The present disclosure provides compounds of formula (I) or salts thereof, wherein R.sup.1-R.sup.10 and x are defined herein; compositions containing these compounds; methods of inhibiting, reducing, or ameliorating bacterial growth on a substrate using these compound; and products such as dental care products, soaps, antibacterial products, and plastics comprise one or more compounds described herein.

##STR00001##

Compounds having the formula (F-I) below are provided herein:

##STR00001##

wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

Compounds having the formula (F-I) below are provided herein:

##STR00001##

wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.

A polysubstituted benzene compound, preparation method thereof, and method of using the same. The compound has a formula I or I, where X represents carbon, sulfur, or oxygen; R.sup.1 represents a C.sub.1-16 alkyl, C.sub.2-16 alkenyl, or C.sub.2-10 alkynyl; R.sup.2 represents hydrogen, halogen, C.sub.1-16 alkyl, C.sub.2-16 alkenyl, or C.sub.2-10 alkynyl; or an aryl group or a substituted aryl group by 1-5 groups selected from halogen, C.sub.1-26 alkyl, C.sub.1-3 halogenated alkyl, OC.sub.1-3 alkyl, hydroxyl, amino, nitro, cyano group, aldehyde group and ester group; or a heteroaryl group or a substituted heteroaryl group by 1-5 groups selected from halogen, C.sub.1-26 alkyl, C.sub.1-3 halogenated alkyl, OC.sub.1-3 alkyl, hydroxyl, amino, nitro, cyano group, aldehyde group and ester group; the heteroaryl group is a 3-10-membered heteroaryl group including N, S, O, or a combination thereof.

The present invention relates to a method for the metal-free preparation of a biaryl compound by a photosplicing reaction and its use in the preparation of chemical compounds, preferably of active ingredients e.g. in the fields of pharmaceuticals and agrochemicals. In particular, it refers to a method for the regiocontrolled preparation of a biaryl compound of formula (I): ArAr by photochemically reacting a precursor compound of formula (II): ArLAr to form a biaryl compound of general formula: ArLAr(II).fwdarw.ArAr (I) wherein Ar and Ar, independently of each other, represent an unsubstituted or substituted C6-C20 aryl group or a heteroaryl group with 5-20 ring atoms selected from carbon, nitrogen, oxygen and sulfur, and L represents a group XYZ as defined herein. The biaryl compounds are generally suitable as intermediates or key building blocks in a very broad spectrum of organic chemical syntheses and their respective utilities. Their use within the field of synthesis of active ingredients is an aspect of the invention, and their use in the preparation of pharmaceutically active ingredients is particularly preferred.

The present invention relates to a method for the metal-free preparation of a biaryl compound by a photosplicing reaction and its use in the preparation of chemical compounds, preferably of active ingredients e.g. in the fields of pharmaceuticals and agrochemicals. In particular, it refers to a method for the regiocontrolled preparation of a biaryl compound of formula (I): ArAr by photochemically reacting a precursor compound of formula (II): ArLAr to form a biaryl compound of general formula: ArLAr(II).fwdarw.ArAr (I) wherein Ar and Ar, independently of each other, represent an unsubstituted or substituted C6-C20 aryl group or a heteroaryl group with 5-20 ring atoms selected from carbon, nitrogen, oxygen and sulfur, and L represents a group XYZ as defined herein. The biaryl compounds are generally suitable as intermediates or key building blocks in a very broad spectrum of organic chemical syntheses and their respective utilities. Their use within the field of synthesis of active ingredients is an aspect of the invention, and their use in the preparation of pharmaceutically active ingredients is particularly preferred.

Disclosed herein are embodiments of aryl compounds and polymers thereof that are made using methods that do not require harsh conditions or expensive reagents. The methods disclosed herein utilize precursor compounds that can be polymerized to form polycyclic aromatic hydrocarbons and polymers, such as carbon-based polymers like nanostructures (e.g., graphene or graphene-like nanoribbons).

A long-life catalyst which can be easily and inexpensively manufactured and has high activity and suppressed leakage of metal. A catalyst according to some embodiments includes: a substrate; and a first metal atom as a catalytic center. The substrate contains a non-metallic atom and a second metal atom, and the non-metallic atom is any one selected from the group consisting of a group 15 element, a group 16 element and a group 17 element.

A long-life catalyst which can be easily and inexpensively manufactured and has high activity and suppressed leakage of metal. A catalyst according to some embodiments includes: a substrate; and a first metal atom as a catalytic center. The substrate contains a non-metallic atom and a second metal atom, and the non-metallic atom is any one selected from the group consisting of a group 15 element, a group 16 element and a group 17 element.

Compounds having the formula (F-I) below are provided herein: ##STR00001##
wherein R.sup.1 and R.sup.2 at each occurrence are independently a C.sub.1-C.sub.5000 alkyl group; R.sup.3 at each occurrence is independently hydrogen or a C.sub.1-C.sub.5000 alkyl group; R.sup.4 is a C.sub.1-C.sub.50 alkyl group or an unsubstituted or substituted phenyl group; R.sup.5 at each occurrence is independently hydrogen or a C.sub.1-C.sub.30 alkyl group; n is 1, 2, 3, or 4; and m+n is 5. Processes for preparing compounds of formula (F-I) as well as base stock and lubricant compositions containing compounds of formula (F-I) are also provided.