Patent classifications
C07C13/18
PROCESS FOR PREPARING A CATALYST FOR THE HYDROGENATION OF AROMATICS, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a catalyst for the hydrogenation of aromatic or polyaromatic compounds comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING SELECTIVE HYDROGENATION CATALYST, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING SELECTIVE HYDROGENATION CATALYST, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
REACTION DEVICE AND REACTION METHOD USING FINE BUBBLES
A reaction device for reacting a liquid-phase reactant and a gas-phase reactant converted into fine bubbles includes: a porous body that includes a plurality of flow paths and in which the flow paths are separated by porous walls, the porous walls include continuous pores, and the porous body includes a reaction catalyst at least on the surface thereof; a solution supply section for supplying a solution containing a gas-phase reactant and a liquid-phase reactant to the continuous pores in the porous body; and a solution discharge section for discharging solution containing a reaction product obtained when the solution flows through the continuous pores of the porous body.
REACTION DEVICE AND REACTION METHOD USING FINE BUBBLES
A reaction device for reacting a liquid-phase reactant and a gas-phase reactant converted into fine bubbles includes: a porous body that includes a plurality of flow paths and in which the flow paths are separated by porous walls, the porous walls include continuous pores, and the porous body includes a reaction catalyst at least on the surface thereof; a solution supply section for supplying a solution containing a gas-phase reactant and a liquid-phase reactant to the continuous pores in the porous body; and a solution discharge section for discharging solution containing a reaction product obtained when the solution flows through the continuous pores of the porous body.
Ways to prevent pump-around heat exchanger fouling and extend run lengths on a benzene hydrogenation unit
A process for hydrogenation of an aromatic hydrocarbon including introducing a hydrocarbon feed comprising the aromatic hydrocarbon, a hydrogen feed comprising hydrogen, and a hydrogenation catalyst into a hydrogenation reactor operable with a liquid phase and a gas phase to produce a hydrogenation product; removing a gas phase product stream comprising the hydrogenation product; withdrawing a portion of the liquid phase; subjecting the withdrawn portion to heat exchange to provide a reduced-temperature withdrawn portion; introducing the reduced-temperature withdrawn portion back into the hydrogenation reactor; and at least one of: (a) providing at least two heat exchangers to effect the subjecting of the withdrawn portion of the liquid phase to heat exchange; (b) separating a decomposition product of the hydrogenation catalyst, the hydrogenation catalyst, or both, from the withdrawn portion of the liquid phase prior to the heat exchange; and (c) reducing exposure of the hydrogenation catalyst to an oxygen-containing species.
Ways to prevent pump-around heat exchanger fouling and extend run lengths on a benzene hydrogenation unit
A process for hydrogenation of an aromatic hydrocarbon including introducing a hydrocarbon feed comprising the aromatic hydrocarbon, a hydrogen feed comprising hydrogen, and a hydrogenation catalyst into a hydrogenation reactor operable with a liquid phase and a gas phase to produce a hydrogenation product; removing a gas phase product stream comprising the hydrogenation product; withdrawing a portion of the liquid phase; subjecting the withdrawn portion to heat exchange to provide a reduced-temperature withdrawn portion; introducing the reduced-temperature withdrawn portion back into the hydrogenation reactor; and at least one of: (a) providing at least two heat exchangers to effect the subjecting of the withdrawn portion of the liquid phase to heat exchange; (b) separating a decomposition product of the hydrogenation catalyst, the hydrogenation catalyst, or both, from the withdrawn portion of the liquid phase prior to the heat exchange; and (c) reducing exposure of the hydrogenation catalyst to an oxygen-containing species.
Hydrodeoxygenation of lignin to hydrocarbons using bimetallic catalysts
Bimetallic catalysts for the hydrodeoxygenation (HDO) conversion of lignin into useful hydrocarbons are provided. The catalysts are bifunctional bimetallic ruthenium catalysts Ru-M/X.sup.+Y comprising a metal M such as iron (Fe), nickel (Ni), copper (Cu) or zinc (Zn), zeolite Y and cation X.sup.+ (e.g. H.sup.+) associated with zeolite Y.
Hydrodeoxygenation of lignin to hydrocarbons using bimetallic catalysts
Bimetallic catalysts for the hydrodeoxygenation (HDO) conversion of lignin into useful hydrocarbons are provided. The catalysts are bifunctional bimetallic ruthenium catalysts Ru-M/X.sup.+Y comprising a metal M such as iron (Fe), nickel (Ni), copper (Cu) or zinc (Zn), zeolite Y and cation X.sup.+ (e.g. H.sup.+) associated with zeolite Y.
Hydrodeoxygenation of lignin to hydrocarbons using bimetallic catalysts
Bimetallic catalysts for the hydrodeoxygenation (HDO) conversion of lignin into useful hydrocarbons are provided. The catalysts are bifunctional bimetallic ruthenium catalysts Ru-M/X.sup.+Y comprising a metal M such as iron (Fe), nickel (Ni), copper (Cu) or zinc (Zn), zeolite Y and cation X.sup.+ (e.g. H.sup.+) associated with zeolite Y.