Processes for producing neopentane are disclosed herein. Processes comprise demethylating a C.sub.6-C.sub.8 alkane within a shell and tube reactor to produce a demethylation product including at least 10 wt % neopentane based on the weight of the demethylation product.

Processes for producing neopentane are disclosed herein. Processes comprise demethylating a C.sub.6-C.sub.8 alkane within a shell and tube reactor to produce a demethylation product including at least 10 wt % neopentane based on the weight of the demethylation product.

The invention relates to a supported catalyst that comprises an oxide substrate that is for the most part calcined aluminum and an active phase that comprises nickel, with the nickel content being between 5 and 65% by weight of said element in relation to the total mass of the catalyst, with said active phase not comprising a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, said catalyst having a median mesopore diameter of between 8 nm and 25 nm, a median macropore diameter of greater than 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.30 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.34 mL/g. The invention also relates to the method for preparation of said catalyst and its use in a hydrogenation method.

The invention relates to a supported catalyst that comprises an oxide substrate that is for the most part calcined aluminum and an active phase that comprises nickel, with the nickel content being between 5 and 65% by weight of said element in relation to the total mass of the catalyst, with said active phase not comprising a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, said catalyst having a median mesopore diameter of between 8 nm and 25 nm, a median macropore diameter of greater than 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.30 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.34 mL/g. The invention also relates to the method for preparation of said catalyst and its use in a hydrogenation method.

The present disclosure relates to processes that catalytically convert a hydrocarbon feed stream predominantly comprising both isopentane and n-pentane to yield upgraded hydrocarbon products that are suitable for use either as a blend component of liquid transportation fuels or as an intermediate in the production of other value-added chemicals. The hydrocarbon feed stream is isomerized in a first reaction zone to convert at least a portion of the n-pentane to isopentane, followed by catalytic-activation of the isomerization effluent in a second reaction zone with an activation catalyst to produce an activation effluent. The process increases the conversion of the hydrocarbon feed stream to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. Certain embodiments provide for further upgrading of at least a portion of the activation effluent by either oligomerization or alkylation.

The present disclosure relates to processes that catalytically convert a hydrocarbon feed stream predominantly comprising both isopentane and n-pentane to yield upgraded hydrocarbon products that are suitable for use either as a blend component of liquid transportation fuels or as an intermediate in the production of other value-added chemicals. The hydrocarbon feed stream is isomerized in a first reaction zone to convert at least a portion of the n-pentane to isopentane, followed by catalytic-activation of the isomerization effluent in a second reaction zone with an activation catalyst to produce an activation effluent. The process increases the conversion of the hydrocarbon feed stream to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. Certain embodiments provide for further upgrading of at least a portion of the activation effluent by either oligomerization or alkylation.

Provided is a separation membrane that is suitable for use in separating one or more hydrocarbons from a hydrocarbon mixture. More specifically, the separation membrane includes a porous support for which acid content is not substantially detected by ammonia temperature programmed desorption in a temperature range of higher than 450 C. and not higher than 600 C. and a porous separation layer containing a zeolite that is disposed on the porous support.

Provided is a separation membrane that is suitable for use in separating one or more hydrocarbons from a hydrocarbon mixture. More specifically, the separation membrane includes a porous support for which acid content is not substantially detected by ammonia temperature programmed desorption in a temperature range of higher than 450 C. and not higher than 600 C. and a porous separation layer containing a zeolite that is disposed on the porous support.

Provided is a separation membrane that is suitable for use in separating one or more hydrocarbons from a hydrocarbon mixture. More specifically, the separation membrane includes a porous support for which acid content is not substantially detected by ammonia temperature programmed desorption in a temperature range of higher than 450 C. and not higher than 600 C. and a porous separation layer containing a zeolite that is disposed on the porous support.

Systems and methods for separating hydrocarbons on an internal combustion powered vehicle via one or more metal organic frameworks are disclosed. Systems and methods can further include utilizing separated hydrocarbons and exhaust to generate hydrogen gas for use as fuel.