C07C13/10

PROCESSES FOR REGENERATING CATALYSTS
20180318812 · 2018-11-08 ·

Disclosed are processes for regenerating catalysts comprising at least one Group 10 metal and a microporous crystalline aluminosilicate having a having a molar ratio of Group 10 metal to Al of greater than or equal to about 0.007:1, and hydrocarbon conversion processes including such regeneration processes. In an aspect, the regeneration processes comprise an oxychlorination step comprising contacting the catalyst with a first gaseous stream comprising a chlorine source and an oxygen source under conditions effective for dispersing at least a portion of the at least one Group 10 metal on the surface of the catalyst and for producing a first Group 10 metal chlorohydrate. The processes further comprise a chlorine stripping step comprising contacting the catalyst with a second gaseous stream comprising an oxygen source, and optionally a chlorine source, under conditions effective for increasing the O/Cl ratio of the first Group 10 metal chlorohydrate to produce a second Group 10 metal chlorohydrate.

Processes for Rejuvenating Catalysts
20180318813 · 2018-11-08 ·

Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 375 C. and a pressure of up to about 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 500 C. and a pressure of up to about 100 bar.

Processes for Rejuvenating Catalysts
20180318813 · 2018-11-08 ·

Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 375 C. and a pressure of up to about 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 500 C. and a pressure of up to about 100 bar.

ANIMAL AND HUMAN ANTI-TRYPANOSOMONAL AND ANTI-LEISHMANIA AGENTS

Provided herein are Aminopurine compounds of Formula I:

##STR00001## or pharmaceutically acceptable salts, tautomers, isotopologues, or stereoisomers thereof, wherein R.sup.1, R.sup.2, and R.sup.3 are as defined herein, compositions comprising an effective amount of an Aminopurine Compound, and methods for treating or preventing animal and human protozoal infections.

<i>Humulus </i>species as industrial chemical feedstocks
12098120 · 2024-09-24 · ·

The present disclosure is directed to novel derivatives of naturally occurring humulones and lupulones, methods of making them, compositions comprising them, and methods for using them.

<i>Humulus </i>species as industrial chemical feedstocks
12098120 · 2024-09-24 · ·

The present disclosure is directed to novel derivatives of naturally occurring humulones and lupulones, methods of making them, compositions comprising them, and methods for using them.

Process for preparing cyclohexane with starting materials originating from a steamcracking process

The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

Process for preparing cyclohexane with starting materials originating from a steamcracking process

The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

MONONUCLEAR IRON COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME

A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound.

##STR00001##

(In the formula, R.sup.1 to R.sup.6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L.sup.1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L.sup.1's are present, two L.sup.1's may be bonded to each other; L.sup.2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L.sup.1, wherein, when multiple L.sup.2's are present, two L.sup.2's may be bonded to each other; and m.sup.1 represents an integer of 1 to 4 and m.sup.2 represents an integer of 0 to 3, wherein the sum total of m.sup.1 and m.sup.2 (i.e., m.sup.1+m.sup.2) satisfies 3 or 4.)

MONONUCLEAR IRON COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME

A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound.

##STR00001##

(In the formula, R.sup.1 to R.sup.6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L.sup.1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L.sup.1's are present, two L.sup.1's may be bonded to each other; L.sup.2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L.sup.1, wherein, when multiple L.sup.2's are present, two L.sup.2's may be bonded to each other; and m.sup.1 represents an integer of 1 to 4 and m.sup.2 represents an integer of 0 to 3, wherein the sum total of m.sup.1 and m.sup.2 (i.e., m.sup.1+m.sup.2) satisfies 3 or 4.)