The purpose of the present invention is to provide a catalyst that enables a hydrogenation reaction of cyclopentadiene to cyclopentene in a gas phase that exhibits both a high conversion rate and high selectivity, and a method for producing the cyclopentene in a gas phase that exhibits both a high conversion rate and high selectivity. A catalyst according to the disclosure and a method for producing cyclopentadienecyclopentene according to the disclosure are a catalyst and a method for producing cyclopentene using the catalyst that is used in a hydrogenation reaction of cyclopentadiene in a gas phase to form the cyclopentene, the catalyst including palladium (Pd) and a titanium dioxide (TiO.sub.2) support, wherein the titanium dioxide (TiO.sub.2) support contains anatase-type titanium dioxide (TiO.sub.2).

The purpose of the present invention is to provide a catalyst that enables a hydrogenation reaction of cyclopentadiene to cyclopentene in a gas phase that exhibits both a high conversion rate and high selectivity, and a method for producing the cyclopentene in a gas phase that exhibits both a high conversion rate and high selectivity. A catalyst according to the disclosure and a method for producing cyclopentadienecyclopentene according to the disclosure are a catalyst and a method for producing cyclopentene using the catalyst that is used in a hydrogenation reaction of cyclopentadiene in a gas phase to form the cyclopentene, the catalyst including palladium (Pd) and a titanium dioxide (TiO.sub.2) support, wherein the titanium dioxide (TiO.sub.2) support contains anatase-type titanium dioxide (TiO.sub.2).

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a crystalline aluminosilicate having a constraint index of less than or equal to 5, and a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a crystalline aluminosilicate having a constraint index of less than or equal to 5, and a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

Disclosed are processes for regenerating catalysts comprising at least one Group 10 metal and a microporous crystalline aluminosilicate having a having a molar ratio of Group 10 metal to Al of greater than or equal to about 0.007:1, and hydrocarbon conversion processes including such regeneration processes. In an aspect, the regeneration processes comprise an oxychlorination step comprising contacting the catalyst with a first gaseous stream comprising a chlorine source and an oxygen source under conditions effective for dispersing at least a portion of the at least one Group 10 metal on the surface of the catalyst and for producing a first Group 10 metal chlorohydrate. The processes further comprise a chlorine stripping step comprising contacting the catalyst with a second gaseous stream comprising an oxygen source, and optionally a chlorine source, under conditions effective for increasing the O/Cl ratio of the first Group 10 metal chlorohydrate to produce a second Group 10 metal chlorohydrate.

Disclosed are processes for regenerating catalysts comprising at least one Group 10 metal and a microporous crystalline aluminosilicate having a having a molar ratio of Group 10 metal to Al of greater than or equal to about 0.007:1, and hydrocarbon conversion processes including such regeneration processes. In an aspect, the regeneration processes comprise an oxychlorination step comprising contacting the catalyst with a first gaseous stream comprising a chlorine source and an oxygen source under conditions effective for dispersing at least a portion of the at least one Group 10 metal on the surface of the catalyst and for producing a first Group 10 metal chlorohydrate. The processes further comprise a chlorine stripping step comprising contacting the catalyst with a second gaseous stream comprising an oxygen source, and optionally a chlorine source, under conditions effective for increasing the O/Cl ratio of the first Group 10 metal chlorohydrate to produce a second Group 10 metal chlorohydrate.

Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 375 C. and a pressure of up to about 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 500 C. and a pressure of up to about 100 bar.

Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 375 C. and a pressure of up to about 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250 C. to about 500 C. and a pressure of up to about 100 bar.

The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.

The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.