Compositions and methods for making biocompatible articles are provided. A method includes preparing a 3D printable mixture and depositing successive layers of the mixture in a predetermined pattern to form a porous biocompatible article. The predetermined pattern has a porosity suitable for a bone or cartilage scaffold. Associated 3D printable compositions and porous articles made from the described methods are also described. The preparing a 3D printable mixture can comprise conjugating an alkyne-terminated polymer to a peptide to form a peptide-containing composite, or providing a mixture that comprises a ceramic material and a binder, and wherein the 3D printable mixture comprises from 50 wt. % to 80 wt. % of the ceramic material.

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

Methods and apparatuses for additive manufacturing are described. A method for additive manufacturing may include exposing a layer of material on a build surface to one or more projections of laser energy including at least one line laser having a substantially linear shape. The intensity of the line laser may be modulated so as to cause fusion of the layer of material according to a desired pattern as the one or more projections of laser energy are scanned across the build surface.

The present invention relates to a method for additive manufacturing of a position sensitive colored ceramic article comprising: a) providing at least one flowable ceramic component; b) forming a green body by sequential deposition of the ceramic component provided in step a) and optionally a support material not intended to be part of the final article; c) position sensitive application of a coloring substance in a solvent to at least a part of the surface of the green body formed in step b), wherein the coloring substance is applied simultaneously to the sequential deposition; d) heat treatment or curing of at least a part of the green body surface obtained in step c); wherein the method steps a)-d) are at least performed once; e) optionally removing the support material from the green body; and f) sintering the green body to obtain the ceramic article; wherein the coloring substance is a dyestuff according to ISO 18451-1:2019(E). In addition, the present invention relates to a system adapted to perform the method and a control data set configured, when implemented in an additive manufacturing system, to cause the system to execute the steps of the inventive method.

A three-dimensional (3D) printing device presented in this invention has a novel printing head design that can be used with a cost-effective 3D printing ink based on cost-competitive camphene solvent utilizing its burning-free, room-temperature solidifying and sublimating properties for 3D printing purposes. The unique combination of the new printing head with pressured air control and the invented ink allows for a mass-production of complex metallic components and parts with a variety of compositions for use in advanced manufacturing in a highly cost-effective way.

A method for forming a complex shape three-dimensional ceramic article by printing a first layer of a first material having a first fraction of first ceramic particles and a first fraction of a first polymeric ceramic precursor. A second layer is printed such that it is at least partially disposed on the first layer of a second material having a second fraction of second ceramic particles and a second fraction of a second polymeric ceramic precursor. A composite of the first layer and the second layer is heated at a temperature sufficient to decompose the first and second polymeric ceramic precursors and sinter the article. During the sintering process, the first and second layers with different fractions of ceramic particles undergo different degrees of shrinkage, resulting in a tuneable mismatch of the bilayer structure and accurately achieving a targeted geometry.

Techniques are disclosed for fabricating multi-part assemblies. In particular, by forming release layers between features such as bearings or gear teeth, complex mechanical assemblies can be fabricated in a single additive manufacturing process.

A feedstock for a 3D manufacturing process, in particular a Fused Filament Fabrication process. The feedstock includes (P) sinterable particles made of a metal, metal alloy, glass, ceramic material, or a mixture thereof; and (B) a binder composition including (b1) 5-15% by weight, relative to the total weight of the binder composition, of a polymeric compatibilizer, and (b2) 85-95% by weight, relative to the total weight of the binder composition, of a polymeric binder component, the polymeric binder component being selected from the group consisting of (b2-1) a polymer mixture or polymer alloy, the mixture or alloy including at least a first and a second polymer; (b2-2) one, two or more block copolymers, including at least a first polymer block and second polymer block; and (b2-3) mixtures of (b2-1) and (b2-2), wherein the amount of sinterable particles P is 40 Vol % or more of the composition.

The present invention relates to a suspension comprising 50-95% by weight of the total suspension (w/w) of at least one metallic material and/or ceramic material and/or polymeric material and/or solid carbon containing material; and at least 5% by weight of the total suspension of one or more fatty acids or derivatives thereof. In addition, the invention relates to uses of such suspension in 3D printing processes.

A powder production method includes providing an elongated workpiece and repeatedly contacting an outer surface of the elongated workpiece with a reciprocating cutter according to a predetermined at least one frequency to produce a powder. The powder includes a plurality of particles, wherein at least 95% of the produced particles have a diameter or maximum dimension ranging from about 10 μm to about 200 μm. A system for producing powders having a plurality of particles including a cutter and at least one controller is also provided herein.