C07C2527/10

Catalyst for Converting Alkylaromatic Hydrocarbon and Preparation Method Thereof
20210178372 · 2021-06-17 ·

Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.

APPLICATION OF METAL HYDRIDE/PALLADIUM COMPOUND SYSTEM IN PREPARATION OF 1,3-DICARBONYL COMPOUND IN CASCADE REACTION OF ELECTRON-DEFICIENT ALKENE COMPOUND
20210206707 · 2021-07-08 ·

Provided is an application of a metal hydride/palladium compound system in the preparation of a 1,3-dicarbonyl compound in a cascade reaction of an electron-deficient alkene compound, said reaction comprising the following steps: under the protection of nitrogen, a palladium compound and a metal hydride are suspended and stirred in a solvent, then an electron-deficient alkene compound is added; the mixture reacts at 0 C. to 100 C. for 0.3 to 10 hours; a saturated ammonium chloride aqueous solution is added to stop the reaction, and then extraction, drying by evaporation and purification by column chromatography are performed to obtain the product of 1,3-dicarbonyl compound. The hydride and palladium compound catalysts used in the method are reagents easily obtained in a laboratory; compared with the commonly used methods of hydrogenation with hydrogen gas, the method can be easily operated, and has high safety, mild conditions and high reaction yield.

LIQUID ACID CATALYZED ALKYLATION PROCESS

A process for acid catalyzed alkylation involving the use of surfactants which form bi-continuous micro-emulsions with the liquid acid and the hydrocarbon is described. The bicontinuous phase formed between the hydrocarbon and liquid acid phases at surfactant addition facilitates and improves the liquid acid catalyzed alkylation reactions including motor-fuel alkylation reaction.

PROCESS FOR PREPARING A POLYISOCYANATE, POLYISOCYANATE, ITS USE AND POLYADDITION PRODUCTS PREPARED THEREFROM

The present invention relates to a process for preparing a polyisocyanate, namely an isocyanate group-terminated polyol polyanthranilic acid ester. The process comprises the step of reacting an anthranilic acid derivative selected from anthranilic acid halide (in particular anthranilic acid chloride), isatoic anhydride or a mixture thereof with a first polyol of a number-average molar mass of at least 200 g/mol and a functionality in the range of 2 to 8, and obtaining, as a result, a polyamine (namely a polyol polyanthranilic acid ester with amine terminal groups) and reacting the polyamine with phosgene and obtaining, as a result, a polyisocyanate (namely an isocyanate group-terminated polyol polyanthranilic acid ester). The invention further relates to the polyisocyanates obtained in this way, their use in polyaddition reactions, and polyaddition products obtainable by these reactions.

Methods of Preparing an Aromatization Catalyst
20200055034 · 2020-02-20 ·

Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.

Production of neopentane

Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating neohexane and/or neoheptane to produce neopentane. The neohexane and/or neoheptane may be provided by the isomerization of C.sub.6-C.sub.7 paraffins.

Production of Neopentane

Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating neohexane and/or neoheptane to produce neopentane. The neohexane and/or neoheptane may be provided by the isomerization of C.sub.6-C.sub.7 paraffins.

Aromatic alkylation using chemically-treated solid oxides

The present invention discloses processes for alkylating an aromatic compound, such as benzene or toluene, using a chemically-treated solid oxide. Suitable chemically-treated solid oxides include fluorided silica-coated alumina and fluorided-chlorided silica-coated alumina.

OLEFIN OLIGOMERIZATIONS USING CHEMICALLY-TREATED SOLID OXIDES

Disclosed is a polyalphaolefin made up of hydrogenated oligomers. The oligomers include at least 80 wt. % of a C.sub.6 to C.sub.12 normal alpha olefin monomer. The polyalphaolefin has a viscosity index greater than or equal to 110 and a kinematic viscosity at 40 C. of less than or equal to 1750 cSt.

Methods of producing para-xylene and terephthalic acid

The present disclosure provides methods to produce para-xylene, toluene, and other compounds from renewable sources (e.g., cellulose, hemicellulose, starch, sugar) and ethylene in the presence of a catalyst. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF), which may be converted into para-xylene by cycloaddition of ethylene to DMF. Para-xylene can then be oxidized to form terephthalic acid.