Disclosed herein are methods, processes and compositions for preparing a compound of formula 8: (8), and formula 18: (18). The methods and processes comprise performing a first allylic oxidation, a protection reaction, a second allylic oxidation, a reduction reaction, performing an acid-catalyzed coupling reaction, a methylation reaction and a deprotection reaction. Disclosed herein are methods, processes and compositions for enantioselectively preparing compounds of formulae 8 and 18. Also disclosed herein are compositions comprising compounds of formulae 8, 18 and/or intermediates and/or starting material thereof.

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The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

Described herein are methods of stabilizing the beta hydrogen of glycerol based esters by the insertion of alkoxy groups to significantly improve the thermal, oxidative, and hydrolytic stability of the ester and allow for controlling the molar density of esters bonds in the lubricants to maximize hydrolytic stability while maintaining biodegradability and further improving performance properties.

The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques.

The invention relates to the use of a specific type of calcium catalyst (C) for the preparation of alkoxylated glycerol esters, alkoxylated glycerol esters prepared in the presence of the catalyst and a process for the preparation of the alkoxylated glycerol esters. It was found that in the presence of the above-mentioned calcium catalyst (C) the alkoxylation reaction requires a significantly smaller amount of time. Furthermore, it has been found that the ethoxylated glycerol esters prepared in the presence of calcium catalyst (C) lead to more homogeneous products with significantly lower hydroxyl values, less decomposition and improved processability.

The invention relates to the use of a specific type of calcium catalyst (C) for the preparation of alkoxylated glycerol esters, alkoxylated glycerol esters prepared in the presence of the catalyst and a process for the preparation of the alkoxylated glycerol esters. It was found that in the presence of the above-mentioned calcium catalyst (C) the alkoxylation reaction requires a significantly smaller amount of time. Furthermore, it has been found that the ethoxylated glycerol esters prepared in the presence of calcium catalyst (C) lead to more homogeneous products with significantly lower hydroxyl values, less decomposition and improved processability.

The invention relates to the use of a specific type of calcium catalyst (C) for the preparation of alkoxylated glycerol esters, alkoxylated glycerol esters prepared in the presence of the catalyst and a process for the preparation of the alkoxylated glycerol esters. It was found that in the presence of the above-mentioned calcium catalyst (C) the alkoxylation reaction requires a significantly smaller amount of time. Furthermore, it has been found that the ethoxylated glycerol esters prepared in the presence of calcium catalyst (C) lead to more homogeneous products with significantly lower hydroxyl values, less decomposition and improved processability.

A cryo-crystallised particulate fat and method for producing such a fat, having reduced D[4,3], D[3,2] and D(50) than particulate fats known in the art, as measured by laser diffraction. Particles are formed by alterations to product throughput, air pressure and flow rate. The particles offer increased functionality in various food applications.

A cryo-crystallised particulate fat and method for producing such a fat, having reduced D[4,3], D[3,2] and D(50) than particulate fats known in the art, as measured by laser diffraction. Particles are formed by alterations to product throughput, air pressure and flow rate. The particles offer increased functionality in various food applications.

A process for producing isomerized olefins, branched aldehydes, branched alcohols, branched surfactants and other branched derivatives through isomerization, hydroformylation, hydrogenation, surfactant forming reactions and other derivative forming reactions.