Patent classifications
C07C2531/30
SYSTEMS AND METHODS INCORPORATING IONIC LIQUIDS FOR ELECTROCHEMICALLY MEDIATED CAPTURING OF LEWIS ACID GASES
The present invention generally relates to methods and systems for capturing a Lewis acid gas (e.g., CO.sub.2). In some embodiments, the methods and systems utilize an ionic liquid incorporated into one or more electrochemical cells.
Metathesis of olefins using ruthenium based catalytic complexes
A self-metathesis process for the production of unsaturated dicarboxylic fatty diacids and/or unsaturated dicarboxylic fatty diesters, wherein unsaturated carboxylic fatty acids and/or esters of unsaturated carboxylic fatty acids are reacted in the presence of at least one defined ruthenium based catalyst compound. A catalyst enhancer compound selected from a sacrificial catalyst or a non-catalyst enhancer may also be used. The process exhibits improved reaction times and/or the catalyst can be used at very low concentrations.
Metathesis process
A process of metathesizing a feedstock in the presence of a metathesis catalyst and at least one catalyst enhancer. The catalyst enhancer can be selected from a sacrificial catalyst or a non-catalyst enhancer. The process exhibits improved reaction times and/or the metathesis catalyst can be used at very low concentrations.
Olefin oligomerization methods
Processes for oligomerizing olefins utilizing a catalyst system including a) a transition metal complex that is transition metal compound complexed to a pyridine bisimine ligand and b) a metal alkyl and controlling the olefin oligomer product distribution K value by adjusting i) a transition metal of the transition metal complex concentration in the reactor, ii) a metal of the metal alkyl concentration in the reactor, iii) a metal of the metal alkyl to transition metal of the transition metal complex molar ratio in the reactor, and iv) any combination thereof.
PROCESS FOR THE PREPARATION OF BIO-BASED OLEFINS FROM PRIMARY ALCOHOL
Propylene is an important industrial intermediate for the production of propylene oxide and polypropylene, while isobutylene is similarly widely used for the production of a variety of industrially important products, such as butyl rubber. Both of propylene and isobutylene are obtained through the catalytic or steam cracking of fossil feedstocks, and the development of a commercially viable process for the direct conversion of alcohol to either material would accordingly be of great interest as fossil resources are depleted and/or become more costly to use, especially in consideration of increased demand for both of propylene and isobutylene. The present invention relates to the process for preparing lower olefins from primary alcohols. More particularly the present invention relates to the process of conversion of primary alcohols to lower olefins wherein the primary alcohols are obtained from renewable sources.