The present invention relates to a method for chlorination and dehydrogenation of ethane, comprising: mixing and reacting a low-melting-point metal chloride with C.sub.2H.sub.6, such that the low-melting-point metal chloride is reduced to a liquid-state low-melting-point metal, and the C.sub.2H.sub.6 is chlorinated and dehydrogenized to give a mixed gas containing HCl, C.sub.2H.sub.6, C.sub.2H.sub.4, C.sub.2H.sub.2 and C.sub.2H.sub.3Cl. In the method, the low-melting-point metal chloride is used as a raw material for chlorination and dehydrogenation, and the low-melting-point metal produced after the reaction is used as an intermediate medium. The method has the characteristics of simple process, low cost and high yield. Moreover, some acetylene and vinyl chloride can be produced as by-products at the same time when the ethylene is produced, by controlling the ratio of ethane to the chloride as desired in production.

The present invention relates to a method for chlorination and dehydrogenation of ethane, comprising: mixing and reacting a low-melting-point metal chloride with C.sub.2H.sub.6, such that the low-melting-point metal chloride is reduced to a liquid-state low-melting-point metal, and the C.sub.2H.sub.6 is chlorinated and dehydrogenized to give a mixed gas containing HCl, C.sub.2H.sub.6, C.sub.2H.sub.4, C.sub.2H.sub.2 and C.sub.2H.sub.3Cl. In the method, the low-melting-point metal chloride is used as a raw material for chlorination and dehydrogenation, and the low-melting-point metal produced after the reaction is used as an intermediate medium. The method has the characteristics of simple process, low cost and high yield. Moreover, some acetylene and vinyl chloride can be produced as by-products at the same time when the ethylene is produced, by controlling the ratio of ethane to the chloride as desired in production.

The present invention relates to a method for chlorination and dehydrogenation of ethane, comprising: mixing and reacting a low-melting-point metal chloride with C.sub.2H.sub.6, such that the low-melting-point metal chloride is reduced to a liquid-state low-melting-point metal, and the C.sub.2H.sub.6 is chlorinated and dehydrogenized to give a mixed gas containing HCl, C.sub.2H.sub.6, C.sub.2H.sub.4, C.sub.2H.sub.2 and C.sub.2H.sub.3Cl. In the method, the low-melting-point metal chloride is used as a raw material for chlorination and dehydrogenation, and the low-melting-point metal produced after the reaction is used as an intermediate medium. The method has the characteristics of simple process, low cost and high yield. Moreover, some acetylene and vinyl chloride can be produced as by-products at the same time when the ethylene is produced, by controlling the ratio of ethane to the chloride as desired in production.

There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with an unsaturated hydrocarbon and/or a saturated hydrocarbon to form products. Separation and/or purification of the products as well as of the metal ions in the lower oxidation state and the higher oxidation state, is provided herein.

There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with an unsaturated hydrocarbon and/or a saturated hydrocarbon to form products. Separation and/or purification of the products as well as of the metal ions in the lower oxidation state and the higher oxidation state, is provided herein.

Integrations of carbon monoxide electrolyzers and chlor-alkali electrolyzers are disclosed herein. The disclosed integrations include novel process chains for the valorization of oxocarbons into hydrochloric acid, vinyl chloride, vinyl acetate, ethylene oxide, and other useful chemicals. The disclosed integrations further include novel ways to operate the electrolyzers in tandem to increase the efficiency of both reactors. This disclosure also includes novel ways to balance the operation of both electrolyzers to assure they are operating at an optimal level to take advantage of the benefits of the disclosed integrations.

Integrations of carbon monoxide electrolyzers and chlor-alkali electrolyzers are disclosed herein. The disclosed integrations include novel process chains for the valorization of oxocarbons into hydrochloric acid, vinyl chloride, vinyl acetate, ethylene oxide, and other useful chemicals. The disclosed integrations further include novel ways to operate the electrolyzers in tandem to increase the efficiency of both reactors. This disclosure also includes novel ways to balance the operation of both electrolyzers to assure they are operating at an optimal level to take advantage of the benefits of the disclosed integrations.

Integrations of carbon monoxide electrolyzers and chlor-alkali electrolyzers are disclosed herein. The disclosed integrations include novel process chains for the valorization of oxocarbons into hydrochloric acid, vinyl chloride, vinyl acetate, ethylene oxide, and other useful chemicals. The disclosed integrations further include novel ways to operate the electrolyzers in tandem to increase the efficiency of both reactors. This disclosure also includes novel ways to balance the operation of both electrolyzers to assure they are operating at an optimal level to take advantage of the benefits of the disclosed integrations.

To provide a heterogeneous catalyst that exhibits high activity and high selectivity, specifically a catalyst suitable for oxychlorination to produce 1,2-dichloroethane from ethylene, and a catalyst system. Provided are: a heterogeneous catalyst supported on a porous carrier, characterized in that the integral value of the hysteresis occurring between an adsorption isotherm and a desorption isotherm by a gas adsorption method, is at most 19% to the total integral value of the adsorption isotherm; and a catalyst system for producing 1,2-dichloroethane, which comprises this catalyst and a diluent having a spherical shape, circular cylindrical shape or hollow cylindrical shape.

To provide a heterogeneous catalyst that exhibits high activity and high selectivity, specifically a catalyst suitable for oxychlorination to produce 1,2-dichloroethane from ethylene, and a catalyst system. Provided are: a heterogeneous catalyst supported on a porous carrier, characterized in that the integral value of the hysteresis occurring between an adsorption isotherm and a desorption isotherm by a gas adsorption method, is at most 19% to the total integral value of the adsorption isotherm; and a catalyst system for producing 1,2-dichloroethane, which comprises this catalyst and a diluent having a spherical shape, circular cylindrical shape or hollow cylindrical shape.