Processes for converting methane into an olefin and methanol are provided. The olefin can be ethylene. Certain exemplary processes can involve parallel use of both steam reforming of methane and oxidative dry reforming of methane to prepare syngas. The processes can further involve conversion of syngas to ethylene and to methanol.

A method for making hydrogenated cyclooctatetraene dimers including cyclo-dimerizing butadiene to form 1,5-cyclooctadiene in the presence of at least one first catalyst, dehydrogenating 1,5-cyclooctadiene to 1,3,5,7-cyclooctatetraene, dimerizing 1,3,5,7-cyclooctatetraene to a C.sub.16 multicyclic hydrocarbon cyclooctatetraene dimer, and hydrogenating multicyclic hydrocarbon cyclooctatetraene dimer to form hydrogenated cyclooctatetraene dimers.

A system for a carbon neutral cycle of gas production may include a molten salt reactor configured to generate zero carbon dioxide (CO.sub.2) emissions electricity. The system may include a desalination unit configured to receive the zero-CO.sub.2 emissions electricity from the molten salt reactor and produce a desalinated water. The system may include an electrolysis unit configured to be powered by the zero-CO2 emissions electricity generated by the molten salt reactor and generate hydrogen (H.sub.2) and oxygen (O.sub.2) from the desalinated water. The system may include an oxy-combustion unit configured to receive and combust a hydrocarbon fuel with the O.sub.2 from the electrolysis unit to produce electricity and CO.sub.2. The system may include a CO.sub.2 capture system adapted to capture the CO.sub.2 produced by the oxy-combustion unit and a catalytic hydrogenation unit configured to receive and convert H.sub.2 from the electrolysis unit and CO.sub.2 from the CO.sub.2 capture system to produce the hydrocarbon fuel.

A system for a carbon neutral cycle of gas production may include a molten salt reactor configured to generate zero carbon dioxide (CO.sub.2) emissions electricity. The system may include a desalination unit configured to receive the zero-CO.sub.2 emissions electricity from the molten salt reactor and produce a desalinated water. The system may include an electrolysis unit configured to be powered by the zero-CO2 emissions electricity generated by the molten salt reactor and generate hydrogen (H.sub.2) and oxygen (O.sub.2) from the desalinated water. The system may include an oxy-combustion unit configured to receive and combust a hydrocarbon fuel with the O.sub.2 from the electrolysis unit to produce electricity and CO.sub.2. The system may include a CO.sub.2 capture system adapted to capture the CO.sub.2 produced by the oxy-combustion unit and a catalytic hydrogenation unit configured to receive and convert H.sub.2 from the electrolysis unit and CO.sub.2 from the CO.sub.2 capture system to produce the hydrocarbon fuel.

The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C.sub.2+ compounds and non-C.sub.2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C.sub.2+ impurities from the C.sub.2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H.sub.2 with CO and/or CO.sub.2 in the non-C.sub.2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.

The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C.sub.2+ compounds and non-C.sub.2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C.sub.2+ impurities from the C.sub.2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H.sub.2 with CO and/or CO.sub.2 in the non-C.sub.2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.

The invention relates to a method for converting a gas into methane (CH.sub.4) which includes: a step of activating a catalytic material including praseodymium oxide (Pr.sub.6O.sub.11) associated with nickel oxide (NiO) and alumina (Al.sub.2O.sub.3), the respective proportions of which are, relative to the total mass of these three compounds: Pr.sub.6O.sub.11: 1 wt % to 20 wt %, NiO: 1 wt % to 20 wt %, and Al.sub.2O.sub.3: 60 to 98 wt %; and a step of passing a gas including at least one carbon monoxide (CO) over the activated catalytic material.

Methods and systems of the present disclosure can function to capture flue gas and convert the flue gas to a synthesis gas, which can be further processed to other components such as liquid fuels. Aspects of the present disclosure provide for a process designed to capture flue gas from large scale (i.e. ˜GW), fossil based power plants in a 24/7 continuous operation. In addition, the method and system can convert the flue gas to a synthesis gas (mainly carbon monoxide and hydrogen), which will be processed into high quality liquid fuels, like diesel.

The present invention provides a process for producing one or more products for use as a transportation or heating fuel. In various embodiments the process comprises treating a cellulosic feedstock in one or more processing steps that release extractives from the feedstock. A solids-liquid separation is subsequently conducted on the process stream comprising the extractives and solids. An aqueous stream comprising one or more of the extractives may be fed to an anaerobic digester to produce crude biogas from which one or more impurities may optionally be removed. In various embodiments the process further comprises providing a solids stream to a thermal process. A product produced or derived from the thermal process may displace a product made from fossil fuel. One or more products obtained or derived from at least one of the foregoing process steps are provided for use as a transportation or heating fuel. In various embodiments the process enables advantaged fuel credit generation.

The invention relates to a chemical plant comprising a reforming section arranged to receive a feed gas comprising hydrocarbons and provide a synthesis gas, wherein the reforming section comprises: an electrically heated reforming reactor housing a first catalyst, said electrically heated reforming reactor being arranged for receiving said feed gas and generating a first synthesis gas; and an autothermal reforming reactor downstream said electrically heated reforming reactor, said autothermal reforming reactor housing a second catalyst, said autothermal reforming reactor being arranged for receiving said first synthesis gas and outputting a second synthesis gas, wherein said reforming section is arranged to output said output synthesis gas comprising said second synthesis gas. The invention also relates to a process for producing a chemical product from a feed gas comprising hydrocarbons, in a chemical plant according to the invention.