According to a method set forth herein a plurality of preform plies having first and second preform plies can be associated together to define a preform. The preform can be subject to chemical vapor infiltration (CVI) processing to define a ceramic matrix composite (CMC) structure.

A sensor element of a gas sensor includes: an element base which is a ceramic structured body including a detection part of detecting a target measurement gas component; and a protective layer which is a porous layer provided in at least a part of an outermost peripheral portion of the element base, wherein in the protective layer, numerous convex parts each having a size of 1.0 μm or less and made up of ceramic microparticles with diameters of 10 nm to 1.0 μm are discretely formed around numerous ceramic coarse grains having diameters of 5.0 μm to 40 μm, the respective ceramic coarse grains are connected to each other directly or via the ceramic microparticle, and a degree of porosity of the protective layer is 5% to 50%.

Disclosed is a ceramic matrix component having a fibrous core and a ceramic matrix composite shell surrounding at least a portion of the fibrous core. The ceramic matrix composite shell comprises a fibrous preform. The fibrous core has a greater porosity than the fibrous preform. A method of making the ceramic matrix component is also disclosed.

A sensor element of a gas sensor includes: an element base which is a ceramic structured body including a detection part of detecting a target measurement gas component; an outer protective layer which is a porous layer provided in at least a part of an outermost peripheral portion of the element base; and an inner protective layer which is a porous layer having a degree of porosity of 30% to 85%, which is larger than a degree of porosity of the outer protective layer, inside the outer protective layer, wherein an average fine pore diameter of the inner protective layer is equal to or larger than 0.5 μm and equal to or smaller than 5.0 μm.

A multilayer ceramic substrate that includes a first layer positioned at a surface of the multilayer ceramic substrate, a second layer adjacent the first layer and positioned inward of the first layer, and a surface layer electrode disposed on a surface of the first layer. The first layer has a porosity of 13% or less and a maximum pore size of 10 μm or less. The second layer has a porosity of 14% or less and a maximum pore size of 11 μm or less.

An article that includes a substrate; a first layer including yttria and zirconia or hafnia, where the first layer has a columnar microstructure and includes predominately the zirconia or hafnia; a second layer on the first layer, the second layer including zirconia or hafnia, ytterbia, samaria, and at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the second layer includes predominately zirconia or hafnia, and where the second layer has a columnar microstructure; and a third layer on the second layer, the third layer including zirconia or hafnia, ytterbia, samaria, and a rare earth oxide including at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the third layer has a dense microstructure and has a lower porosity than the second layer.

An article that includes a substrate; a first layer including yttria and zirconia or hafnia, where the first layer has a columnar microstructure and includes predominately the zirconia or hafnia; a second layer on the first layer, the second layer including zirconia or hafnia, ytterbia, samaria, and at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the second layer includes predominately zirconia or hafnia, and where the second layer has a columnar microstructure; and a third layer on the second layer, the third layer including zirconia or hafnia, ytterbia, samaria, and a rare earth oxide including at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the third layer has a dense microstructure and has a lower porosity than the second layer.

A filter including a plurality of pillar-shaped honeycomb structure segments made of porous ceramics, side faces of the segments being bonded together via a bonding material, wherein each of the pillar-shaped honeycomb structure segments includes an outer peripheral side wall, and partition walls partitioning a plurality of cells extending from a first end face to a second end face, and in each of the pillar-shaped honeycomb structure segments, an average porosity of the outer peripheral side wall is lower than that of the partition walls.

A method of making a ceramic matrix composite (CMC) article by combining a preceramic polymer with one or more sized nanopowders and optional surfactants and/or solvents to form a mixture suitable for 3D printing, depositing the mixture on a mandrel, curing it to form a green body, and pyrolyzing the green body such that the nanocrystalline surface of the CMC article has sufficiently the same surface roughness and figure accuracy of the mandrel to enable the CMC article to be used without further polishing. The mixture can be a paste or slurry that is self supporting and exhibit pseudoplastic rheology. The preceramic polymer is preferably a precursor to SiC, and the nanopowders preferably comprise SiC. The article can be densified by using polymer infiltration pyrolysis, with or without nanoparticles. The curing and pyrolysis of the article can be performed with microwave radiation. An example structure is a gradient density lattice with a mirror surface for use in a cryogenically cooled infrared optical system such as an orbiting space telescope.

A plate-shaped carbon fiber-reinforced carbon composite has a longitudinal length-to-widthwise length ratio of more than 1. The carbon fiber-reinforced carbon composite is such that at least two layers that are a first carbon fiber-reinforced carbon composite layer in which carbon fibers are placed in the carbonaceous matrix and are oriented in the longitudinal direction and a second carbon fiber-reinforced carbon composite layer different in the arrangement of the carbon fibers from the first carbon fiber-reinforced carbon composite layer are stacked, the first carbon fiber-reinforced carbon composite layer forms an outermost layer of at least one plate surface, the thickness thereof is 70% or more of the thickness of the carbon fiber-reinforced carbon composite, and the longitudinal bending elastic modulus is 150 GPa or more. The first carbon fiber-reinforced carbon composite layer in which the carbon fibers are aligned in the longitudinal direction is placed only on an outermost layer of one or both of plate surfaces and another site is a carbon fiber-reinforced carbon composite layer different in the arrangement of the carbon fibers from the first carbon fiber-reinforced carbon composite layer; hence, the longitudinal bending elastic modulus is significantly increased and warping, peeling, or cracking during usage and interlayer delamination due to gases produced during manufacture are suppressed.