Patent classifications
C07C4/14
PROCESS FOR PRODUCING CRESOL AND XYLENE
Processes for producing cresol from an alkylphenol stream involve transalkylating the longer-chain alkylphenols (i.e., having an alkyl chain with 2 or more carbon atoms) with an aromatic solvent such as benzene and/or toluene in a first transalky lation reaction zone to obtain phenol, cresol, xylenol, trimethylphenol, and alkylbenzenes. The xylenols and trimethylphenols are reacted with phenol in a second transalkylation reactor to obtain the desired cresols. Xylenes can also be produced.
PROCESS FOR PRODUCING CRESOL AND XYLENE
Processes for producing cresol from an alkylphenol stream involve transalkylating the longer-chain alkylphenols (i.e., having an alkyl chain with 2 or more carbon atoms) with an aromatic solvent such as benzene and/or toluene in a first transalky lation reaction zone to obtain phenol, cresol, xylenol, trimethylphenol, and alkylbenzenes. The xylenols and trimethylphenols are reacted with phenol in a second transalkylation reactor to obtain the desired cresols. Xylenes can also be produced.
Process for producing BTX from a C5-C12 hydrocarbon mixture
The present invention relates to a process for producing chemical grade BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a catalyst having hydrocracking/hydrodesulphurization activity. Particularly, a process for producing BTX from a feedstream comprising C5-C12 hydrocarbons is provided comprising the steps of: (a) contacting said feedstream in the presence of hydrogen with a combined hydrocracking/hydrodesulphurization catalyst to produce a hydrocracking product stream comprising BTX; and (b) separating the BTX from the hydrocracking product stream. The hydrocracking/hydrodesulphurization catalyst comprises 0.1-1 wt-% hydrogenation metal in relation to the total catalyst weight. The hydrocracking/hydrodesulphurization catalyst further comprises a zeolite having a pore size of 5-8 and a silica (SiO.sub.2) to alumina (Al.sub.2O.sub.3) molar ratio of 5-200. The hydrocracking/hydrodesulphurization conditions include a temperature of 450-580 C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-10 h.sup.1.
Process for producing BTX from a C5-C12 hydrocarbon mixture
The present invention relates to a process for producing chemical grade BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a catalyst having hydrocracking/hydrodesulphurization activity. Particularly, a process for producing BTX from a feedstream comprising C5-C12 hydrocarbons is provided comprising the steps of: (a) contacting said feedstream in the presence of hydrogen with a combined hydrocracking/hydrodesulphurization catalyst to produce a hydrocracking product stream comprising BTX; and (b) separating the BTX from the hydrocracking product stream. The hydrocracking/hydrodesulphurization catalyst comprises 0.1-1 wt-% hydrogenation metal in relation to the total catalyst weight. The hydrocracking/hydrodesulphurization catalyst further comprises a zeolite having a pore size of 5-8 and a silica (SiO.sub.2) to alumina (Al.sub.2O.sub.3) molar ratio of 5-200. The hydrocracking/hydrodesulphurization conditions include a temperature of 450-580 C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-10 h.sup.1.
Hydrodearylation reactor
A system and method including providing a feed having alkyl-bridged multi-aromatic compounds to a tubular reactor, heating the tubular reactor, and cleaving an alkyl bridge of the alkyl-bridged multi-aromatic compounds.
Hydrodearylation reactor
A system and method including providing a feed having alkyl-bridged multi-aromatic compounds to a tubular reactor, heating the tubular reactor, and cleaving an alkyl bridge of the alkyl-bridged multi-aromatic compounds.
HEAT INTEGRATION IN DISPROPORTIONATION OR TRANSALKYLATION PROCESSES
Toluene disproportionation and C9/C10 transalkylation are a significant source of xylenes in a modern aromatics complex. Methods and apparatuses for improving the energy efficiency of these disproportionation and transalkylation processes are provided.
HEAT INTEGRATION IN DISPROPORTIONATION OR TRANSALKYLATION PROCESSES
Toluene disproportionation and C9/C10 transalkylation are a significant source of xylenes in a modern aromatics complex. Methods and apparatuses for improving the energy efficiency of these disproportionation and transalkylation processes are provided.