Disclosed herein are catalysts and methods of making and use thereof, wherein the catalysts comprises a layered inter-metallic compound.

Novel doped oxide and mixed-oxide materials having a metal homogenously dispersed in the form of isolated metal ions throughout the oxide lattice and methods for making the same.

Novel doped oxide and mixed-oxide materials having a metal homogenously dispersed in the form of isolated metal ions throughout the oxide lattice and methods for making the same.

The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; acetylene, present in the process gas in an amount of at least 1 ppm; and 0 to 190 ppm or at least 600 ppm carbon monoxide. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway.

The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; acetylene, present in the process gas in an amount of at least 1 ppm; and 0 to 190 ppm or at least 600 ppm carbon monoxide. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway.

The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; acetylene, present in the process gas in an amount of at least 1 ppm; and 0 to 190 ppm or at least 600 ppm carbon monoxide. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway.

Disclosed is a method for producing hydrogen, carbon, and ethylene from a methane-containing feedstock even without recycling of unreacted methane by providing a single process or system in which a methane-containing feedstock is subjected to two methane conversion steps. The method includes a first conversion step of producing hydrogen and carbonaceous materials and a second conversion step of producing acetylene from unreacted methane and hydrogen discharged from the first conversion step while maintaining a good methane conversion and suppressing coke formation, followed by separating and recovering ethylene and hydrogen produced through selective hydrogenation of acetylene.

Disclosed is a method for producing hydrogen, carbon, and ethylene from a methane-containing feedstock even without recycling of unreacted methane by providing a single process or system in which a methane-containing feedstock is subjected to two methane conversion steps. The method includes a first conversion step of producing hydrogen and carbonaceous materials and a second conversion step of producing acetylene from unreacted methane and hydrogen discharged from the first conversion step while maintaining a good methane conversion and suppressing coke formation, followed by separating and recovering ethylene and hydrogen produced through selective hydrogenation of acetylene.

Disclosed is a method for producing hydrogen, carbon, and ethylene from a methane-containing feedstock even without recycling of unreacted methane by providing a single process or system in which a methane-containing feedstock is subjected to two methane conversion steps. The method includes a first conversion step of producing hydrogen and carbonaceous materials and a second conversion step of producing acetylene from unreacted methane and hydrogen discharged from the first conversion step while maintaining a good methane conversion and suppressing coke formation, followed by separating and recovering ethylene and hydrogen produced through selective hydrogenation of acetylene.

The catalyst for a hydrogenation reaction according to an exemplary embodiment of the present application comprises: a porous carrier; a catalytic component supported on the porous carrier; and a polymer provided on at least a part of the surfaces of the porous carrier and the catalytic component and comprising the repeating unit represented by Chemical Formula 1.