C07C1/2078

HIGH YIELD JET FUEL FROM MIXED FATTY ACIDS
20220315508 · 2022-10-06 ·

Disclosed herein are processes and systems that utilize olefin cross metathesis of triglycerides to produce jet fuel such as hydrocarbons with carbons numbers from C9 to C16. Jet range hydrocarbons may include paraffins, naphthenes, and aromatics with carbon numbers from 9 to 16 (C9-C16), and isomers thereof. The process described herein is versatile and may be suitable for producing jet range hydrocarbons from many different grades and sources of triglycerides. Further, the process described herein may be selective to jet range hydrocarbons which may result in increased yield as compared to hydrocracking or other processes for producing jet range hydrocarbons from triglycerides.

METHOD TO PRODUCE BIO-RENEWABLE PROPYLENE FROM OILS AND FATS
20210300843 · 2021-09-30 · ·

A method is disclosed for upgrading a bio-based material, the method including pretreating bio-renewable oil(s) and/or fat(s) to provide a bio-renewable raw material, deoxygenating the bio-renewable raw material, followed by separation, to provide a propane feed, and subjecting the propane feed to dehydrogenation and to separation to provide a propylene material.

Even carbon number paraffin composition and method of manufacturing same

Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.

PROCESS FOR THE PRODUCTION OF OLEFINIC COMPOUNDS AND A HYDROCARBON FUEL OR A FRACTION THEREOF

The present invention relates to a process for the production of olefinic compounds that can be used for the production of detergents, additives, lubricants and/or plastic materials, or components which can be used in the field of oil explorations and productions, and a hydrocarbon fuel or a fraction thereof, which comprises subjecting a mixture of glycerides having at least one unsaturated hydrocarbon chain, to metathesis reaction and, after separating the olefinic mixture obtained, effecting a hydrodeoxygenation and subsequently hydroisomerization process, so as to obtain the hydrocarbon fuel or a fraction thereof.

Process for the production of olefinic compounds and a hydrocarbon fuel or a fraction thereof

The present invention relates to a process for the production of olefinic compounds that can be used for the production of detergents, additives, lubricants and/or plastic materials, or components which can be used in the field of oil explorations and productions, and a hydrocarbon fuel or a fraction thereof, which comprises subjecting a mixture of glycerides having at least one unsaturated hydrocarbon chain, to metathesis reaction and, after separating the olefinic mixture obtained, effecting a hydrodeoxygenation and subsequently hydroisomerization process, so as to obtain the hydrocarbon fuel or a fraction thereof.

High yield jet fuel from mixed fatty acids

Disclosed herein are processes and systems that utilize olefin cross metathesis of triglycerides to produce jet fuel such as hydrocarbons with carbons numbers from C9 to C16. Jet range hydrocarbons may include paraffins, naphthenes, and aromatics with carbon numbers from 9 to 16 (C9-C16), and isomers thereof. The process described herein is versatile and may be suitable for producing jet range hydrocarbons from many different grades and sources of triglycerides. Further, the process described herein may be selective to jet range hydrocarbons which may result in increased yield as compared to hydrocracking or other processes for producing jet range hydrocarbons from triglycerides.

Hydrodeoxigenation process of vegetable oils for obtaining green diesel

The present disclosure relates to a process for the hydrodeoxygenation of vegetable oils or animal fats to produce green diesel, which comprises contacting the vegetable oil or animal fat with a Nickel-Molybdenum or Cobalt-Molybdenum catalyst supported on alumina-titania or titania, respectively; in a fixed bed reactor in the presence of hydrogen. The process involves hydrocracking, hydrogenation, decarboxylation, decarbonylation, carried out in a fixed bed reactor at temperature of about 270 C. to about 360 C., pressure of about 40 kg.sub.f/cm.sup.2 to about 60 kg.sub.f/cm.sup.2, liquid hourly space velocity (LHSV) between about 0.8 h.sup.1 to about 3.0 h.sup.1, and H.sub.2/oil ratio of about 2,700 ft.sup.3/bbl to about 7,000 ft.sup.3/bbl, that allows to obtain a conversion up to 99% and up to 92.7% yield on green diesel.

PROPERTY MODULATION WITH CHEMICAL TRANSFORMATIONS

Disclosed herein is a method of generating a combinatorial library of products having a diverse array of properties. In particular, the method comprises: (a) selecting one or more pairs of reactants comprising complementary functional groups; (b) mapping all possible bond arrangements between the complementary functional groups of each pair to provide a library of possible products; (c) analyzing one or more properties of each possible product to select one or more products with desired properties (desired products); and (d) synthesizing the one or more desired products. Further disclosed herein is a method that involves the retrosynthetic reduction of a complex molecule into simple starting materials.

PROPERTY MODULATION WITH CHEMICAL TRANSFORMATIONS

Disclosed herein is a method of generating a combinatorial library of products having a diverse array of properties. In particular, the method comprises: (a) selecting one or more pairs of reactants comprising complementary functional groups; (b) mapping all possible bond arrangements between the complementary functional groups of each pair to provide a library of possible products; (c) analyzing one or more properties of each possible product to select one or more products with desired properties (desired products); and (d) synthesizing the one or more desired products. Further disclosed herein is a method that involves the retrosynthetic reduction of a complex molecule into simple starting materials.

EVEN CARBON NUMBER PARAFFIN COMPOSITION AND METHOD OF MANUFACTURING SAME

Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.