C07C45/59

Hydrogenation reaction method
10106488 · 2018-10-23 · ·

The present invention provides a novel hydrogenation reaction and hydrogenolysis reaction, and does not require a large scale hydrogen supply equipment and a high-pressure facility for a respective reaction. The present invention relates to a method for producing a hydrogenated compound, characterized in reducing a compound to be hydrogenated (C) using a hydrogen-containing compound (A) and a reduced compound (B) to produce the hydrogenated compound (c).

PROCESS FOR THE PRODUCTION OF (1R,2S,5R)-1-AMINO-5-[2-(DIHYDROXYBORANYL)ETHYL]-2-[(DIMETHYLAMINO)METHYL]-CYCLOHEXANE-1-CARBOXYLIC ACID

The present invention relates to a process for the preparation of (1R,2S,5R)-1-amino-5-[2-(dihydroxyboranyl)ethyl]-2-[(dimethylamino)methyl]cyclohexane-1-carboxylic acid in anhydrous crystalline form A. The present invention further relates to methyl (1R,2R,4R)-2-acetamido-2-(tert-butylcarbamoyl)-4-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)-cyclohexane-1-carboxylate which is the intermediate in this process.

PROCESS FOR THE PRODUCTION OF (1R,2S,5R)-1-AMINO-5-[2-(DIHYDROXYBORANYL)ETHYL]-2-[(DIMETHYLAMINO)METHYL]-CYCLOHEXANE-1-CARBOXYLIC ACID

The present invention relates to a process for the preparation of (1R,2S,5R)-1-amino-5-[2-(dihydroxyboranyl)ethyl]-2-[(dimethylamino)methyl]cyclohexane-1-carboxylic acid in anhydrous crystalline form A. The present invention further relates to methyl (1R,2R,4R)-2-acetamido-2-(tert-butylcarbamoyl)-4-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)-cyclohexane-1-carboxylate which is the intermediate in this process.

PROCESS FOR PURIFICATION OF A MIXTURE INCLUDING DIOLS AND ACETALS
20240294451 · 2024-09-05 ·

Process for purifying a mixture of a diol and an acetal, comprising hydrolysing the mixture with formation of the relative aldehydes/ketones and diols; and reducing the aldehydes/ketones present in the hydrolysis product by adding a reducing agent, resulting in a diol of the same species as present in the starting mixture.

PROCESS FOR PURIFICATION OF A MIXTURE INCLUDING DIOLS AND ACETALS
20240294451 · 2024-09-05 ·

Process for purifying a mixture of a diol and an acetal, comprising hydrolysing the mixture with formation of the relative aldehydes/ketones and diols; and reducing the aldehydes/ketones present in the hydrolysis product by adding a reducing agent, resulting in a diol of the same species as present in the starting mixture.

LIGNIN DEPOLYMERISATION AND DOXYGENATION PROCESS FOR OBTAINING AROMATIC COMPOUNDS AND THEIR CATALYTIC REACTION COMPOSITION

The present invention is related to a catalytic process, which includes catalytic compositions for depolymerisation and deoxygenation of lignin contained in the biomass for obtaining aromatic hydrocarbons. The catalytic composition consists of at least one non-noble element from group VIIIB of the periodic table supported on a mesoporous matrix composed of an inorganic oxide, which can be alumina surface-modified with a second inorganic oxide with the object of inhibiting the interaction between the active component and the support. The process of lignin depolymerisation consists of dissolving lignin in a mixture of protic liquids, reacting it|a reaction system by batch or in continuous flow at inert and/or reducing atmosphere, at a temperature of between 60 to 320 C. and a pressure of from 5 to 90 kg/cm.sup.2. When the reaction is developed into a batch system, oxygenated aromatic hydrocarbons are mainly produced, both by thermal as well as catalytic depolymerisation, whereas in a continuous flow reaction system, deoxygenated aromatic hydrocarbons are produced.

LIGNIN DEPOLYMERISATION AND DOXYGENATION PROCESS FOR OBTAINING AROMATIC COMPOUNDS AND THEIR CATALYTIC REACTION COMPOSITION

The present invention is related to a catalytic process, which includes catalytic compositions for depolymerisation and deoxygenation of lignin contained in the biomass for obtaining aromatic hydrocarbons. The catalytic composition consists of at least one non-noble element from group VIIIB of the periodic table supported on a mesoporous matrix composed of an inorganic oxide, which can be alumina surface-modified with a second inorganic oxide with the object of inhibiting the interaction between the active component and the support. The process of lignin depolymerisation consists of dissolving lignin in a mixture of protic liquids, reacting it|a reaction system by batch or in continuous flow at inert and/or reducing atmosphere, at a temperature of between 60 to 320 C. and a pressure of from 5 to 90 kg/cm.sup.2. When the reaction is developed into a batch system, oxygenated aromatic hydrocarbons are mainly produced, both by thermal as well as catalytic depolymerisation, whereas in a continuous flow reaction system, deoxygenated aromatic hydrocarbons are produced.

Method for producing aldehyde compound, and acetal compound

Provided are a method for producing 3-methylglutaraldehyde in a good yield under a mild condition and a novel acetal compound which is useful for carrying out the foregoing method. The method is a production method of 3-methylglutaraldehyde including a step of hydrolyzing a compound represented by the following general formula (1): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 6 carbon atoms, or are mutually coupled to represent an alkylene group having 2 to 6 carbon atoms.

Method for producing aldehyde compound, and acetal compound

Provided are a method for producing 3-methylglutaraldehyde in a good yield under a mild condition and a novel acetal compound which is useful for carrying out the foregoing method. The method is a production method of 3-methylglutaraldehyde including a step of hydrolyzing a compound represented by the following general formula (1): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 6 carbon atoms, or are mutually coupled to represent an alkylene group having 2 to 6 carbon atoms.

Method for producing aldehyde compound, and acetal compound

Provided are a method for producing 3-methylglutaraldehyde in a good yield under a mild condition and a novel acetal compound which is useful for carrying out the foregoing method. The method is a production method of 3-methylglutaraldehyde including a step of hydrolyzing a compound represented by the following general formula (1): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 6 carbon atoms, or are mutually coupled to represent an alkylene group having 2 to 6 carbon atoms.