Synthesizing an alkane includes heating a mixture including an alkene and water at or above the water vapor saturation pressure in the presence of a catalyst and one or both of hydrogen and a reductant, thereby hydrogenating the alkene to yield an alkane and water, and separating the alkane from the water to yield the alkane. The reductant includes a first metal and the catalyst includes a second metal.

The present invention pertains to a novel process of manufacturing the compound 2,3,3,3-tetrafluoropropene (1234yf). The compound 1234yf is the newest refrigerant with zero OPD (Ozone Depleting Potential) and zero GWP (Global Warming Potential). Thus, the invention relates to a process, involving a carbene generation route, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and optionally of the compound 2-chloro-1,1,1-trifluoropropene (1233xf) via carbene route and compound 243db (2,3-dichloro-1,1,1-trifluoropropane). The invention also relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), wherein the compound 243db (2,3-dichloro-1,1,1-trifluoropropane) serves as a starting material, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf). Further, the invention relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), and of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), the initial starting materials are selected from the group consisting of com-pound 123 (2,2-dichloro-1,1,1-trifluoroethane), compound 124 (2-chloro-1,1,1,2-tetrafluoroethane), and compound 125 (pentafluoroethane).

A method for reducing carbon dioxide to manufacture a multi-carbon hydrocarbon compound includes steps as follows. A reduction reaction with separation and purification system is provided, which includes a carbon dioxide absorption tower, a reactor, a gas-liquid separation device, a liquid-phase purification device and a gas-phase purification device. An absorption step is performed, wherein a carbon dioxide gas is absorbed to form a mixed solution. A photocatalysis step is performed, wherein the mixed solution is reacted with a photocatalyst to form a carbon-based compound. A separation step is performed, wherein the carbon-based compound is separated to form a liquid-phase mixture and a gas-phase mixture. A liquid-phase purification step is performed, wherein the liquid-phase mixture is purified. A gas-phase purification step is performed, wherein the gas-phase mixture is separated and purified to form a multi-carbon hydrocarbon compound.

A catalyst for converting hydrocarbon, a method of making the same, and a method of using the same are provided. Such a catalyst includes a zeotype microporous material, a binder material, and a metal phosphide, which can be in a range of from 0.01% to 10% by weight of a total weight of the catalyst. For example, such a catalyst can be used to convert light alkene or alkane into aromatic hydrocarbon such as benzene, toluene, xylenes, and a combination thereof. The alkene may be ethylene, propylene, butylene, or a combination thereof. The alkene may be supplied directly or from a stream converted from light alkane such as methane, ethane, propane, butane, or a combination thereof.

The present invention pertains to a novel process of manufacturing the compound 2,3,3,3-tetrafluoropropene (1234yf). The compound 1234yf is the newest refrigerant with zero OPD (Ozone Depleting Potential) and zero GWP (Global Warming Potential). Thus, the invention relates to a process, involving a carbene generation route, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and optionally of the compound 2-chloro-1,1,1-trifluoropropene (1233xf) via carbene route and compound 243db (2,3-dichloro-1,1,1-trifluoropropane). The invention also relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), wherein the compound 243db (2,3-dichloro-1,1,1-trifluoropropane) serves as a starting material, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf). Further, the invention relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), and of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), the initial starting materials are selected from the group consisting of com-pound 123 (2,2-dichloro-1,1,1-trifluoroethane), compound 124 (2-chloro-1,1,1,2-tetrafluoroethane), and compound 125 (pentafluoroethane).

Catalytic chemical conversion of carbon dioxide gas combined with a hydrocarbon gas, comprising natural gas, methane, ethane, propane, butane or pentane, over a transition metal oxide, produces organic solvent products. The process converts oxidized carbon compounds to valued organic products and can reduce or eliminate the carbon footprint of industrial electric power generation industry. Catalytic processes are taught for chemical conversion of oxides of carbon, principally carbon dioxide (formed by combustion of hydrocarbons), to solvent compounds comprising acetone, butanol, pentane and related organic products. The catalysts are transition metal oxides, selected from the group comprising manganese, iron and cobalt or combinations thereof.

A process of the type for producing 1,1,1,2,3-pentachloropropane by introducing 1,1,1,3-tetrachloropropane, chlorine, and Lewis acid catalyst, optionally in the presence of carbon tetrachloride, the improvement comprising introducing the Lewis acid as a slurry within a chlorinated hydrocarbon.

A carbon-coated transition metal nanocomposite material includes carbon-coated transition metal particles having a core-shell structure. The shell layer of the core-shell structure is a graphitized carbon layer doped with oxygen and/or nitrogen, and the core of the core-shell structure is a transition metal nanoparticle. The nanocomposite material has a structure rich in mesopores, is an adsorption/catalyst material with excellent performance, can be used for catalyzing various hydrogenation reduction reactions, or used as a catalytic-oxidation catalyst useful for the treatment of volatile organic compounds in industrial exhaust gases.

A method for preparing a zinc ferrite-based catalyst comprising: obtaining a precipitate by bringing a metal precursor solution including a zinc precursor, a ferrite precursor, a solution containing an acid and water into contact with a basic aqueous solution; filtering the precipitate; drying the filtered precipitate; and firing the dried precipitate, wherein the solution containing the acid includes one or more of nitric acid (HNO.sub.3) and hydrocarbon acid.

A supported catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is a supported zeolite. A carrier is one or more than one of hierarchical pores Al.sub.2O.sub.3, SiO.sub.2, TiO.sub.2, ZrO.sub.2, CeO.sub.2, MgO and Ga.sub.2O.sub.3; the zeolite is one or more than one of CHA and AEI structures; and the load of the zeolite is 4%-45% wt. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has an extremely high light olefin selectivity; the sum of the selectivity of the light olefin comprising ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.