The present specification relates to a method for producing a deuterated aromatic compound and a deuterated reaction composition.

The present specification relates to a composition including two or more compounds represented by Chemical Formula 1 and having a different number of deuterium substitution, wherein, in the composition, the number of deuterium of an isotope having a highest isotope content among each isotope content for each mass number of the two or more compounds having a different number of deuterium substitution is 13 or greater, and an electronic device and an organic light emitting device including the same.

The present specification relates to a composition including two or more compounds represented by Chemical Formula 1 and having a different number of deuterium substitution, wherein, in the composition, the number of deuterium of an isotope having a highest isotope content among each isotope content for each mass number of the two or more compounds having a different number of deuterium substitution is 13 or greater, and an electronic device and an organic light emitting device including the same.

Provided are a family of chromophores including naphthyl or naphthyl-like carbocyclic or heterocyclic rings as luminescent dyes that can be useful as emitters in OLEDs. These compounds have Formula I,

##STR00001##

Also provided are formulations including these inventive compounds. Further provided are OLEDs and related consumer products that utilize these inventive compounds.

Provided are a family of chromophores including naphthyl or naphthyl-like carbocyclic or heterocyclic rings as luminescent dyes that can be useful as emitters in OLEDs. These compounds have Formula I,

##STR00001##

Also provided are formulations including these inventive compounds. Further provided are OLEDs and related consumer products that utilize these inventive compounds.

The device provided herein is an organic electroluminescent device and includes a substrate; a first electrode on the substrate and with high reflectivity; a translucent or transparent second electrode over the first electrode; and a first, a second and a third organic layer included between the first and the second electrode; where the second organic layer has a thickness >80 nm and is made of a second organic material; the third organic layer is a light-emitting layer including at least one light-emitting material and at least one host material; the first organic layer has a conductivity >1×10.sup.−4 S/m and <1×10.sup.−2 S/m; an energy level difference between HOMO energy level of the second organic material and HOMO energy level of the at least one host material is <0.27 eV; and the first electrode and the second organic layer are in direct contact with the first organic layer.

The device provided herein is an organic electroluminescent device and includes a substrate; a first electrode on the substrate and with high reflectivity; a translucent or transparent second electrode over the first electrode; and a first, a second and a third organic layer included between the first and the second electrode; where the second organic layer has a thickness >80 nm and is made of a second organic material; the third organic layer is a light-emitting layer including at least one light-emitting material and at least one host material; the first organic layer has a conductivity >1×10.sup.−4 S/m and <1×10.sup.−2 S/m; an energy level difference between HOMO energy level of the second organic material and HOMO energy level of the at least one host material is <0.27 eV; and the first electrode and the second organic layer are in direct contact with the first organic layer.

Provided is an organic light-emitting device including a light-emitting layer comprising a compound of Chemical Formula 1, and a first organic material layer comprising a compound of Chemical Formula 2:

##STR00001## wherein: Cy1 to Cy5 are each independently one selected from the group consisting of a substituted or unsubstituted: aromatic hydrocarbon ring, aliphatic hydrocarbon ring, and an aromatic hetero ring, or a ring in which two or more rings selected from the above group are fused, one or more of Cy1 to Cy5 are a ring of the following Chemical Formula 1-A,

##STR00002##

wherein: Ar1 and Ar2 are the same as or different from each other, and are each independently a phenyl, a biphenyl, a terphenyl, a naphthyl, a phenanthrenyl, or a triphenylenyl, where the naphthyl, phenanthrenyl, and triphenylenyl can be substituted with a phenyl.

Provided is a compound of Formula I

##STR00001##

in which at least one moiety A, moiety B, moiety C, or moiety D is a 6-membered carbocyclic or heterocyclic ring, and at least one R.sup.A, R.sup.B, R.sup.C, or R.sup.D includes a group having Formula II

##STR00002##

where R.sup.X can be silyl, germyl, boryl, nitrile, F, CF.sub.3, cycloalkyl, heterocycloalkyl, or monocyclic heteroaryl. The compounds are useful as emitters in OLEDs providing improved efficiency.

Provided is a compound of Formula I

##STR00001##

in which at least one moiety A, moiety B, moiety C, or moiety D is a 6-membered carbocyclic or heterocyclic ring, and at least one R.sup.A, R.sup.B, R.sup.C, or R.sup.D includes a group having Formula II

##STR00002##

where R.sup.X can be silyl, germyl, boryl, nitrile, F, CF.sub.3, cycloalkyl, heterocycloalkyl, or monocyclic heteroaryl. The compounds are useful as emitters in OLEDs providing improved efficiency.