Disclosed herein are processes and reaction systems for controlling a temperature of an oligomerization reaction zone using a heat exchange system.

The present application relates to branched alkanes comprising n carbon atoms, n being an integer between 9 and 50, to the process for preparing same and to uses thereof. The present application also relates to the olefins for obtaining these branched alkanes.

The present application relates to branched alkanes comprising n carbon atoms, n being an integer between 9 and 50, to the process for preparing same and to uses thereof. The present application also relates to the olefins for obtaining these branched alkanes.

Methods for determining ethylene concentration in an ethylene oligomerization reactor using an ultrasonic flow meter are described, and these methods are integrated into ethylene oligomerization processes and related oligomerization reactor systems.

Methods of hydromethylation of alkenes and ketones, including methods that use Tebbe's reagent. The methods may include contacting Cp.sub.2Ti(μ-Cl)(μ-CH.sub.2)AlMe.sub.2 and an alkene or a ketone to produce an intermediate product that may include a titanacyclobutane. The intermediate product may be contacted with an acid to produce a methylated product.

Disclosed herein are processes and reaction systems for controlling a temperature of an oligomerization reaction zone using a heat exchange system.

The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

A process includes periodically or continuously introducing an olefin monomer and periodically or continuously introducing a catalyst system or catalyst system components into a reaction mixture within a reaction system, oligomerizing the olefin monomer within the reaction mixture to form an oligomer product, and periodically or continuously discharging a reaction system effluent comprising the oligomer product from the reaction system. The reaction system includes a total reaction mixture volume and a heat exchanged portion of the reaction system comprising a heat exchanged reaction mixture volume and a total heat exchanged surface area providing indirect contact between the reaction mixture and a heat exchange medium. A ratio of the total heat exchanged surface area to the total reaction mixture volume within the reaction system is in a range from 0.75 in.sup.−1 to 5 in.sup.−1, and an oligomer product discharge rate from the reaction system is between 1.0 (lb)(hr.sup.−1)(gal.sup.−1) to 6.0 (lb)(hr.sup.−1)(gal.sup.−1).

Catalyst systems suitable for tetramerizing ethylene to form 1-octene may include a catalyst having a structure according to Formula (VI) or Formula (VII). In Formulas (VI) and (VII), X is a halogen, a (C.sub.2-C.sub.30) carboxylate, acetylacetonate, or a (C.sub.1-C.sub.30) hydrocarbyl; L.sub.1 is a neutral coordinating ligand; n is an integer from 0 to 6; Y is a (C.sub.6-C.sub.20)fluorine-substituted aryl, a (C.sub.6-C.sub.20)fluorine-substituted aryloxy, or a (C.sub.1-C.sub.20)fluorine-substituted alkoxy; and L∩L is a bidentate chelating ligand. The catalyst system may also include an aluminum containing agent which includes a reaction product of an organoaluminum compound and an antifouling compound. The antifouling compound may include one or more organic acids, organic acid salts, esters, anhydrides, or combinations of these.

Catalyst systems for tetramerizing ethylene to form 1-octene may include a catalyst which may include a chromium compound coordinated with a ligand and a co-catalyst which may include an organoaluminum compound. The ligand may have a chemical structure according to Chemical Structure (I), wherein R.sub.5, R.sub.6, and R.sub.7 are each independently chosen from a (C.sub.1-C.sub.50) hydrocarbyl group or a (C.sub.1-C.sub.50) heterohydrocarbyl group, and wherein the (C.sub.1-C.sub.50) hydrocarbyl or (C.sub.1-C.sub.50) heterohydrocarbyl groups of R.sub.5, R.sub.6, and R.sub.7 have greater than 10 carbon atoms combined and R.sub.A, R.sub.B, R.sub.C, and R.sub.D and R.sub.1, R.sub.2, R.sub.3, and R.sub.4, are independently chosen from a hydrogen atom or a (C.sub.1-C.sub.50) hydrocarbyl group.