Processes are provided for conversion of oxygenated hydrocarbon, such as methanol and/or dimethyl ether, to aromatics, such as a para-xylene, and olefins, such as ethylene and propylene. The processes entail using a reactor having multiple reaction zones where each zone is prepared to promote desired reactions.

A reactor system for carrying out an endothermic reaction of a feed gas, including: a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 200 C. by passing an electrical current through the electrically conductive material. Also, a process for performing an endothermic reaction of a feed gas.

A reactor system for carrying out an endothermic reaction of a feed gas, including: a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 200 C. by passing an electrical current through the electrically conductive material. Also, a process for performing an endothermic reaction of a feed gas.

A method for upgrading a naphtha feed includes passing the naphtha feed to an adsorption unit to produce at least a paraffin stream and an isoparaffin stream, wherein the isoparaffin stream comprises isoparaffins and aromatics. Passing the isoparaffin stream to an isoparaffin aromatization catalytic unit that contacts the isoparaffin stream with at least one aromatization catalyst produces aromatics from the isoparaffins thereby yielding an aromatization effluent. The at least one aromatization catalyst may comprise ZSM-5 zeolite. Benzene, toluene, and/or xylene (BTX) may be separated from the aromatization effluent by separating the aromatics effluent into a gas stream and a liquid stream in a gas/liquid separator, wherein the liquid stream contains BTX. Passing the liquid stream to a BTX-separation unit may produce a BTX stream and a recycle stream, wherein the BTX stream contains benzene, toluene, and/or xylene.

A method for upgrading a naphtha feed includes passing the naphtha feed to an adsorption unit to produce at least a paraffin stream and an isoparaffin stream, wherein the isoparaffin stream comprises isoparaffins and aromatics. Passing the isoparaffin stream to an isoparaffin aromatization catalytic unit that contacts the isoparaffin stream with at least one aromatization catalyst produces aromatics from the isoparaffins thereby yielding an aromatization effluent. The at least one aromatization catalyst may comprise ZSM-5 zeolite. Benzene, toluene, and/or xylene (BTX) may be separated from the aromatization effluent by separating the aromatics effluent into a gas stream and a liquid stream in a gas/liquid separator, wherein the liquid stream contains BTX. Passing the liquid stream to a BTX-separation unit may produce a BTX stream and a recycle stream, wherein the BTX stream contains benzene, toluene, and/or xylene.

A process for carrying out an endothermic reaction of a feed gas in a reactor system including a pressure shell housing a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, the ceramic coating supporting a catalytically active material.

A process for carrying out an endothermic reaction of a feed gas in a reactor system including a pressure shell housing a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, the ceramic coating supporting a catalytically active material.

The present disclosure relates to the integration of systems and methods associated with steam cracking, oligomerization reactions, hydrogenation reactions, and aromatization reactions for the production of benzene via the hydrogenation of oligomers produced from ethylene. In some aspects, the disclosed systems and methods utilize one or more of an oligomerization process, a hydrotreating process, and an aromatization process for producing a benzene comprising effluent. In further aspects, the systems and methods disclosed herein utilize one or more selective oligomerization catalyst systems.

The present disclosure relates to the integration of systems and methods associated with steam cracking, oligomerization reactions, hydrogenation reactions, and aromatization reactions for the production of benzene via the hydrogenation of oligomers produced from ethylene. In some aspects, the disclosed systems and methods utilize one or more of an oligomerization process, a hydrotreating process, and an aromatization process for producing a benzene comprising effluent. In further aspects, the systems and methods disclosed herein utilize one or more selective oligomerization catalyst systems.

Present disclosure relates to process for increasing the purity and recovery of hydrogen product stream obtained from a dehydrogenation process. The dehydrogenated effluent stream is separated to obtain the net gas stream. The net gas stream is compressed in a hydrogen compressor section. Even after compressing the net gas, traces of toluene are still present in the gas phase. Applicants have found to recover these toluene traces, the compressed gas from the hydrogen compressor section is chilled in a vapor economizer followed by a chiller to produce a chilled stream at a temperature of from about 27 C. to about 17 C. This process also helps maintain the Wobbe Index of the hydrogen product stream in the range of about 44 to about 49 MJ/m.sup.3. In another embodiment, the compressed net gas stream from the hydrogen compressor section is adsorbed in an adsorption unit to separate hydrogen product stream from the recycle gas stream, wherein the recycle gas stream is completely recycled to the hydrogen compressor.