A biomass-based long-chain alcohol ether oxygenated additive and a preparation method and application thereof are disclosed. The additive used agricultural and forestry wastes as raw materials, and has a general chemical formula of R—(O—C.sub.1-3).sub.n—R—OH. The preparation method includes the following steps: step 1, performing drying pretreatment on biomass raw materials, performing rapid pyrolysis under an inert atmosphere to obtain a pyrolysis product containing water, gases, water-phase bio-oil and oil-phase bio-oil, separating out the water-phase bio-oil and performing catalytic hydrogenation on the water-phase bio-oil to obtain polyols; step 2, performing catalytic dehydration on the polyols obtained in step 1 under a basic catalyst system to obtain epoxyalkane; and step 3, making the epoxyalkane obtained in step 2 and methanol undergo a reaction under a molecular sieve catalyst and removing the solid catalyst by separation to obtain the long-chain alcohol ether oxygenated additive.

A biomass-based long-chain alcohol ether oxygenated additive and a preparation method and application thereof are disclosed. The additive used agricultural and forestry wastes as raw materials, and has a general chemical formula of R—(O—C.sub.1-3).sub.n—R—OH. The preparation method includes the following steps: step 1, performing drying pretreatment on biomass raw materials, performing rapid pyrolysis under an inert atmosphere to obtain a pyrolysis product containing water, gases, water-phase bio-oil and oil-phase bio-oil, separating out the water-phase bio-oil and performing catalytic hydrogenation on the water-phase bio-oil to obtain polyols; step 2, performing catalytic dehydration on the polyols obtained in step 1 under a basic catalyst system to obtain epoxyalkane; and step 3, making the epoxyalkane obtained in step 2 and methanol undergo a reaction under a molecular sieve catalyst and removing the solid catalyst by separation to obtain the long-chain alcohol ether oxygenated additive.

A biomass-based long-chain alcohol ether oxygenated additive and a preparation method and application thereof are disclosed. The additive used agricultural and forestry wastes as raw materials, and has a general chemical formula of R—(O—C.sub.1-3).sub.n—R—OH. The preparation method includes the following steps: step 1, performing drying pretreatment on biomass raw materials, performing rapid pyrolysis under an inert atmosphere to obtain a pyrolysis product containing water, gases, water-phase bio-oil and oil-phase bio-oil, separating out the water-phase bio-oil and performing catalytic hydrogenation on the water-phase bio-oil to obtain polyols; step 2, performing catalytic dehydration on the polyols obtained in step 1 under a basic catalyst system to obtain epoxyalkane; and step 3, making the epoxyalkane obtained in step 2 and methanol undergo a reaction under a molecular sieve catalyst and removing the solid catalyst by separation to obtain the long-chain alcohol ether oxygenated additive.

Method (M) for the preparation of an end compound from an internal ketone, said method comprising: —synthesizing the internal ketone by a process (P) for the decarboxylative ketonization of a fatty acid, a fatty acid derivative or a mixture thereof in a liquid phase with a metal compound as catalyst in the substantial absence of added solvent, wherein the fatty acid, fatty acid derivative or mixture thereof is added in sequential steps, the first step taking place at a temperature sequentially at a temperature from 100° C. to 270° C., —causing the internal ketone to react in accordance with a single or multiple chemical reaction scheme involving at least one reagent other than the internal ketone, wherein at least one product of the chemical reaction scheme is the end compound that is not further caused to be chemically converted into another compound.

Method (M) for the preparation of an end compound from an internal ketone, said method comprising: —synthesizing the internal ketone by a process (P) for the decarboxylative ketonization of a fatty acid, a fatty acid derivative or a mixture thereof in a liquid phase with a metal compound as catalyst in the substantial absence of added solvent, wherein the fatty acid, fatty acid derivative or mixture thereof is added in sequential steps, the first step taking place at a temperature sequentially at a temperature from 100° C. to 270° C., —causing the internal ketone to react in accordance with a single or multiple chemical reaction scheme involving at least one reagent other than the internal ketone, wherein at least one product of the chemical reaction scheme is the end compound that is not further caused to be chemically converted into another compound.

Method (M) for the preparation of an end compound from an internal ketone, said method comprising: —synthesizing the internal ketone by a process (P) for the decarboxylative ketonization of a fatty acid, a fatty acid derivative or a mixture thereof in a liquid phase with a metal compound as catalyst in the substantial absence of added solvent, wherein the fatty acid, fatty acid derivative or mixture thereof is added in sequential steps, the first step taking place at a temperature sequentially at a temperature from 100° C. to 270° C., —causing the internal ketone to react in accordance with a single or multiple chemical reaction scheme involving at least one reagent other than the internal ketone, wherein at least one product of the chemical reaction scheme is the end compound that is not further caused to be chemically converted into another compound.

Disclosed is a method for preparing propylene glycol phenyl ether, comprising carrying out a polymerization reaction of phenol and a propylene oxide in the presence of a quaternary phosphonium salt compound as a catalyst. Preferably, the method comprises mixing phenol and a quaternary phosphonium salt compound, and then adding propylene oxide under oxygen-free conditions, wherein the phenol is polymerized with the propylene oxide to produce the propylene glycol phenyl ether. The propylene glycol phenyl ether thus prepared has few impurities and contains no metal ions, such as potassium and sodium, and does not require subsequent operations to remove metal ions and perform rectification separation, thereby reducing the costs and allowing same to be directly applied to high-standard industrial production.

Disclosed is a method for preparing propylene glycol phenyl ether, comprising carrying out a polymerization reaction of phenol and a propylene oxide in the presence of a quaternary phosphonium salt compound as a catalyst. Preferably, the method comprises mixing phenol and a quaternary phosphonium salt compound, and then adding propylene oxide under oxygen-free conditions, wherein the phenol is polymerized with the propylene oxide to produce the propylene glycol phenyl ether. The propylene glycol phenyl ether thus prepared has few impurities and contains no metal ions, such as potassium and sodium, and does not require subsequent operations to remove metal ions and perform rectification separation, thereby reducing the costs and allowing same to be directly applied to high-standard industrial production.

Disclosed is a method for preparing propylene glycol phenyl ether, comprising carrying out a polymerization reaction of phenol and a propylene oxide in the presence of a quaternary phosphonium salt compound as a catalyst. Preferably, the method comprises mixing phenol and a quaternary phosphonium salt compound, and then adding propylene oxide under oxygen-free conditions, wherein the phenol is polymerized with the propylene oxide to produce the propylene glycol phenyl ether. The propylene glycol phenyl ether thus prepared has few impurities and contains no metal ions, such as potassium and sodium, and does not require subsequent operations to remove metal ions and perform rectification separation, thereby reducing the costs and allowing same to be directly applied to high-standard industrial production.

A high-activity double-metal-cyanide catalyst, a method for fabricating the same, and applications of the same are disclosed. An organic complexing ligand, which is formed via mixing fatty alcohols and alicyclic carbonates, is used to generate a high-activity double-metal-cyanide catalyst. The high-activity double-metal-cyanide catalyst includes at least one double-metal-cyanide compound, at least one organic complexing ligand, and an optional functionalized compound. The double-metal-cyanide catalyst of the present invention has a higher activity than the conventional double-metal-cyanide catalysts. The polyols generated by the present invention has an insignificant amount of high-molecular-weight compounds.