C07C2603/98

COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME

Provided are a novel compound and an organic electronic device using the same. The novel compound is represented by the following Formula (I):

##STR00001##

COMPOUND AND ELECTRONIC DEVICE INCLUDING SAME
20170213990 · 2017-07-27 ·

A compound is disclosed. The compound has a formula of MA.sub.xL.sub.y, wherein: A is

##STR00001## L is one of

##STR00002## M is a metal having six valence electrons, x is an integer from 1-3, y is an integer from 0-2, x+y=3, any of R.sub.a-R.sub.b and R.sub.1-R.sub.3 is independently selected from a group consisting of hydrogen, deuterium, fluorine, chlorine, bromine, iodine, N(R.sup.1).sub.2, N(Ar.sup.1).sub.2, C(O)Ar.sup.2, P(O)Ar.sup.3.sub.2, S(O)Ar.sup.4, S(O).sub.2Ar.sup.5, CR.sup.2CR.sup.3Ar.sup.6, CN, NO.sub.2, Si(R.sup.4).sub.3, B(OR.sup.5).sub.2, OSO.sub.2R.sup.6, a linear alkyl having 1 to 40 carbon atoms, a C.sub.1-C.sub.40 alkoxyl, a C.sub.1-C.sub.40 alkylthiol, a C.sub.3-C.sub.40 branched alkyl, a C.sub.3-C.sub.40 cycloalkyl, a C.sub.3-C.sub.40 branched alkoxyl, a C.sub.3-C.sub.40 cyclic alkoxyl, a C.sub.3-C.sub.40 branched alkylthiol and a C.sub.3-C.sub.40 cyclic alkylthiol, any of R.sup.1-R.sup.6 is one of a hydrogen and an alkyl, any of Ar.sup.1-Ar.sup.6 is one of a hydrogen and an aryl, and any of R.sub.4R.sub.11 and R.sub.13R.sub.15 is independently selected from a group consisting of a hydrogen, a deuterium, a halogen, a substituted or unsubstituted alkyl, a substituted or unsubstituted cycloalkyl and a substituted or unsubstituted aryl.

A Continuous Flow Process For The Preparation Of Ingenol-3-Mebutate
20170190652 · 2017-07-06 ·

Disclosed is a continuous process for the preparation of ingenol-3-mebutate by reaction, in solution, of ingenol or ingenol anion and angelic anhydride or an equivalent angelylating agent. The continuous flow process is preferably performed in the presence of a base such as lithium hexamethyl disilazane (LiHMDS) and/or an activating agent such as dicyclohexylcarbodiimide (DCC). Also disclosed is a process for recycling the other reaction products obtained in the continuous process for preparation of ingenol-3-mebutate for formation of ingenol, which can then be recycled to form ingenol-3-mebutate.

##STR00001##

Method of producing ingenol-3-angelate

The present invention relates to methods of producing ingenol-3-angelate (I) from ingenol (II). ##STR00001## Furthermore, the invention relates to intermediates useful for the synthesis of ingenol-3-angelate (I) from ingenol (II) and to methods of producing said intermediates.

Process for the preparation of ingenol-3-angelate from 20-deoxy-ingenol
09624157 · 2017-04-18 · ·

The present invention provides a method for preparing ingenol-3-angelate.