A method for recovering paraxylene from a mixture of aromatic hydrocarbons. The process uses a pressure swing adsorption zone followed by a paraxylene recovery zone. The invention provides for lower throughput through the paraxylene recovery zone, resulting in lower capital costs and operating costs.

Described is a process for producing field butane. The process includes increasing the n-butane concentration in field butane. The process may include a concentration process that includes distillation and a thermal cracking process.

A process and system for converting bio ethanol to high purity isobutene is provided. The system includes a dehydration unit configured to receive a bio ethanol containing stream, convert the bio ethanol to bio ethylene, and produce a bio ethylene containing stream, a dimerization unit configured to receive the bio ethylene stream, dimerize ethylene, and produce an n-butenes containing stream, a skeletal isomerization unit configured to receive the n-butenes containing stream, convert n-butenes to produce a skeletal isomerization stream comprising an isobutene, isobutane, n-butenes, and n-butane, and a catalytic separation unit configured to receive the skeletal isomerization stream, convert olefins and/or isoolefins contained therein to produce a converted skeletal isomerization reaction product, and to fractionate the skeletal isomerization reaction product and produce bio isobutene.

A process and system for converting bio ethanol to high purity isobutene is provided. The system includes a dehydration unit configured to receive a bio ethanol containing stream, convert the bio ethanol to bio ethylene, and produce a bio ethylene containing stream, a dimerization unit configured to receive the bio ethylene stream, dimerize ethylene, and produce an n-butenes containing stream, a skeletal isomerization unit configured to receive the n-butenes containing stream, convert n-butenes to produce a skeletal isomerization stream comprising an isobutene, isobutane, n-butenes, and n-butane, and a catalytic separation unit configured to receive the skeletal isomerization stream, convert olefins and/or isoolefins contained therein to produce a converted skeletal isomerization reaction product, and to fractionate the skeletal isomerization reaction product and produce bio isobutene.

The invention is directed to a combined naphtha hydrotreating (NHT) and isomerization process scheme, which includes dividing wall columns (DWC) that replace multiple distillation columns and allow optimized heat integration within the system. The disclosed design provides reductions in both capital and energy costs compared to conventional schemes.

A process for converting isobutane to propylene. The process including dehydrogenating isobutane to produce a mixed product stream comprising isobutane and isobutene, skeletal isomerizing the mixed product stream comprising isobutane and isobutene to convert isobutene to n-butenes including 1-butene and 2-butenes and to recover a skeletal isomerization reaction product comprising isobutane, isobutene, butadiene, 1-butene, and 2-butenes. The process further including fractionating the skeletal isomerization reaction product, isomerizing the 1-butene contained therein to 2-butenes, recovering an overhead fraction comprising isobutane, a side draw fraction comprising isobutane and isobutene, and a bottoms fraction comprising 2-butenes, and combining the bottoms fraction with ethylene and converting the ethylene and 2-butenes to produce a reaction effluent comprising propylene.

A process for converting isobutane to propylene. The process including dehydrogenating isobutane to produce a mixed product stream comprising isobutane and isobutene, skeletal isomerizing the mixed product stream comprising isobutane and isobutene to convert isobutene to n-butenes including 1-butene and 2-butenes and to recover a skeletal isomerization reaction product comprising isobutane, isobutene, butadiene, 1-butene, and 2-butenes. The process further including fractionating the skeletal isomerization reaction product, isomerizing the 1-butene contained therein to 2-butenes, recovering an overhead fraction comprising isobutane, a side draw fraction comprising isobutane and isobutene, and a bottoms fraction comprising 2-butenes, and combining the bottoms fraction with ethylene and converting the ethylene and 2-butenes to produce a reaction effluent comprising propylene.

A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. A naphtha feed stream may be separated into a normal paraffin stream and a non-normal paraffin stream. An isomerization feed stream may be taken from the non-normal paraffin stream and isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins and produce an isomerization effluent stream. The isomerization effluent stream may be separated into a propane stream and a C4+ hydrocarbon stream optionally in a single column. The C4+ hydrocarbon stream may be recycled to the step of separating a naphtha feed stream.

A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. A naphtha feed stream may be separated into a normal paraffin stream and a non-normal paraffin stream. An isomerization feed stream may be taken from the non-normal paraffin stream and isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins and produce an isomerization effluent stream. The isomerization effluent stream may be separated into a propane stream and a C4+ hydrocarbon stream optionally in a single column. The C4+ hydrocarbon stream may be recycled to the step of separating a naphtha feed stream.

Device and process for converting a feedstock of aromatic compounds, in which the feedstock is notably treated using a fractionation train (4-7), a xylenes separating unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon-based feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO2 and H2; a WGS water gas shift reaction section (50) suitable for treating the pyrolysis gas and for producing a WGS gas enriched in CO2 and in hydrogen; a CO2 aromatization reaction section (52) suitable for: at least partly treating the WGS gas to produce a hydrocarbon effluent comprising aromatic compounds, and feeding the feedstock with the hydrocarbon effluent.