Patent classifications
C04B2103/006
Phosphorylated polycondensate as high efficiency water reducing agent and preparation method thereof
The present invention discloses a phosphorylated polycondensate high-performance water-reducing agent with a phosphorylated melamine derivative, instead of a conventional carboxyl group or sulfonic group, as a main adsorption group. The use of aryl alkoxypolyether as a side chain of the polymer provides a strong steric effect to improve the dispersibility and dispersion-retaining properties of the polymer. A polycondensate high-performance water-reducing agent and a method for preparing the same provided by the present invention have excellent overall performance, high adaptability for current low-grade raw materials of concrete, strong market demands, and vast application prospects. Additionally, the polycondensate has an advanced preparation process provided with the characteristics of industrially scalable production, which offers the prospect of a core technology in the field of water-reducing agent of concrete so as to promote development of the industry.
COMPOSITION CONTAINING A SEMI-ORDERED CALCIUM SILICATE HYDRATE
A curing accelerator composition for building chemical mixtures comprises a mineral constituent and a polymeric water-soluble dispersant. The mineral constituent comprises a semi-ordered calcium silicate hydrate having an apparent crystallite size of 15 nm or less and less than 35% by weight of crystalline phases other than the semi-ordered calcium silicate hydrate. The composition displays a more pronounced accelerating effect than comparative compositions in which the mineral component comprises a calcium silicate hydrate having a higher degree of crystallinity.
PREPARATION METHOD OF TEMPERATURE/PH-RESPONSIVE POLYCARBOXYLIC ACID
A preparation method of comb structure temperature/pH-responsive polycarboxylic acid adopts acrylic ester, temperature/pH-responsive monomer and other raw materials to obtain polycarboxylic acid via acrylate monomer self-polymerization, grafting with temperature/pH-responsive monomers and hydrolyzation. In other words, acrylate is used as the reaction monomer to polymerize polyacrylate with controllable molecular weight under the action of initiator and chain transfer agent, then the graft copolymers are copolymerized with temperature/pH-responsive monomers to obtain graft copolymers with acrylate polymers main chain and temperature/pH-responsive polymer side chains. Finally, the graft copolymer is hydrolyzed to obtain the comb structure temperature/pH-responsive polycarboxylic acid with polyacrylic acid main chain and temperature/pH-responsive monomer side chain.
Additive containing a superplasticizer and a copolymer
The present invention relates to admixtures, especially a dispersant for solid particles, in particular a dispersant for mineral binder compositions, comprising: a) a superplasticizer and b) a copolymer having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a nonrandom distribution of the monomer units M1 and/or the monomer units M2 in a direction along the polymer backbone, and wherein the superplasticizer and the copolymer differ from a chemical and/or structural point of view.
Additive containing a superplasticizer and a copolymer
The present invention relates to admixtures, especially a dispersant for solid particles, in particular a dispersant for mineral binder compositions, comprising: a) a superplasticizer and b) a copolymer having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a nonrandom distribution of the monomer units M1 and/or the monomer units M2 in a direction along the polymer backbone, and wherein the superplasticizer and the copolymer differ from a chemical and/or structural point of view.
POLYELECTROLYTE-LAYER FORMING BLOCK COPOLYMERS AND COMPOSITIONS AND USES THEREOF
The present invention relates generally to polyelectrolyte-layer forming block copolymers adsorbed at colloid interfaces in aqua solution and compositions and uses thereof. In particular, the present invention relates to agricultural material compositions comprising particles of at least one agricultural material and a polyelectrolyte-layer forming block copolymer. The present invention also relates to non-agricultural material compositions comprising particles of at least one non-agricultural material and a polyelectrolyte-layer forming block co-polymer.
Method for Controlling Clay Impurities in Construction Aggregates and Cementitious Compositions
The present invention provides a method for treating clay-bearing aggregates, particularly those used for construction purposes, which involve introducing to clay-bearing aggregates an ion-exchanged polycondensate of dialkylamine and epichlorohydrin having anionic groups comprising both acetate and chloride ionic groups, wherein the acetate is present in an amount of 51-99 percent, and more preferably in the amount of 60-95 percent, based on molar concentration of the anionic groups, whereby chloride ionic groups are minimally present.
ADMIXTURE FOR HYDRAULIC COMPOSITION
An admixture for a hydraulic composition includes a polycondensation product P containing a copolymer prepared by polycondensation of a monomer mixture containing compounds A to C of the following Formulae (A) to (C); and a polycarboxylic acid-based polymer Q including a structural unit having an amino and an imino group, and/or a structural unit having an amino, imino, and amido group:
##STR00001## (wherein R.sub.1 is a hydrogen atom, alkyl, or alkenyl group; A.sub.1O is a C.sub.2-4 alkylene oxide group; p is a number of 1 to 300; and X is a hydrogen atom, an alkyl, or acyl group; R.sub.2 is an alkyl or alkenyl group; A.sub.2O is a C.sub.2-4 alkylene oxide group; q is a number of 1 to 300; and Y.sub.1 is a phosphate ester group; and R.sub.3 is a hydrogen atom, carboxy, alkyl, alkenyl, phenyl, naphthyl, or heterocyclic group; and r is a number of 1 to 100).
Controllable High Flow Concrete
The present invention relates to very high workable yet controllable concrete mix design, admixture composition, and process for placing concrete. The mix design relates to particular aggregate/cement ratios and types which are characteristic of ready mix concrete (RMC), which provide high fluidity reminiscent of self-consolidating concrete (SCC), and which provides advantages over both RMC and SCC in terms of ease and speed in placement and finishability at the construction site placement zone, regardless of whether into a horizontal formwork (e.g., for slabs, floors) or into vertical formwork (e.g., for blocks, walls, columns, etc.), without loss of control and without generating high risks of segregation even when small amounts of water are added at the size to facilitate finishing of the concrete surface. An inventive admixture combination which enables this unique design involves two different polycarboxylate comb polymers in combination with two specific viscosity modifying agents, and this combination provides highly workable concrete to be placed in a controlled, efficient manner.
Use of comb polymers for controlling the rheology of mineral binder compositions
A comb polymer is used for increasing the flow rate and/or reducing the viscosity of a mineral binder composition, where the comb polymer has a main chain including acid groups and there are pendent chains linked to the main chain, and where the average number-average molar mass of all of the pendent chains is from 120 to 1000 g/mol and the molar ratio of the acid groups to the side chains is in the range from 0.5 to 2.