The present invention concerns a zeolitic adsorbent agglomerate comprising at least one zeolite of faujasite type comprising barium and/or potassium, of porosity between 25% and 45%, and having a standard deviation σ of crystal size distribution in said agglomerate of less than 0.30 μm.

The invention also concerns the use of the zeolitic adsorbent agglomerate for the separation of hydrocarbon mixtures, and the process for separating hydrocarbon mixtures using said zeolitic adsorbent agglomerate.

Processes for converting C8 aromatic hydrocarbons. In some embodiments, the process can include feeding a gaseous hydrocarbon feed that can include meta-xylene, ortho-xylene, or both into a conversion zone. The process can also include contacting the gaseous hydrocarbon feed with a catalyst that can include a ZSM-11 zeolite in the conversion zone under conversion conditions to effect isomerization of at least a portion of any meta-xylene, or at least a portion of any ortho-xylene, or both to produce a conversion product rich in para-xylene. In some embodiments, the ZSM-11 zeolite can have an alpha value of 1 to 3,000 and a molar ratio of silica to alumina of from 15 to 200.

Processes for converting C8 aromatic hydrocarbons. In some embodiments, the process can include feeding a gaseous hydrocarbon feed that can include meta-xylene, ortho-xylene, or both into a conversion zone. The process can also include contacting the gaseous hydrocarbon feed with a catalyst that can include a ZSM-11 zeolite in the conversion zone under conversion conditions to effect isomerization of at least a portion of any meta-xylene, or at least a portion of any ortho-xylene, or both to produce a conversion product rich in para-xylene. In some embodiments, the ZSM-11 zeolite can have an alpha value of 1 to 3,000 and a molar ratio of silica to alumina of from 15 to 200.

A process for the production of an aromatic compound which comprise reacting a mixture comprising ethylene and a furan compound over a zeolitic material having a BEA-type framework structure is described, wherein the zeolitic material having a BEA-type framework structure comprised in the catalyst is obtainable and/or obtained according to an organotemplate-free synthetic process.

A process for the production of an aromatic compound which comprise reacting a mixture comprising ethylene and a furan compound over a zeolitic material having a BEA-type framework structure is described, wherein the zeolitic material having a BEA-type framework structure comprised in the catalyst is obtainable and/or obtained according to an organotemplate-free synthetic process.

This disclosure provides an improved process for converting benzene/toluene via methylation with methanol/dimethyl ether for producing, e.g., p-xylene, comprising separating and recycling dimethyl ether from the methylation reaction product mixture effluent to the methylation reactor. High selectivity toward p-xylene, among others, can be achieved.

This disclosure provides an improved process for converting benzene/toluene via methylation with methanol/dimethyl ether for producing, e.g., p-xylene, comprising separating and recycling dimethyl ether from the methylation reaction product mixture effluent to the methylation reactor. High selectivity toward p-xylene, among others, can be achieved.

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

An ethylbenzene dealkylation catalyst composition comprising a ZSM-5 type zeolite as a carrier component, wherein said zeolite has been synthesized from an aqueous reaction mixture comprising one or more alumina sources, one or more silica sources, one or more alkali sources, and one or more primary and/or secondary amines and wherein the ZSM-5 type zeolite has a number average crystallite size in the range of from 1 to 10 μm and a molar silica-to-alumina ratio (SAR) in the range of from 30 to 70; a method for reducing xylene losses in an ethylbenzene dealkylation process, said method comprising conducting the ethylbenzene dealklylation process in the presence of the afore-mentioned catalyst composition; and a process for the dealkylation of ethylbenzene, which process comprises contacting, in the presence of hydrogen, a feedstock which comprises ethylbenzene with said catalyst composition.