloylmorpholine monomer units, acrylic acid monomer units, and 2-acrylamido-2-methylpropane sulfonic acid monomer units.

The invention provides a carbon dioxide-resistant hydraulic cement composition. The inventive composition comprises a Portland cement, Class C fly ash and water. The Class C fly ash is present in the composition in an amount in the range of from about 5% to less than about 30% by weight based on the total weight of the cementitious components in the composition. In another aspect, the invention provides a method of cementing in a carbon dioxide environment. In yet another aspect, the invention provides a method of enhancing the recovery of a hydrocarbon fluid from a subterranean formation.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.

A method of cementing a subterranean formation includes forming a cement composition comprising cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant; and pozzolanic material; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. A method of making a cement composition includes combining cementitious material, an aqueous base fluid, a nano-reinforcement particle suspension comprising a surfactant, and a pozzolanic material, where the rate of hydration of the surfaces of the cementitious material is less retarded by the surfactant than an equivalent cement composition without pozzolanic material.