C07C11/09

Process for the production of renewable distillate-range hydrocarbons

A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.

Process for the production of renewable distillate-range hydrocarbons

A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.

METHOD FOR PURIFYING ISOBUTENE FROM A C4 STREAM AND PROCESS SYSTEM THEREFOR

A process for the purification of isobutene from a C4 stream with at least 1-butene, 2-butene, isobutane and isobutene includes isomerizing 1-butene from a stream of material which is concentrated in isobutane and isobutene obtained from the C4 stream into 2-butene, using a catalyst in an isomerization reactor; supplying a product stream from the isomerization reactor to a rectification column; and providing a stream of material which is concentrated in isobutene. A processing facility is utilized for the purification of isobutene from the C4 stream.

METHOD FOR PURIFYING ISOBUTENE FROM A C4 STREAM AND PROCESS SYSTEM THEREFOR

A process for the purification of isobutene from a C4 stream with at least 1-butene, 2-butene, isobutane and isobutene includes isomerizing 1-butene from a stream of material which is concentrated in isobutane and isobutene obtained from the C4 stream into 2-butene, using a catalyst in an isomerization reactor; supplying a product stream from the isomerization reactor to a rectification column; and providing a stream of material which is concentrated in isobutene. A processing facility is utilized for the purification of isobutene from the C4 stream.

PROCESS FOR ENHANCING THE PERFORMANCE OF THE DEHYDROGENATION OF ALKANES

A process of catalytically dehydrogenating an alkane to an alkene, using Cr.sub.2O.sub.3 as a catalyst, where the catalyst is oxidized to CrO.sub.3 during the dehydrogenation, and is regenerated by using CO as a reducing gas. In regenerating the catalyst with CO, CO.sub.2 is produced, which may be fed to a dehydrogenation reactor with the alkane and reacted with H.sub.2 produced by the dehydrogenation, to form CO and H.sub.2O by the reverse water-gas shift reaction.

PROCESS FOR ENHANCING THE PERFORMANCE OF THE DEHYDROGENATION OF ALKANES

A process of catalytically dehydrogenating an alkane to an alkene, using Cr.sub.2O.sub.3 as a catalyst, where the catalyst is oxidized to CrO.sub.3 during the dehydrogenation, and is regenerated by using CO as a reducing gas. In regenerating the catalyst with CO, CO.sub.2 is produced, which may be fed to a dehydrogenation reactor with the alkane and reacted with H.sub.2 produced by the dehydrogenation, to form CO and H.sub.2O by the reverse water-gas shift reaction.

PROCESS FOR ENHANCING THE PERFORMANCE OF THE DEHYDROGENATION OF ALKANES

A process of catalytically dehydrogenating an alkane to an alkene, using Cr.sub.2O.sub.3 as a catalyst, where the catalyst is oxidized to CrO.sub.3 during the dehydrogenation, and is regenerated by using CO as a reducing gas. In regenerating the catalyst with CO, CO.sub.2 is produced, which may be fed to a dehydrogenation reactor with the alkane and reacted with H.sub.2 produced by the dehydrogenation, to form CO and H.sub.2O by the reverse water-gas shift reaction.

Exotherm, conversion and selectivity management for oligomerization process
09834495 · 2017-12-05 · ·

A process is presented for the control of the exotherm from an oligomerization process. The oligomerization process is for the conversion of C3 and C4 olefins to distillate. The process includes controlling the extent of the reaction to limit temperature rise, and recycle of a portion of the reactor effluent stream for dilution of the C3 and C4 olefins passed to the oligomerization reactors, and for separating out the product distillate.

Exotherm, conversion and selectivity management for oligomerization process
09834495 · 2017-12-05 · ·

A process is presented for the control of the exotherm from an oligomerization process. The oligomerization process is for the conversion of C3 and C4 olefins to distillate. The process includes controlling the extent of the reaction to limit temperature rise, and recycle of a portion of the reactor effluent stream for dilution of the C3 and C4 olefins passed to the oligomerization reactors, and for separating out the product distillate.

PROCESS FOR THE ISOMERIZING DEHYDRATION OF A PRIMARY ALCOHOL FEEDSTOCK SUBSTITUTED IN POSITION 2 BY AN ALKYL GROUP ON A CATALYST COMPRISING AN IRON-TYPE ZEOLITE

Isomerizing dehydration of feedstock containing a primary alcohol substituted in position 2 by an alkyl group in which the feedstock is heated to the reaction temperature by indirect heat exchange then vaporization by mixing with a diluent effluent, the diluted and vaporized feedstock being dehydrated in at least one dehydration reactor operating in gas phase at an inlet temperature comprised between 250 and 375° C., at a pressure comprised between 0.2 MPa and 1 MPa and at a WHSV comprised between 1 and 18 h.sup.−1, in the presence of a catalyst comprising a zeolite having at least one series of channels the opening of which is defined by a ring with 8 oxygen atoms (8MR) and a binder, the catalyst being coked beforehand in-situ or ex-situ, so as to produce a dehydration effluent, the latter being treated and separated into a diluent effluent, an alkenes effluent and a heavy hydrocarbons effluent.