Patent classifications
C07C2523/80
Process for the removal of carbon monoxide from non-catalytic oxidative dehydrogenation product streams
A method of removing CO from a mixture of CO and saturated and unsaturated hydrocarbons CO to CO.sub.2 is provided. In one embodiment, the method is to contact feed stream with an oxygen transfer agent; and then oxidize at least a portion of the CO to CO.sub.2 to produce a stream enriched in CO.sub.2. The saturated and unsaturated hydrocarbons in the feed are not further oxidized during the oxidation. The oxygen transfer agent includes at least one of: i) water; ii) at least one reducible metal oxide; iii) at least one reducible chalcogen; or mixtures thereof. In another embodiment, the CO is converted to methane. The unsaturated hydrocarbons in the feed are not hydrogenated. In both of these alternatives, the CO.sub.2 or methane are then removed. Systems for removing the CO are also provided.
METHOD FOR PRODUCING METHANOL FROM SYNTHESIS GAS WITHOUT THE EMISSION OF CARBON DIOXIDE
A process for preparing methanol from a carbon-containing feedstock by producing synthesis gas therefrom in a synthesis gas production unit, converting the synthesis gas to methanol in a methanol synthesis unit and working up the reaction mixture obtained stepwise to isolate the methanol, wherein the carbon monoxide, carbon dioxide, dimethyl ether and methane components of value from the streams separated off in the isolation of the methanol are combusted with an oxygenous gas, and the carbon dioxide in the resultant flue gas is separated off in a carbon dioxide recovery unit and recycled to the synthesis gas production unit and/or to the methanol synthesis unit.
METHOD FOR PREPARING ZINC FERRITE-BASED CATALYST AND ZINC FERRITE-BASED CATALYST PREPARED THEREBY
A method for preparing a zinc ferrite-based catalyst comprising: obtaining a precipitate by bringing a metal precursor solution including a zinc precursor, a ferrite precursor, a solution containing an acid and water into contact with a basic aqueous solution; filtering the precipitate; drying the filtered precipitate; and firing the dried precipitate, wherein the solution containing the acid includes one or more of nitric acid (HNO.sub.3) and hydrocarbon acid.
Method for producing ferrite-based coated catalyst and method for producing butadiene by using same
The method for preparing a ferrite-based coating catalyst including mixing a support, a ferrite-based catalyst, and water in a coating machine which is a rotating body, in which a weight ratio of the water based on a total weight of the support is 0.15 to 0.3.
MULTI-SANDWICH COMPOSITE CATALYST AND PREPARATION METHOD AND APPLICATION THEREOF
The present disclosure relates to a multi-sandwich composite catalyst and a preparation method and application thereof. The present disclosure provides a preparation method of a multi-sandwich composite catalyst, comprises the following steps: sequentially depositing a first layer oxide, a first active metal, an oxide interlayer, a second active metal and a surface oxide on a template, and sequentially performing calcination and reduction, thereby obtaining a multi-sandwich composite catalyst; wherein the first active metal and the second active metal are different kinds of active metals. In the present disclosure, a multi-sandwich structure is formed by depositing the oxides and active metals alternately, so that the position and spacing distance of the active centers can be precisely controlled. The multi-sandwich composite catalyst prepared by the method provided described herein has a higher conversion than that of a catalyst without an interlayer when used for the catalytic reaction.
Method for producing butadiene
An exemplary embodiment of the present application provides a method for preparing butadiene, the method comprising a process of performing an oxidative dehydrogenation reaction by introducing a reactant comprising butene, oxygen, nitrogen, and steam into a reactor which is filled with a catalyst, in which during a first start-up of the oxidative dehydrogenation reaction, the oxygen is introduced into the reactor before the butene, or the oxygen is introduced into the reactor simultaneously with the butene.
METHOD FOR PRODUCING CATALYST FOR OXIDATIVE DEHYDROGENATION REACTION, CATALYST FOR OXIDATIVE DEHYDROGENATION REACTION, AND METHOD FOR PRODUCING BUTADIENE USING SAME
A method for manufacturing a catalyst for oxidative dehydrogenation reaction, a catalyst for oxidative dehydrogenation reaction, and a method for manufacturing butadiene using the same.
Method for producing methanol from synthesis gas without the emission of carbon dioxide
A process for preparing methanol from a carbon-containing feedstock by producing synthesis gas therefrom in a synthesis gas production unit, converting the synthesis gas to methanol in a methanol synthesis unit and working up the reaction mixture obtained stepwise to isolate the methanol, wherein the carbon monoxide, carbon dioxide, dimethyl ether and methane components of value from the streams separated off in the isolation of the methanol are combusted with an oxygenous gas, and the carbon dioxide in the resultant flue gas is separated off in a carbon dioxide recovery unit and recycled to the synthesis gas production unit and/or to the methanol synthesis unit.
Single-atom-based catalyst systems
The disclosure relates to a single-atom-based catalyst system with total-length control of single-atom catalytic sites. The single-atom-based catalyst system comprises at least one catalyst structure comprising a first assembly of a plurality of single-atom-catalyst superparticles. The single-atom-catalyst superparticles comprise a second assembly of a plurality of single-atom-catalyst nanoparticles. The single-atom-based catalyst system has controlled porosity and spatial distribution of active single-atom catalysts from the atomic scale to the macroscopic scale. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
Reactor layout for methanol production from low quality synthesis gas
A reactor layout for a process of methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.