A method of performing an oxidative coupling of methane (OCM) reaction to produce C.sub.2+ compounds using a low temperature gas mixture feed is provided. The method includes introducing a gas mixture feed containing methane, oxygen, hydrogen, and carbon monoxide at a temperature of less than or equal to 300° C. to an inlet of an OCM reactor, which contains a combustion catalyst and an OCM catalyst. At least a portion of the gas mixture feed is combusted using the combustion catalyst to generate a heated gas mixture having a temperature of at least 450° C. The heated gas mixture contacts the OCM catalyst to initiate an OCM reaction and produce an OCM effluent that includes C.sub.2+ compounds. A system for performing an OCM reaction using a low temperature feedstock gas mixture is also provided.

An engine system includes an engine configured to combust liquid natural gas and generate an exhaust gas comprising methane; a catalytic reactor coupled downstream of the engine and configured to convert methane into a product through one or more of oxidative coupling of methane (OCM) reaction and steam methane reforming (SMR) reaction; and a recirculation loop configured to recirculate at least a part of the product back to the engine.

An engine system includes an engine configured to combust liquid natural gas and generate an exhaust gas comprising methane; a catalytic reactor coupled downstream of the engine and configured to convert methane into a product through one or more of oxidative coupling of methane (OCM) reaction and steam methane reforming (SMR) reaction; and a recirculation loop configured to recirculate at least a part of the product back to the engine.

Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.

Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.

Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.

Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.

Catalysts, catalytic materials having catalysts present on supports and catalytic methods are provided. The catalysts, catalytic material and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.

Catalysts, catalytic materials having catalysts present on supports and catalytic methods are provided. The catalysts, catalytic material and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.

Catalysts, catalytic materials having catalysts present on supports and catalytic methods are provided. The catalysts, catalytic material and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.