C07C31/135

CHROMIUM-CATALYZED PRODUCTION OF ALCOHOLS FROM HYDROCARBONS IN THE PRESENCE OF OXYGEN

Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.

TERPINEOL AND PREPARATION METHOD AND APPLICATION THEREOF

The present invention discloses a terpinenol compound as well as its preparation method and application. The structure of such terpinenol compound is as shown in Formula (I) or (II). In Formula (I), R is independently selected from C.sub.12-C.sub.16 alkyl, NR.sup.1R.sup.2, SR.sup.3 or OR.sup.4; R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently selected from C.sub.1-C.sub.6 alkyl or NO.sub.2; the C.sub.1-C.sub.6 alkyl can be substituted by OH; Alternatively, the R.sup.1 and R.sup.2 form a five-member ring or six-member ring in together with N used to link up them; the five-member or six-member ring may contain one O or CO. As indicated by results of activity test, such terpinenol compound has satisfactory effect in prevention of asthma, inflammation and pulmonary artery hypertension, which also has high pharmaceutical significance.

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Open-flask hydroboration and the use thereof

The present disclosure generally relates to a process for hydroboration of an alkene or alkyne using ammonia borane (AB). In particular, the present invention relates to hydroboration of an alkene or alkyne in the presence of air or moisture, and a clean process for facile preparation of an alcohol by oxidizing the organoborane so formed with hydrogen peroxide. The products, including aminodialkylboranes, ammonia trialkylborane complexes, as well as various alcohols so prepared, are within the scope of this disclosure.

MIXTURES OF META AND PARA SUBSTITUTED 4-ISOBUTYL-CYCLOHEXANE AS AROMA INGREDIENT

The present invention relates to a compound of formula (I) which is used as an aroma chemical. Specifically. it relates to the use of compound of formula (I) as an aroma chemical and also for enhancing and/or modifying the aroma of a composition. The present invention further relates to a mixture of compound of formula (I) with compound of formula (II).

Chromium-catalyzed production of alcohols from hydrocarbons in the presence of oxygen

Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.

Chromium-catalyzed production of alcohols from hydrocarbons in the presence of oxygen

Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.

1-HYDROXYMETHYL-1,2,2,6-TETRAMETHYL-CYCLOHEXANE AND DERIVATIVES THEREOF AND THEIR USE AS AROMA CHEMICALS

The invention relates to compounds of formula (A) as defined herein, and esters of the compound of formula (A), and ketones of the compound of formula (A). The invention further relates to a method for preparing compounds of formula (A) and esters of the compound of formula (A), and ketones of the compound of formula (A). The invention further relates to the use of at least one compound selected from compounds of formula (A) and the esters of a compound of formula (A) and the ketones of a compound of formula (A) as aroma chemical.

ALICYCLIC ALCOHOL, ALICYCLIC ALCOHOL COMPOSITION, AND PERFUME COMPOSITION

An alicyclic alcohol represented by General Formula (1) below, and an alicyclic alcohol composition comprising the alicyclic alcohol, is described:

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The alicyclic alcohol composition may comprise an alicyclic alcohol represented by Formula (3) below and an alicyclic alcohol represented by Formula (4) below:

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A fragrance composition is also disclosed, which comprises the alicyclic alcohol represented by General Formula (1).

NOVEL AROMA CHEMICALS HAVING A 1,2,2-TRIMETHYLCYCLOPENTAN-1-YL MOIETY

The present invention relates to novel compounds of general formulae (la), (lb) and (Ic) and to the stereoisomers thereof. The compounds are useful as a fragrance or as flavor as they have a sandalwood like scent. The invention also relates to a method for imparting or modifying a scent or a flavor to a composition by including said compounds into such composition, to a fragrance containing composition and/or a fragrance material containing said compound and to a process for preparing these compounds. X is C(R.sup.4)OH or CO; R.sup.1 is selected from the group consisting of hydrogen, C.sub.1-C.sub.4-alkyl, C.sub.2-C.sub.4-alkenyl and C.sub.3-C.sub.4-cycloalkyl, R.sup.2 is selected from the group consisting of hydrogen, C.sub.1-C.sub.4-alkyl, C.sub.2-C.sub.4-alkenyl and C.sub.3-C.sub.4-cycloalkyl, R.sup.3 is C.sub.1-C.sub.4-alkyl, R.sup.3a is selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl, R.sup.3b is hydrogen or together with R.sup.3a is CH.sub.2; R.sup.4 is selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl.

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NOVEL AROMA CHEMICALS HAVING A 1,2,2-TRIMETHYLCYCLOPENTAN-1-YL MOIETY

The present invention relates to novel compounds of general formulae (la), (lb) and (Ic) and to the stereoisomers thereof. The compounds are useful as a fragrance or as flavor as they have a sandalwood like scent. The invention also relates to a method for imparting or modifying a scent or a flavor to a composition by including said compounds into such composition, to a fragrance containing composition and/or a fragrance material containing said compound and to a process for preparing these compounds. X is C(R.sup.4)OH or CO; R.sup.1 is selected from the group consisting of hydrogen, C.sub.1-C.sub.4-alkyl, C.sub.2-C.sub.4-alkenyl and C.sub.3-C.sub.4-cycloalkyl, R.sup.2 is selected from the group consisting of hydrogen, C.sub.1-C.sub.4-alkyl, C.sub.2-C.sub.4-alkenyl and C.sub.3-C.sub.4-cycloalkyl, R.sup.3 is C.sub.1-C.sub.4-alkyl, R.sup.3a is selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl, R.sup.3b is hydrogen or together with R.sup.3a is CH.sub.2; R.sup.4 is selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl.

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